9,9-bis-(3-hydroxyphenyl)fluorene

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-bis-(3-hydroxyphenyl)fluorene
• 英文别名: 3-[9-(3-Hydroxyphenyl)fluoren-9-yl]phenol
• 化学式: C₂₅H₁₈O₂
• 分子量: 350.417
• InChiKey: NGQGRUANWKNCAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,9-bis-(3-hydroxyphenyl)fluorene 、 1,3-二氟苯 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 48.0h， 以32%的产率得到
  参考文献：
  名称：

  화합물 및 이를 포함하는 유기 발광 소자

  摘要：

  本说明提供了化学式1的化合物以及包含它的有机发光器件。

  公开号：

  KR20180112721A
• 作为产物：
  描述：

  9,9-di(3-anisyl)fluorene 在 三溴化硼 作用下， 以 氯仿 为溶剂， 以86%的产率得到9,9-bis-(3-hydroxyphenyl)fluorene
  参考文献：
  名称：

  화합물 및 이를 포함하는 유기 발광 소자

  摘要：

  本说明提供了化学式1的化合物以及包含它的有机发光器件。

  公开号：

  KR20180112721A

文献信息

• ANTIREFLECTIVE COATING COMPOSITION AND PROCESS THEREOF
  申请人：RAHMAN M. Dalil

  公开号：US20140370444A1

  公开（公告）日：2014-12-18

  The present invention relates to an absorbing hard mask antireflective coating composition comprising a novel polymer, where the novel polymer comprises in the backbone of the polymer four repeat units -A-, -B-, -C- and -D-, where A is repeat unit which comprises a fused aromatic ring in its backbone, B has the structure (1), C is a hydroxylbiphenyl of structure (2) and D is a derivatized fluorene of structure (3), where R 1 is C 1 -C 4 alkyl, R 2 is C 1 -C 4 alkyl, R 3 and R 4 are independently hydrogen or C 1 -C 4 alkyl, and Ar′ and Ar″ are independently phenylenic, or naphthalenic derived moieties, R 5 and R 6 are independently —OH or —CH 2 ) n OH where n=2-4, and R 7 and R 8 are independently hydrogen or C 1 -C 4 alkyl. This invention also relates to a process for forming an image using the novel antireflective coating composition.

  本发明涉及一种吸收硬掩膜抗反射涂层组合物，其包括一种新型聚合物，其中该新型聚合物在其聚合物骨架中包含四个重复单元-A-，-B-，-C-和-D-，其中A是包含融合芳香环的重复单元，B具有结构（1），C是结构（2）的羟基联苯，D是结构（3）的衍生物芴，其中R1是C1-C4烷基，R2是C1-C4烷基，R3和R4独立地为氢或C1-C4烷基，Ar′和Ar″独立地为苯基或萘基衍生物，R5和R6独立地为—OH或—CH2）nOH，其中n=2-4，R7和R8独立地为氢或C1-C4烷基。本发明还涉及使用新型抗反射涂层组合物形成图像的过程。
• Infrared cut filter, solid-state imaging device, and imaging/display apparatus
  申请人：AGC Inc.

  公开号：US10345498B2

  公开（公告）日：2019-07-09

  Provided is an infrared cut filter including: an infrared absorbing layer of a transparent resin containing an infrared absorber; and a selected wavelength cut layer stacked on the infrared absorbing layer, wherein the following requirements are satisfied. (i) In a spectral transmittance curve for an incident angle of 0°, an average transmittance in a 450-600 nm range is 80% or more, a transmittance in a 700-1200 nm range is 2.0% or less, and D0 represented by the following expression is less than 0.04. D0 (%/nm)=(Tmax·0−Tmin·0)/(λ(Tmax·0)−λ(Tmin·0)) (ii) wherein a spectrum transmittance curve for an incident angle of 30°, an average transmittance in the 450 to 600 nm range is 80% or more, a transmittance in the 700-1200 nm range is 2.0% or less, and D30 represented by the following expression is less than 0.04. D30 (%/nm)=(Tmax·30−Tmin·30)/(λ(Tmax·30)−×(Tmin·30))

  本发明提供了一种红外线切割滤光片，包括：由含有红外线吸收剂的透明树脂构成的红外线吸收层；以及叠加在红外线吸收层上的选定波长切割层，其中满足以下要求。(i) 在入射角为 0°的光谱透射率曲线中，450-600 纳米范围内的平均透射率为 80% 或以上，700-1200 纳米范围内的透射率为 2.0% 或以下，用以下表达式表示的 D0 小于 0.04。D0 (%/nm)=(Tmax-0-Tmin-0)/(λ(Tmax-0)-λ(Tmin-0)) (ii) 在入射角为 30°的光谱透射率曲线中，450-600 纳米范围内的平均透射率为 80% 或以上，700-1200 纳米范围内的透射率为 2.0% 或以下，且由以下表达式表示的 D30 小于 0.04。D30 (%/nm)=(Tmax-30-Tmin-30)/(λ(Tmax-30)-×(Tmin-30))
• POLYAMIDE MOULDING COMPOSITION AND MULTI-LAYERED STRUCTURE MADE HEREFROM
  申请人：EMS-PATENT AG

  公开号：EP3312224B1

  公开（公告）日：2018-12-26
• ANTIREFLECTIVE COATING COMPOSITIONS AND PROCESSES THEREOF
  申请人：AZ ELECTRONIC MATERIALS (LUXEMBOURG) S.A.R.L.

  公开号：US20150309410A1

  公开（公告）日：2015-10-29

  The present invention relates to a novel absorbing antireflective coating composition comprising a novel crosslinkable polymer comprising at least one repeat unit (A) having structure (1), at least one repeat unit (B) having a structure (2), and at least one repeat unit (C) having structure (3) where D is a direct valence bound or C(R 1 )(R 2 ) methylene moiety where R 1 and R 2 are independently H, C 1 -C 5 alkyl, C 3 -C 24 cycloalkyl or C 6 -C 24 aryl; Ar i , Ar ii , Ar iii and Ar iv are independently phenylenic and naphthalenic moiety, R 3 and R 4 are independently hydrogen or C 1 -C 8 alkyl; and R 5 and R 6 are independently hydrogen or C 1 -C 8 alkyl; and a solvent. The invention also relates to a process for forming an image using the novel antireflective coating composition.
• POLYCARBONATE MADE FROM LOW SULFUR BISPHENOL A AND CONTAINING CONVERSIONS MATERIAL CHEMISTRY, AND ARTICLES MADE THEREFROM
  申请人：SABIC Global Technologies B.V.

  公开号：US20160369049A1

  公开（公告）日：2016-12-22

  In one embodiment, a light emitting device, comprises: a lighting element located in a housing, wherein the housing is formed from a plastic composition comprising: a polycarbonate formed from reacting, in the presence of a transesterification catalyst, a diaryl carbonate ester and a bisphenol A, wherein the bisphenol A has a sulfur concentration of 1 ppm to 15 ppm, based upon a weight of the bisphenol A; and a conversion material wherein the conversion material comprises an inorganic material that converts radiation of a certain wavelength and re-emits of a different wavelength; wherein after the conversion material has been exposed to an excitation source, the conversion material has a luminescence lifetime of less than 10 −4 seconds when the excitation source is removed.