5-carboxylic acid tetracene

• 分子结构分类: 有机化合物 - 苯类化合物 - 并四苯
• 英文名称: 5-carboxylic acid tetracene
• 英文别名: 5-tetracenecarboxylic acid；naphthacene-5-carboxylic acid；Naphthacen-5-carbonsaeure；5-Tetracenecarboxylic acid；tetracene-5-carboxylic acid
• 化学式: C₁₉H₁₂O₂
• 分子量: 272.303
• InChiKey: OEGYGYSSZOFILE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-carboxylic acid tetracene 在 aluminum (III) chloride 、 氯化亚砜 、 sulfur 作用下， 以 N,N-二甲基甲酰胺 、 邻二氯苯 、 苯 为溶剂， 反应 26.42h， 生成 N-(iso-propyl)-tetracenecarboxylic acid 5,6-imide-11,12-disulfide
  参考文献：
  名称：

  四氢呋喃二羧酸酰亚胺及其二硫化物：用于有机光伏电池的双极性有机半导体的合成

  摘要：

  我们设计并合成了一种新的供体/受体型并四苯衍生物，方法是分别引入二羧酸酰亚胺和二硫化物基团作为吸电子和供电子单元。制备的化合物并四苯并二羧酸酰亚胺（TI）及其二硫化物（TIDS）具有很高的化学和电化学稳定性，并在薄膜中具有高达886 nm的长波长吸收。TIDS分子的晶体堆积结构具有面对面π堆积的特性，这种堆积源自偶极子-偶极子相互作用。值得注意的是，TIDS在p – n和p–i–n中均表现出给电子性和接受性的双极性性质。异质结有机薄膜光伏器件。因此，TI和TIDS有望成为用于设计新型有机半导体的有前途的化合物。

  DOI：

  10.1002/asia.201100590
• 作为产物：
  描述：

  并四苯 生成 5-carboxylic acid tetracene
  参考文献：
  名称：

  Martynoff, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1954, vol. 238, p. 249

  摘要：

  DOI：

文献信息

• POLYMERIZABLE COMPOSITION
  申请人：TOYO INK MFG. CO., LTD.

  公开号：EP1816152A1

  公开（公告）日：2007-08-08

  According to the invention, there is provided a polymerizable composition which is cured by irradiation with a small amount of energy line, and offers excellent adhesiveness and transparency. The composition comprises an acid generator (A) containing a sulfonium cation and a borate anion represented by the following general formula (1), and a cationic polymerizable compound (B). General formula (1)         [BYmZn]-     general formula(1) Wherein, Y represents a fluorine or chlorine atom, Z represents a phenyl group substituted with two or more groups selected from a fluorine atom, cyano group, nitro group, and trifluoromethyl group, m represents an integer from 0 to 3, n represents an integer from 1 to 4, and m+n=4.

  根据本发明，提供了一种可聚合组合物，该组合物可通过少量能量线照射固化，并具有极佳的粘合性和透明度。该组合物包括含有由以下通式（1）表示的锍阳离子和硼酸阴离子的酸发生体（A），以及阳离子可聚合化合物（B）。 通式（1） [BYmZn]--通式(1) 其中，Y 代表氟原子或氯原子，Z 代表被两个或两个以上选自氟原子、氰基、硝基和三氟甲基的基团取代的苯基，m 代表 0 至 3 的整数，n 代表 1 至 4 的整数，m+n=4。
• EASILY REMOVABLE CURABLE COMPOSITION FOR DENTAL USE
  申请人：SUN MEDICAL CO., LTD.

