α,α,α-tribromo-o-xylene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α,α,α-tribromo-o-xylene
• 英文别名: 1-Methyl-2-(tribromomethyl)benzene
• 化学式: C₈H₇Br₃
• 分子量: 342.856
• InChiKey: JYRQNJHCKJSGIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  邻二甲苯 在 偶氮二异丁腈 、 1,3,4,6-Tetrabromo-3α,6α-diphenylglycoluril 作用下， 以 四氯化碳 为溶剂， 反应 2.0h， 以20%的产率得到2-甲基苄溴
  参考文献：
  名称：

  甲基芳烃和甲基杂芳烃的改进卤化：四卤代二苯基甘脲的意外反应

  摘要：

  1,3,4,6-四氯 (TCDGU) 和 1,3,4,6-四溴-3α,6α-二苯基甘脲平滑卤素氧化剂已被开发用作自由基取代某些 N-卤代琥珀酰亚胺非反应性试剂的新方向双杂环。对于感兴趣的甲基苯、甲基杂环和甲基双杂环，观察到了意想不到的选择性和反应性。已进行化学计量学研究以优化与 TCDGU 氯化反应的五个独立因素。建立了卤化转化率和一氯化比的预测模型。

  DOI：

  10.1002/hc.21314

文献信息

• Organic electroluminescent element material, organic electroluminescent element, display device and lighting device
  申请人：Ikemizu Dai

  公开号：US20070196690A1

  公开（公告）日：2007-08-23

  An organic electroluminescent element material represented by Formula (1), Formula (1): wherein Z is a heterocylcic ring comprising a substituent having a steric parameter value (Es) of −0.5 or less at the third atom of the ring counted from a nitrogen atom attached to Z, the nitrogen atom being counted as the first atom; and other symbols in Formula (1) are described in the specification.

  一种由式（1）表示的有机电致发光元件材料，式（1）：其中Z是一个杂环环，包括一个取代基，在从Z连接的氮原子算起的第三个原子处具有空间参数值（Es）小于或等于-0.5，该氮原子被计为第一个原子；式（1）中的其他符号在说明书中描述。
• Photolysis of a series of α-brominated ortho-xylenes in apolar solvents
  作者：Daisy de B. Rezende、Ivan P. de Arruda Campos、Vicente G. Toscano、Luiz H. Catalani

  DOI：10.1039/p29950001857

  日期：——

  The alpha-brominated ortho-xylenes have been subjected to 254-nm irradiation in deaerated benzene, isooctane and benzene-cyclohexene. The product analysis revealed that homolysis of the C-Br bond is followed by a series of hydrogen abstraction and radical recombination reactions resulting in xylenes more and less brominated than the starting compound. The less brominated products are formed with higher quantum yield when cyclohexene is present, due to hydrogen abstraction by the o-benzyl radical formed initially, together with cyclohexene dimers. Additionally, the formation of 2-bromo-2,4,4-trimethylpentane is observed when isooctane is the solvent. The quantum yields observed for the photolysis of 1 and 2 are higher in benzene than in isooctane, suggesting sensitization by benzene. A biradical intermediate of the type o-quinodimethane was expected in the case of (a) photolysis of the o-benzyl radical formed (biphotonic process) or (b) intramolecular hydrogen abstraction. However, the addition of cyclohexene failed to produce the expected Diels-Alder adduct; The synthesis of the novel alpha,alpha-dibromo-o-xylene 3 is reported.
• ORGANIC ELECTROLUMINESCENCE ELEMENT, LIGHTING DEVICE AND DISPLAY DEVICE
  申请人：Katakura Rie

  公开号：US20100045171A1

  公开（公告）日：2010-02-25

  Disclosed is an organic electroluminescent device having high external quantum efficiency and long emission life. Also disclosed are an illuminating device and a display, each comprising such an organic electroluminescent device. The organic electroluminescent device is characterized by comprising at least an anode and a cathode on a supporting substrate, while having at least one light-emitting layer between the anode and the cathode. The organic electroluminescent device is also characterized by containing a polymer which at least partially contains a compound A having a partial structure represented by the general formula (a) below and a reactive group, and is obtained by polymerizing the compound A through the reactive group. (In the formula, Ar1 and Ar2 respectively represent an aromatic ring.)
• ORGANIC ELECTROLUMINESCENCE ELEMENT, NEW COMPOUND FOR THE SAME, DISPLAY DEVICE AND LIGHTING DEVICE USING THE SAME
  申请人：KATAKURA Rie

  公开号：US20110006670A1

  公开（公告）日：2011-01-13

  Disclosed is an organic electroluminescence element comprising an anode, a cathode and a plurality of organic compound layers between the anode and the cathode, provided that one of the organic compound layers is a light emitting layer containing a phosphorescence emitting compound, wherein at least one of the organic compound layers contains a compound represented by Formula (1), wherein, X represents O or S; Y 1 to Y 3 each represents a hydrogen atom, a substituent or a group represented by Formula (A) disclosed in the specification, provided that at least two of Y 1 to Y 3 are groups represented by Formula (A), not all of Y 1 to Y 3 are the same group, and at least one of the groups represented by Formula (A) has Ar of a carbazolyl group, or an azacarbazolyl group containing 2 to 5 nitrogen atoms.
• US8852757B2
  申请人：——

  公开号：US8852757B2

  公开（公告）日：2014-10-07