N,10-dimethyl-N-phenyl-9-anthracenamime

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N,10-dimethyl-N-phenyl-9-anthracenamime
• 英文别名: N,10-dimethyl-N-phenylanthracen-9-amine
• 化学式: C₂₂H₁₉N
• 分子量: 297.4
• InChiKey: FFRMQFVJYFILHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,2-二甲基咪唑 、 2-(三甲基硅)苯基三氟甲烷磺酸盐 在 cesium fluoride 作用下， 以 乙腈 为溶剂， 反应 12.0h， 以70%的产率得到N,10-dimethyl-N-phenyl-9-anthracenamime
  参考文献：
  名称：

  苯并烷的新串联反应：一锅合成含蒽的芳基胺。

  摘要：

  [反应：见正文]苯炔与N-取代的咪唑的反应提供了一种在非常温和的条件下制备含蒽芳基胺的新颖方法。假定这种转化是通过涉及狄尔斯-阿尔德反应和分子间亲核偶联反应的串联反应进行的。

  DOI：

  10.1021/ol063017g

文献信息

• Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines
  作者：Sheng Zhang、Yi Wang、Xiujuan Feng、Ming Bao

  DOI：10.1021/ja300164d

  日期：2012.3.28

  Palladium-catalyzed amination of chloromethylnaphthalene and chloromethylanthracene derivatives to produce naphthylamines and anthrylamines in satisfactory to good yields has been developed. The unprecedented amination reactions proceeded smoothly under mild conditions in the presence of Pd(PPh3)(4) as a catalyst.
• POLYMER COMPOUND, NET-LIKE POLYMER COMPOUND PRODUCED BY CROSSLINKING THE POLYMER COMPOUND, COMPOSITION FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC EL DISPLAY, AND ORGANIC EL LIGHTING
  申请人：Iida Koichiro

  公开号：US20110108814A1

  公开（公告）日：2011-05-12

  An object of the invention is to provide a polymer compound having a high hole transport capacity, excellent in electrochemical stability, and suitable to film formation according to a wet film formation method. Another object of the invention is to provide an organic electroluminescence element having a high current efficiency, a low drive voltage, and a long derive lifetime. The polymer compound has a crosslinking group bonding to the arylamine moiety in the repeating unit via at least one single bond therebetween.
• US8581241B2
  申请人：——

  公开号：US8581241B2

  公开（公告）日：2013-11-12