N-(3-chloropropyl)cyclohexanammonium chloride

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(3-chloropropyl)cyclohexanammonium chloride
• 化学式: C₉H₁₈ClN*ClH
• 分子量: 212.163
• InChiKey: IEXQGTBVNJPKOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.96
• 重原子数：
  12.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.03
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  2,6-diisopropylphenylisocyanogold(I) chloride 、 N-(3-chloropropyl)cyclohexanammonium chloride 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以91%的产率得到
  参考文献：
  名称：

  异腈路线合成不同种类的六元金（I）NHC配合物

  摘要：

  Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.

  DOI：

  10.1021/acs.organomet.6b00023
• 作为产物：
  描述：

  3-环己基氨基-1-丙醇 在 氯化亚砜 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以71%的产率得到N-(3-chloropropyl)cyclohexanammonium chloride
  参考文献：
  名称：

  异腈路线合成不同种类的六元金（I）NHC配合物

  摘要：

  Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.

  DOI：

  10.1021/acs.organomet.6b00023

文献信息

• Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
  作者：Thomas Wurm、Florian Mulks、Constantin R. N. Böhling、Dominic Riedel、Poorya Zargaran、Matthias Rudolph、Frank Rominger、A. Stephen K. Hashmi

  DOI：10.1021/acs.organomet.6b00023

  日期：2016.4.25

  Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.