1-((E)-2-(2-bromophenyl)-1-ethenyl)-2-iodobenzene

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-((E)-2-(2-bromophenyl)-1-ethenyl)-2-iodobenzene
• 英文别名: 1-bromo-2-[(E)-2-(2-iodophenyl)ethenyl]benzene
• 化学式: C₁₄H₁₀BrI
• 分子量: 385.042
• InChiKey: LPHMZDNBRDUGGO-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-碘苯甲醛 、 [(2-溴苯基)甲基]三苯基-鏻溴化物 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 25.5h， 生成 1-((Z)-2-(2-bromophenyl)-1-ethenyl)-2-iodobenzene 、 1-((E)-2-(2-bromophenyl)-1-ethenyl)-2-iodobenzene
  参考文献：
  名称：

  Extremely deep-blue fluorescent emitters with CIEy ≤ 0.04 for non-doped organic light-emitting diodes based on an indenophenanthrene core

  摘要：

  The fluorescent molecules 7,7-dimethyl-N,N-diphenyl-7H-indeno[1,2-a] phenanthren-9-amine (DIP) and 4-(7,7-dimethyl-7H-indeno[1,2-a]phenanthren-9-yl)-N,N-diphenylaniline (TIP), with indenophenanthrene cores and attached arylamine structures, were synthesized for use as extremely deep blue fluorescent emitting materials. A non-doped device using DIP as an emitting material exhibited a maximum external quantum efficiency of 3.27% and had Commission Internationale de l'Eclairage (CIE) color coordinates of (0.158, 0.040). (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2017.05.014

文献信息

• Efficient Phenanthrene, Helicene, and Azahelicene Syntheses
  作者：David C. Harrowven、Ian L. Guy、Lana Nanson

  DOI：10.1002/anie.200504287

  日期：2006.3.27
• Extremely deep-blue fluorescent emitters with CIEy ≤ 0.04 for non-doped organic light-emitting diodes based on an indenophenanthrene core
  作者：Seongjin Jeong、Jong-In Hong

  DOI：10.1016/j.dyepig.2017.05.014

  日期：2017.9

  The fluorescent molecules 7,7-dimethyl-N,N-diphenyl-7H-indeno[1,2-a] phenanthren-9-amine (DIP) and 4-(7,7-dimethyl-7H-indeno[1,2-a]phenanthren-9-yl)-N,N-diphenylaniline (TIP), with indenophenanthrene cores and attached arylamine structures, were synthesized for use as extremely deep blue fluorescent emitting materials. A non-doped device using DIP as an emitting material exhibited a maximum external quantum efficiency of 3.27% and had Commission Internationale de l'Eclairage (CIE) color coordinates of (0.158, 0.040). (C) 2017 Elsevier Ltd. All rights reserved.