(1E)-1,3-二(3-氯苯基)三氮杂-1-烯 | 17596-04-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (1E)-1,3-二(3-氯苯基)三氮杂-1-烯
• 英文名称: 1,3-bis-(3-chloro-phenyl)-triazene
• 英文别名: 1,3-Bis-(3-chlor-phenyl)-triazen；3.3'-Dichlor-diazoaminobenzol；3,3'-Dichlor-diazoaminobenzol；m,m'-Dichlordiazoaminobenzol；3-chloro-N-[(3-chlorophenyl)diazenyl]aniline
• CAS: 17596-04-2
• 化学式: C₁₂H₉Cl₂N₃
• 分子量: 266.13
• InChiKey: LJFGVHJIOVPLEQ-UHFFFAOYSA-N

物化性质

• 沸点：
  373.3±52.0 °C(Predicted)
• 密度：
  1.32±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (1E)-1,3-二(3-氯苯基)三氮杂-1-烯 以 乙醇 为溶剂， 反应 1.0h， 生成 4,6-O-butylidene-N-N-((3',3-dichloro)-4-azobenzyl)-β-D-glucopyranosylamine
  参考文献：
  名称：

  Synthesis and Properties of Amphiphilic Photoresponsive Gelators for Aromatic Solvents

  摘要：

  A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partial trans-cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel-sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.

  DOI：

  10.1021/ol203294v
• 作为产物：
  描述：

  3-氯苯胺 在 盐酸 、 sodium acetate 、 sodium nitrite 作用下， 生成 (1E)-1,3-二(3-氯苯基)三氮杂-1-烯
  参考文献：
  名称：

  Pytela, Oldrich; Pilny, Miroslav; Vecera, Miroslav, Collection of Czechoslovak Chemical Communications, 1984, vol. 49, # 5, p. 1173 - 1181

  摘要：

  DOI：

文献信息

• Reactions of substituted 1,3-diphenyltriazenes with phenyl isocyanates. Catalysis and substituent effects
  作者：Blanka Plandorová、Oldřich Pytela、Miroslav Večeřa、Pavel Vetešník

  DOI：10.1135/cccc19801279

  日期：——

  Reactions of phenyl isocyanate with 12 monosubstituted and 15 symmetrical disubstituted 1,3-diphenyltriazanes have been studied in tetrahydrofurane at 25°C. The found rate constants correlate with the Hammett substituent constants, the slopes being - 1.206 and - 1.682 in case of the monosubstituted and the disubstituted compounds, respectively. Under conditions of pseudomonomolecular reaction catalysis by the products and that by the catalysts used in reactions of isocyanates with amines or hydroxy compounds have not been observed. Rates of reactions of 6 substituted phenyl isocyanates with the parent 1,3-diphenyltriazane have also been measured. In this case the found rate constants correlate with the Hammett substituent constants, the slope being +1.038. The results indicate that the reaction involves rate limiting formation of a six-membered cyclic complex which successively undergoes only a rapid reorganization of electrons.

  苯基异氰酸酯与12种单取代和15种对称双取代的1,3-二苯基三氮烷在25°C下在四氢呋喃中的反应已经研究。发现的速率常数与Hammett取代基常数相关，单取代化合物和双取代化合物的斜率分别为-1.206和-1.682。在伪单分子反应催化条件下，观察到了由产物和异氰酸酯与胺或羟基化合物反应中使用的催化剂引起的反应。还测量了6种取代苯基异氰酸酯与母体1,3-二苯基三氮烷的反应速率。在这种情况下，发现的速率常数与Hammett取代基常数相关，斜率为+1.038。结果表明，反应涉及限速形成一个六元环复合物，该复合物随后仅经历电子的快速重组。
• Pigment dispersion, method for manufacturing toner, aqueous ink, and triazo compound
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10678156B2

  公开（公告）日：2020-06-09

  A pigment dispersion has low viscosity and good dispersion property without depending on pigment species. The pigment dispersion contains a dispersion medium, an organic pigment, and a triazo compound having a specific structure.

  一种颜料分散剂具有低粘度和良好的分散性能，不依赖于颜料种类。该颜料分散剂包含分散介质、有机颜料和具有特定结构的三唑化合物。
• MEASURING POVERTY AND DEPRIVATION IN SOUTH AFRICA
  作者：Stephen Klasen

  DOI：10.1111/j.1475-4991.2000.tb00390.x

  日期：2000.3

  This paper compares a standard expenditure‐based poverty measure with a specifically created composite measure of deprivation using household survey data from South Africa. While there is a strong overall correlation between expenditures and levels of deprivation, the correlation is much weaker among the worst‐off South Africans. In addition, the two measures differ considerably in the impact of race, headship, location (urban, rural), and household size on expenditure poverty versus deprivation. In general, the deprivation measure finds more Africans, rural dwellers, members of de facto female‐headed households, and members of smaller households deprived than expenditure poor. Only the differences in the effect of household size on poverty are sensitive to assumptions about equivalence scales. As a result, the two measures diverge greatly in identifying the poorest and most deprived sections of the population, which may have considerable consequences for targeting.
• Niementowski, Chemisches Zentralblatt, 1902, p. II,938
  作者：Niementowski

  DOI：——

  日期：——
• Niementowski, Bulletin International de Academie des Sciences de Cracovie, 1902, p. 417
  作者：Niementowski

  DOI：——

  日期：——