  公开号：EP2491915A1

  公开（公告）日：2012-08-29

  A dental curable composition whose polymerization is not impeded even in a moist environment and in the presence of oxygen and which has excellent marginal sealability and enables the provision of flexibility and the control of removability. The dental curable composition comprises (A) a polymerizable monomer and (B) an organic amine-based polymerization initiator, wherein (A') a long-chain polymerizable monomer having a chain length of 17 or more atoms is contained in the component (A) and/or (C) a soft resin material are/is contained in the composition, and when the amount (parts by weight) based on 100 parts by weight of the component (A) of the component (Aʹ) is represented by [aʹ] and the amounts (parts by weight) based on 100 parts by weight of the total of the components (A) and (B) of the components (A), (B) and (C) are represented by (a), (b) and (c), respectively, 70 ≦ (a) ≦ 99.99, 0.01 ≦ (b) ≦ 30,1 ≦ [aʹ]/5 + (c)/1, 0 ≦ [aʹ] ≦ 95, and 0 ≦ (c) ≦ 250.

  一种牙科固化组合物，其聚合即使在潮湿环境和有氧气存在的情况下也不会受阻，具有极佳的边缘密封性，并能提供柔韧性和控制可移除性。 牙科固化组合物包括 (A) 可聚合单体和 (B) 有机胺类聚合引发剂，其中 (A') 组分 (A) 中含有链长为 17 个或更多原子的长链可聚合单体，和/或 (C) 组合物中含有软树脂材料、当组分(Aʹ)中基于 100 份重量的组分(A)的量(重量份数)用[aʹ]表示，组分(A)、(B)和(C)中基于 100 份重量的组分(A)和(B)总量的量(重量份数)分别用(a)、(b)和(c)表示时，70 ≦ (a) ≦ 99.99，0.01 ≦ (b) ≦ 30，1 ≦ [aʹ]/5 + (c)/1，0 ≦ [aʹ] ≦ 95，0 ≦ (c) ≦ 250。
• Acene-based transmitter molecules for photon upconversion
  申请人：THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

  公开号：US10351580B2

  公开（公告）日：2019-07-16

  Provided herein are transmitter ligands that improve photon upconversion of near infrared light (NIR) to visible light. The presently provided ligands are complexed to semiconductor nanocrystals and improve triplet energy transfer from semiconductor nanocrystal to annihilator in triplet-triplet annihilation. Suitable applications include bio-imaging.

  本文提供的发射配体可改善近红外线（NIR）到可见光的光子上转换。目前提供的配体与半导体纳米晶体络合，可改善三重三重湮灭中从半导体纳米晶体到湮灭器的三重三重能量转移。适合的应用包括生物成像。
• Polymerizable Composition
  申请人：Kanno Masaki

  公开号：US20080044149A1

  公开（公告）日：2008-02-21

  According to the invention, there is provided a polymerizable composition which is cured by irradiation with a small amount of energy line, and offers excellent adhesiveness and transparency. The composition comprises an acid generator (A) containing a sulfonium cation and a borate anion represented by the following general formula (1), and a cationic polymerizable compound (B). General formula (1) [BY m Z n ] − general formula (1) Wherein, Y represents a fluorine or chlorine atom, Z represents a phenyl group substituted with two or more groups selected from a fluorine atom, cyano group, nitro group, and trifluoromethyl group, m represents an integer from 0 to 3, n represents an integer from 1 to 4, and m+n=4.
• REMOVABLE DENTAL CURABLE COMPOSITION
  申请人：Ori Tatsuya

  公开号：US20120213832A1

  公开（公告）日：2012-08-23

  A dental curable composition comprises (A) a polymerizable monomer and (B) an organic amine-based polymerization initiator, wherein (A′) a long-chain polymerizable monomer having a chain length of 17 or more atoms is contained in the component (A) and/or (C) a soft resin material are/is contained in the composition, and when the amount (parts by weight) based on 100 parts by weight of the component (A) of the component (A′) is represented by [a′] and the amounts (parts by weight) based on 100 parts by weight of the total of the components (A) and (B) of the components (A), (B) and (C) are represented by (a), (b) and (c), respectively, 70≦(a)≦99.99, 0.01≦(b)≦5 30, 1≦[a′]/5+(c)/1, 0≦[a′]≦95, and 0≦(c)≦250.