四氯化锡-2-吡啶 | 17100-04-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 四氯化锡-2-吡啶
• 英文名称: bis(pyridine)tetrachlorotin
• 英文别名: SnCl4*2pyridine；SnCl4*2C5H5N；Pyridine;tetrachlorostannane
• CAS: 17100-04-8；22798-23-8；95462-91-2
• 化学式: C₁₀H₁₀Cl₄N₂Sn
• 分子量: 418.725
• InChiKey: RLRHMVBZGXGYDV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  4.54
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  在 pyridine 作用下， 以 吡啶 、 乙腈 为溶剂， 生成 四氯化锡-2-吡啶
  参考文献：
  名称：

  Studies on adducts of tin tetrahalides and titanium tetrachloride with β-aminothiones and β-ketoamines

  摘要：

  DOI：

  10.1016/0584-8539(84)80071-9

文献信息

• Electron density redistribution on complexation in non-transition element complexes
  作者：O.Kh. Poleshchuk、B. Nogaj、G.N. Dolenko、V.P. Elin

  DOI：10.1016/0022-2860(93)80185-x

  日期：1993.8

  Complexes of tin, antimony, silicon, germanium, iodine, boron and titanium halogenides with organic ligands were investigated using nuclear quadrupole resonance (NQR) and X-ray fluorescence spectroscopies, and Mossbauer effect and quantum-chemical calculations. A discussion of results which we obtained previously as well as literature data is included. The correlations between Cl-35 NQR and ClKalpha line shifts in SnCl4L2, SbCl5L and TiCl4L2 complexes were obtained. The geometry of the acceptor was found to influence the value of the effective charge on the chlorine atom (q(Cl)) in SnCl4L2 complexes, but not to influence the chlorine atom in TiCl4L2 complexes. Values of q(Sn) and q(Sb) were calculated from Mossbauer isomer shifts in the SnCl4L2 and SbCl5L complexes. Electron-density transfer from the ligand to the vacant d orbital of the central atom on complexation was observed.
• Fichter, F.; Herszbein, S., Helvetica Chimica Acta, 1928, vol. 11, p. 562 - 567
  作者：Fichter, F.、Herszbein, S.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: MVol.C2, 14.12.1, page 221 - 222
  作者：

  DOI：——

  日期：——
• Studies on adducts of tin tetrahalides and titanium tetrachloride with β-aminothiones and β-ketoamines
  作者：R.P. Singh、V.D. Gupta

  DOI：10.1016/0584-8539(84)80071-9

  日期：1984.1