(2E)-4-{4-[2-(4-羟基苯基)-2-丙基]苯氧基}-4-氧代-2-丁烯酸 | 94158-54-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (2E)-4-{4-[2-(4-羟基苯基)-2-丙基]苯氧基}-4-氧代-2-丁烯酸
• 英文名称: Bisphenol A monofumarate
• 英文别名: (E)-4-[4-[2-(4-hydroxyphenyl)propan-2-yl]phenoxy]-4-oxobut-2-enoic acid
• CAS: 94158-54-0
• 化学式: C₁₉H₁₈O₅
• 分子量: 326.3
• InChiKey: YGVINVPNQKMIAI-VAWYXSNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

文献信息

• Curable cross-linked polyphenylene ether interpenetrating polymer network compositions and process
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0261574A2

  公开（公告）日：1988-03-30

  Curable compositions comprising a polyphenylene ether resin free of substituents which inhibit free radicals are combined with a polyvinyl unsaturated compound, such as poly(bisphenol-A fumarate) or divinyl benzene, and, optionally liquid polymerizable unsaturated monovinyl monomers, such as styrene, and cured with an optional catalyst to produce crosslinked interpolymers more rapidly than in the prior art. Before curing, the compositions can be combined with flame retardants, reinforcing fillers and/or impact modifiers.

  由不含抑制自由基的取代基的聚苯醚树脂组成的可固化组合物与聚乙烯不饱和化合物（如聚（双酚 A 富马酸酯）或二乙烯基苯）以及可选择的液态可聚合不饱和单乙烯基单体（如苯乙烯）相结合，并在可选择的催化剂作用下固化，从而比现有技术更快地生成交联互聚合物。 在固化前，组合物可与阻燃剂、增强填料和/或抗冲改性剂相结合。
• High strength composite
  申请人：AlliedSignal Inc.

  公开号：EP0658589A1

  公开（公告）日：1995-06-21

  An article made from at least one network of high strength fibers and a matrix composition that includes a vinyl ester and diallyl phthalate. Preferably, the article is made from at least one prepreg element which includes at least two adjacent layers of the high strength fiber network in the vinyl ester-containing matrix composition. The prepreg element is made by applying a mixture of vinyl ester, diallyl phthalate and a carbon-carbon saturated solvent to the high strength fiber network.

  一种由至少一层高强度纤维网和一种含有乙烯基酯和邻苯二甲酸二烯丙酯的基体组合物制成的制品。该制品最好由至少一个预浸件制成，该预浸件包括含乙烯基酯基体组合物中至少两层相邻的高强度纤维网。预浸料元件是通过将乙烯基酯、邻苯二甲酸二烯丙酯和碳碳饱和溶剂的混合物涂抹在高强度纤维网上制成的。
• Radically curable resin compositions
  申请人：DSM IP Assets B.V.

  公开号：EP1586596A1

  公开（公告）日：2005-10-19

  The present invention relates to resin compositions for radical curing comprising a component (I) containing reactive carbon-carbon unsaturations and a component (II) containing XH-groups, with X not being C or O., which resin compositions (a) are substantially free of photoinitiators; (b.) have an average number of reactive carbon-carbon unsaturations of component (I) equal to or higher than 2; (c) have an average number of XH-groups of component (II) equal to or higher than 2; (d) whereby at least one of the average numbers of (b) and (c) is higher than 2; (e) and at most 5 mol% of the reactive unsaturations is capable of undergoing homopolymerisation; (f) respectively is present in the form of a mono-ene functional alkylene; and (g) the molar ratio of the XH-groups and of the reactive unsaturations is in the range of from 4 : 1 to 1 : 4. The present invention also relates to processes for curing such resin compositions, in particular by cold curing. And finally, the present invention also relates to a new process for the synthesis of Diels-Alder adducts of cyclopentadiene and a resin component containing telechelic carbon-carbon unsaturation. The resin compositions are capable of providing constructive materials with tack-free surfaces by fast, and tunable, radical curing, and without any problems of so-called oxygen inhibition. Suitable applications are in chemical anchoring, roofing, flooring, (re)-lining, SMCs and BMCs.

  本发明涉及用于自由基固化的树脂组合物，该树脂组合物包括含有活性碳-碳不饱和基的组分(I)和含有XH-基团的组分(II)，其中X不是C或O、这些树脂组合物 (a) 基本上不含光引发剂； (b.组分（I）中活性碳-碳不饱和基的平均数量等于或高于 2； (c) 组分（II）中 XH 基的平均数量等于或高于 2； (d) 其中(b)和(c)的平均数量中至少有一个高于 2；(e) 反应性不饱和物最多有 5 摩尔%能够发生均聚合反应； (f) 分别以单烯烃官能团烯烃的形式存在；以及 (g) XH-基团和反应性不饱和物的摩尔比在 4 ：1 至 1 : 4 的范围内。 本发明还涉及此类树脂组合物的固化工艺，尤其是冷固化工艺。最后，本发明还涉及一种合成环戊二烯的 Diels-Alder 加合物和含有远志碳-碳不饱和树脂成分的新工艺。 这种树脂组合物能够通过快速、可调的自由基固化提供表面无粘性的结构材料，而且不存在所谓的氧抑制问题。适用于化学锚固、屋顶、地板、（再）衬里、SMC 和 BMC。
• Polyester resin compositions with reduced emission of volatile organic compounds
  申请人：DSM IP Assets B.V.

