对叔丁基苯酚与乙炔的聚合物 | 28514-92-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 对叔丁基苯酚与乙炔的聚合物
• 英文名称: Acetylene;4-tert-butylphenol
• CAS: 28514-92-3
• 化学式: C12H16O
• 分子量: 176.25
• InChiKey: VUBQYTCIOHLJGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.94
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Adhesive compositions
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0243956A2

  公开（公告）日：1987-11-04

  An adhesive composition comprising 100 parts by weight of a block copolymer (a) containing of at least one polymer block composed mainly of a vinyl aromatic hydrocarbon and at least one polymer block composed mainly of butadiene in which (i) the vinyl aromatic hydrocarbon content [S] is 10 to 30% by weight, (ii) the 1,2-vinyl content of butadiene portion [V] is 20 to 50%, and (iii) the relationship between said vinyl aromatic hydrocarbon content [S] and said 1,2-vinyl content of butadiene portion [V] satisfies the formula: 40 to 200 parts by weight of a tackifier (b), and, optionally contain various stabilizers; and a process for producing said composition.

  一种粘合剂组合物，包括 100 重量份的嵌段共聚物(a)，其中至少含有一个主要由乙烯基芳香烃组成的聚合物嵌段和至少一个主要由丁二烯组成的聚合物嵌段，其中(i)乙烯基芳香烃含量[S]为 10-30%（重量），(ii)丁二烯部分的 1,2-乙烯基含量[V]为 20-50%，(iii)所述乙烯基芳香烃含量[S]和所述丁二烯部分的 1,2-乙烯基含量[V]之间的关系符合公式： 40 至 200 重量份的增粘剂 (b)，以及可选的各种稳定剂；以及生产所述组合物的工艺。
• TERMINAL-MODIFIED BLOCK COPOLYMER AND COMPOSITION CONTAINING SAID COPOLYMER
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0245505A1

  公开（公告）日：1987-11-19

  A terminal-modified block copolymer wherein an amino group- or amino group-containing, terminal-treating agent is bound to the terminals of the polymer. It is obtained by reacting the active terminals of a block copolymer of a conjugated diene with a vinylaromatic hydrocarbon comprising 5 to 95 % of a vinylaromatic hydrocarbon and having a number- average molecular weight of 5,000 to 1,000,000 (obtained by using at least one member selected from among alkali metals and organic alkali metal compounds as a polymerization initiator) with at least one terminal-treating agent selected from among imide compounds, cyanamide compounds, aziridinyl compounds, amide compounds, and other tertiary amino group-containing compounds. A pressure-sensitive adhesive composition excellent in adhesiveness and anti-creeping properties comprising said block copolymer and a tackifying resin, a water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplastic resin composition comprising said block copolymer and a thermoplastic resin, and a conductive composition comprising said block copolymer and a conductive material are also disclosed.

  一种末端改性嵌段共聚物，其中一种含氨基或氨基基团的末端处理剂与聚合物的末端结合。它是通过将共轭二烯与乙烯基芳烃的嵌段共聚物的活性末端与至少一种末端处理剂反应而得到的，该末端处理剂选自亚胺化合物、氰胺化合物、氮杂环丁基化合物、酰胺化合物和其他含三级氨基基团的化合物，乙烯基芳烃的含量为 5%至 95%，平均分子量为 5,000 至 1,000,000 （通过使用至少一种选自碱金属和有机碱金属化合物的成员作为聚合引发剂而得到）。此外，还公开了由所述嵌段共聚物和增粘树脂组成的粘合性和防蠕变性能优异的压敏胶组合物、由所述嵌段共聚物和高吸水性树脂组成的吸水组合物、由所述嵌段共聚物和热塑性树脂组成的热塑性树脂组合物以及由所述嵌段共聚物和导电材料组成的导电组合物。
• Specific hydrogenated block copolymer composition and process for producing the same
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0299499A2

  公开（公告）日：1989-01-18

  A composition comprising, (a) 1 to 99 parts by weight of a specific hydrogenated product of a block copolymer having at least one polymer block composed mainly of a vinyl aromatic compound and at least one polymer block composed mainly of a conjugated diene compound, a modified product which comprises said product modified with an α,8-unsaturated carboxylic acid or a derivative thereof, or a mixture of said product and said modified product, wherein the content of the vinyl aromatic compound prior to hydrogenation is 5 to 95 % by weight and a content of vinyl linkages [V] prior to hydrogenation which originated from the conjugated diene compound is 10 to 80 %, said product satisfying the following conditions; (1) the hydrogenated ratio [A] of the total of aliphatic double bonds which originated from the conjugated diene compound is not lower than 5 % and lower than 50 %, and (2) [B]/[V]1/2 = 3 to 20, wherein [B] is the hydrogenated ratio of the vinyl linkage portions which originated from the conjugated diene compound, and (b) 99 to 1 parts by weight of at least one thermoplastic substance selected from the group consisting of tackifier resins, thermoplastic resins and bituminous materials, and a process for producing the same.

