(((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(bis(4-(trifluoromethyl)phenyl)phosphane)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(bis(4-(trifluoromethyl)phenyl)phosphane)
• 英文别名: [(4R,5R)-5-[bis[4-(trifluoromethyl)phenyl]phosphanylmethyl]-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-bis[4-(trifluoromethyl)phenyl]phosphane
• 化学式: C₃₅H₂₈F₁₂O₂P₂
• 分子量: 770.5
• InChiKey: IWUVZYAJPOAIGF-KYJUHHDHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  51
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  14

文献信息

• Methods of Using Homogenous Rhodium Catalysts with N-Heterocyclic Carbene Ligands for the Hydroformylation of Olefins and Substituted Olefins
  申请人：Lyondell Chemical Technology, L. P.

  公开号：US20160068458A1

  公开（公告）日：2016-03-10

  A method of using homogenous rhodium catalysts comprising N-heterocyclic carbene ligands for the hydroformylation of olefins and substituted olefins is provided. In some aspects, the methods provided herein relate to the hydroformylation of allyl alcohol to 4-hydroxybutaldehyde in the presence of a rhodium catalyst which contains one or more N-heterocyclic carbene ligands of the formula: wherein R 1 , R 2 , R 3 , and R 4 are defined herein.
• US9765005B2
  申请人：——

  公开号：US9765005B2

  公开（公告）日：2017-09-19