  公开号：EP1621567A1

  公开（公告）日：2006-02-01

  Thermally curable resin composition, having shrink-controlled properties and being suitable for use in sheet moulding compounds and bulk moulding compounds (SMCs and BMCs) comprising, inter alia (a) an unsaturated polyester; (b) an alkenyl aromatic monomer; (c) a low profile additive; (d) a peroxide initiator; (e) a thickening agent; (f) fibrous reinforcement material; and optionally one or more components selected from the group of (g) mould release agents; (h) wetting and viscosity reducing agents; and (i) fillers, wherein the composition also comprises a uret dione diisocyanate, in an amount of at least 0,2-1,0% by weight relative to the total weight of components (a), (b) and (c) of the resin composition. The resin compositions according to the invention in particular have a low emission of volatile organic compounds (VOC). More particularly, the resin compositions have excellent Class A properties. The present invention also relates to low profile additives (LPAs) wherein a uret dione diisocyanate is chemically attached through one or both of its reactive side-chain isocyanate groups to one or more of the OH-, NH2-, or COOH- groups of a component already having LPA properties. Finally, the present invention relates to low-VOC products and parts produced from the SMCs and BMCs according to the invention.

  热固化树脂组合物，具有收缩控制特性，适用于片状模塑料和块状模塑料 （SMC 和 BMC），除其他外包括：(a) 不饱和聚酯；(b) 烯基芳香族单体；(c) 低剖面添加剂；(d) 过氧化物引发剂；(e) 增稠剂；(f) 纤维增强材料；(g) 脱模剂；(h) 润湿剂和降粘剂；(i) 填料，其中该组合物还包括脲基二酮二异氰酸酯，其含量至少为树脂组合物中组分(a)、(b) 和(c)总重量的 0.2-1.0%（重量百分比）。本发明的树脂组合物尤其具有低挥发性有机化合物（VOC）排放的特点。更特别的是，该树脂组合物具有优异的 A 级特性。本发明还涉及低剖面添加剂（LPA），其中脲基二酮二异氰酸酯通过其一个或两个反应性侧链异氰酸酯基团与已具有 LPA 性能的组分的一个或多个 OH-、NH2- 或 COOH-基团进行化学连接。最后，本发明涉及用本发明的 SMC 和 BMC 生产的低 VOC 产品和部件。
• Polymerisation initiators, polymerisable compositions, and uses thereof for bonding low surface energy substrates
  申请人：LOCTITE (R&D) LIMITED

  公开号：US20030226472A1

  公开（公告）日：2003-12-11

  Quaternary boron salts are used as initiators of polymerisation in adhesive compositions for bonding low surface energy substrates such as polyolefins. The quaternary boron salts are of the formula I 1 wherein R 1 is C 1 -C 10 alkyl, R 2 , R 3 and R 4 , which may be the same or different, are, C 1 -C 10 alkyl or C 3 -C 10 cycloalkyl, phenyl, or phenyl-substituted C 1 -C 10 alkyl or C 3 -C 10 cycloalkyl, provided that any two of R 1 -R 4 may optionally be part of a carbocyclic ring, and M + is a metal ion or a quaternary ammonium ion. When M + is a quaternary ammonium ion, the initiator may be used in a two-part composition having a (meth)acrylate monomer in both parts and the initiator compound in one part, the two parts being in a weight ratio of about 1:1. Particular examples of initiator compounds include sodium tetraethyl borate, lithium tetraethyl borate, lithium phenyl triethyl borate, tetramethylammonium phenyl triethyl borate, and tetra methyl ammonium phenyl tri-n-butyl borate, the last-mentioned of which is a novel compound.

  季硼酸盐可用作粘合剂组合物中的聚合引发剂，用于粘合聚烯烃等低表面能基材。季硼酸盐的化学式为 I 1 其中 R 1 是 C 1 -C 10 烷基、 R 2 , R 3 和 R 4 可以相同或不同，它们是 C 1 -C 10 烷基或 C 3 -C 10 环烷基、苯基或苯基取代的 C 1 -C 10 烷基或 C 3 -C 10 环烷基，条件是 R 1 -R 4 可选择成为碳环的一部分，以及 M 为金属离子或季铵盐离子； 是金属离子或季铵盐离子。 当 M 是季铵离子时 为季铵盐离子时，引发剂可用于两部分组成的组合物中，其中两部分为（甲基）丙烯酸酯单体，一部分为引发剂化合物，两部分的重量比约为 1:1。 引发剂化合物的具体例子包括四乙基硼酸钠、四乙基硼酸锂、苯基三乙基硼酸锂、苯基三乙基硼酸四甲基铵和苯基三正丁基硼酸四甲基铵，其中最后提到的苯基三正丁基硼酸四甲基铵是一种新型化合物。