  一种组合物，包括 (a) 1 至 99 份(重量)嵌段共聚物的特定氢化产物，该嵌段共聚物至少有一 个主要由乙烯基芳香族化合物组成的聚合物嵌段和至少有一个主要由共轭二 烯化合物组成的聚合物嵌段；改性产物，该改性产物包括用α,8-不饱和羧酸 或其衍生物改性的上述产物、或上述产品和上述改性产品的混合物，其中氢化前乙烯基芳香族化合物的含量为 5% 至 95%（重量百分比），氢化前源自共轭二烯化合物的乙烯基链节[V]的含量为 10% 至 80%，上述产品满足以下条件； (1) 源自共轭二烯化合物的脂肪族双键总数的氢化比率[A]不低于 5%，也不低于 50%，以及 (2) [B]/[V]1/2 = 3 至 20、 其中[B]是源自共轭二烯化合物的乙烯基连接部分的氢化比率，以及 (b) 至少一种热塑性物质，其重量占 99 至 1 份，该热塑性物质选自增粘剂树脂、 热塑性树脂和沥青材料组成的组，以及生产该热塑性物质的工艺。
• Compositions containing a terminal-modified block copolymer
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0473206A2

  公开（公告）日：1992-03-04

  An adhesive composition excellent in tackiness, adhesiveness, and creep resistance characteristic which comprises said block copolymer and a tackifier resin, a water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplastic resin composition comprising said block copolymer and a thermoplastic resin, and an electroconductive composition comprising said block copolymer and an electroconductive material, which consists of a terminal-modified block copolymer having the rest of the terminal-treating agent bonded to the polymer terminal which is obtained by treating the active terminal of a block copolymer comprising conjugated dienes and vinylaromatic hydrocarbon compounds which is obtained by using as the polymerization initiator at least one member selected from alkali metals or organoalkali metals and has a vinylaromatic hydrocarbon content of 5 to 95% by weight and a number average molecular weight of 5,000 to 1,000,000.

  一种粘合剂组合物，具有优异的粘性、粘附性和抗蠕变性，由所述嵌段共聚物和增粘树脂、由所述嵌段共聚物和高吸水性树脂组成的吸水组合物、由所述嵌段共聚物和热塑性树脂组成的热塑性树脂组合物以及由所述嵌段共聚物和导电材料组成的导电组合物构成、其中包括一种末端改性嵌段共聚物，其末端处理剂的其余部分与聚合物末端结合，该聚合物末端是通过处理由共轭二烯和乙烯基芳烃化合物组成的嵌段共聚物的活性末端而获得的，该嵌段共聚物是通过使用至少一种选自碱金属或有机碱金属的成员作为聚合引发剂而获得的，其乙烯基芳烃含量为 5%至 95%（按重量计），平均分子量为 5,000 至 1,000,000 。
• Rubber composition for tire treads
  申请人：BRIDGESTONE CORPORATION

  公开号：EP0697432A1

  公开（公告）日：1996-02-21

  Rubber compositions for tire treads. Typically, they contain a rubber component containing at least 70 parts by weight of a styrene-butadiene rubber whose styrene content is 20 to 60%; and contain, based on 100 parts by weight of the rubber component, 5 to 150 parts by weight of a powdery inorganic compound represented by formula (I) and having a particle size from 0.01 to 10 µm:         mM¹ · xSiOy · zH₂O   (I) in which M¹ is at least one selected from the group consisting of Al, Mg, Ti, and Ca; any oxide of any one of the metals; or any hydroxide of any one of the metals; and m, x, y, and z are integers from 1 to 5, 0 to 10, 2 to 5, and 0 to 10, respectively; and 5 to 170 parts by weight of carbon black having a nitrogen adsorption specific area of 80 to 280 m/g so that the total amount of the powdery inorganic compound and the carbon black falls in the range of 70 to 200 parts by weight. The amount of an extract obtained by extracting the rubber composition after being vulcanized from acetone and chloroform should be 30 to 270 parts by weight. Similar compositions containing silica are also disclosed.

  用于轮胎胎面的橡胶组合物。通常，它们包含一种橡胶成分，按重量计至少含有 70 份苯乙烯-丁二烯橡胶，其苯乙烯含量为 20% 至 60%；按 100 份橡胶成分的重量计，含有 5 至 150 份由式（I）表示的粉末状无机化合物，其粒径为 0.01 至 10 微米： mM¹ - xSiOy - zH₂O (I) m、x、y 和 z 分别为 1 至 5、0 至 10、2 至 5 和 0 至 10 的整数；以及 5 至 170 重量份的炭黑，其氮吸附比面积为 80 至 280 m/g，从而使粉状无机化合物和炭黑的总量在 70 至 200 重量份的范围内。通过从丙酮和氯仿中萃取硫化后的橡胶组合物而获得的萃取物的量应为 30 至 270 份（按重量计）。此外，还公开了含有二氧化硅的类似组合物。