1-Diazenylanthracene-9,10-dione

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-Diazenylanthracene-9,10-dione
• 化学式: C₁₄H₈N₂O₂
• 分子量: 236.22
• InChiKey: SSASYCDOBAXKNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.4
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• [EN] ANTHRAQUINONE AZO DYES<br/>[FR] COLORANTS ANTHRAQUINONE-AZOÏQUES
  申请人：HUNTSMAN ADV MAT SWITZERLAND

  公开号：WO2013182391A1

  公开（公告）日：2013-12-12

  The present invention relates to azo dyes of the formula (1), wherein R1 is hydrogen or hydroxy, R2 is hydrogen or hydroxy, at least one of the radicals R1 and R2 being hydroxy, R3 is hydrogen, cyano, nitro or halogen, R4 is hydrogen, cyano, nitro or halogen, D represents a radical of the formula (2) or (3), wherein R5 denotes C1-C12alkyl, C1-C12hydroxyalkyl, C1-C12alkoxyalkyl, C2-C12alkenyl, C6-C30aryl or C7-C36aralkyl and R6 and R7, each independently of the other, is hydrogen, C1-C12alkyl, C1-C12hydroxyalkyl, C1C12alkoxyalkyl, C6-C30aryl or C7-C36aralkyl, with the proviso that the compound of formula (1) is excluded, wherein R1 is hydrogen, R2 is hydroxy, R3 and R4 is hydrogen and D is the radical of formula (2) wherein R5 is ethyl, and to the use of those dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.

  本发明涉及式（1）的偶氮染料，其中R1是氢或羟基，R2是氢或羟基，R1和R2中至少有一个是羟基，R3是氢、氰基、硝基或卤素，R4是氢、氰基、硝基或卤素，D代表式（2）或（3）的基团，其中R5表示C1-C12烷基、C1-C12羟基烷基、C1-C12烷氧基烷基、C2-C12烯基、C6-C30芳基或C7-C36芳基烷基，R6和R7分别独立于对方，是氢、C1-C12烷基、C1-C12羟基烷基、C1-C12烷氧基烷基、C6-C30芳基或C7-C36芳基烷基，但式（1）的化合物除外，其中R1是氢、R2是羟基、R3和R4是氢，D是式（2）中R5为乙基的基团，以及在染色或印花半合成或合成疏水纤维材料中使用这些染料混合物。
• Anthraquinone Azo Dyes
  申请人：Huntsman International LLC

  公开号：US20150096132A1

  公开（公告）日：2015-04-09

  The present invention relates to azo dyes of the formula (1), wherein R 1 is hydrogen or hydroxy, R 2 is hydrogen or hydroxy, at least one of the radicals R 1 and R 2 being hydroxy, R 3 is hydrogen, cyano, nitro or halogen, R 4 is hydrogen, cyano, nitro or halogen, D represents a radical of the formula (2) or (3), wherein R 5 denotes C 1 -C 12 alkyl, C 1 -C 12 hydroxyalkyl, C 1 -C 12 alkoxyalkyl, C 2 -C 12 alkenyl, C 6 -C 30 aryl or C 7 -C 36 aralkyl and R 6 and R 7 , each independently of the other, is hydrogen, C 1 -C 12 alkyl, C 1 -C 12 hydroxyalkyl, C 1 C 12 alkoxyalkyl, C 6 -C 30 aryl or C 7 -C 36 aralkyl, with the proviso that the compound of formula (1) is excluded, wherein R 1 is hydrogen, R 2 is hydroxy, R 3 and R 4 is hydrogen and D is the radical of formula (2) wherein R 5 is ethyl, and to the use of those dye mixtures in the dyeing or printing of semi-synthetic or synthetic hydrophobic fibre materials.

  本发明涉及式（1）的偶氮染料，其中R1为氢或羟基，R2为氢或羟基，R1和R2中至少有一个为羟基，R3为氢、氰基、硝基或卤素，R4为氢、氰基、硝基或卤素，D代表式（2）或（3）的基团，其中R5表示C1-C12烷基、C1-C12羟基烷基、C1-C12烷氧基烷基、C2-C12烯基、C6-C30芳基或C7-C36芳基烷基，R6和R7分别独立于对方，为氢、C1-C12烷基、C1-C12羟基烷基、C1-C12烷氧基烷基、C6-C30芳基或C7-C36芳基烷基，但式（1）的化合物除外，其中R1为氢，R2为羟基，R3和R4为氢，D为式（2）中R5为乙基的基团，以及在染色或印花半合成或合成疏水纤维材料中使用这些染料混合物。
• Anthraquinone-azo dyes
  申请人：Tzikas Athanassios

  公开号：US20050182247A1

  公开（公告）日：2005-08-18

  The present invention relates to an azo dye of formula I, II or III: (formula I, II or III); wherein R 1 and R 2 are each independently of the other one or more divalent groups selected from alkylene, arylene, aralkylene and cycloalkylene, which may be interrupted by —O—, —S—, —NH—, —NR 8 —, —COO—, —CONH— or —CONR 9 —, wherein R 8 and R 9 are alkyl or aryl, X is —O— or —NH—, R 3 is —CN or —CONH 2 , R 4 is methyl or trifluoromethyl and R 5 , R 6 , R 7 and R 8 are each independently of the others hydrogen, halogen or —CN, to a process for the preparation thereof and to the use thereof in a method of producing mass-coloured plastics or polymeric colour particles.

  本发明涉及一种公式I、II或III的偶氮染料：（公式I、II或III）其中，R1和R2各自独立地选自可以被—O—、—S—、—NH—、—NR8—、—COO—、—CONH—或—CONR9—中断的烷基、芳基、芳基烷基和环烷基中的一个或多个二价基团，其中R8和R9为烷基或芳基，X为—O—或—NH—，R3为—CN或—CONH2，R4为甲基或三氟甲基，而R5、R6、R7和R8各自独立地为氢、卤素或—CN。本发明还涉及一种制备该染料的方法以及在生产质量着色塑料或聚合色粒子的方法中使用该染料的用途。
• Cyanoborate, Fluoroalkylphosphate, Fluoroalkylborate or Imide Dyes
  申请人：Ignatyev Nikolai (Mykola)

  公开号：US20080275224A1

  公开（公告）日：2008-11-06

  The present invention relates to dyes of the general formula CAT + Y − (I), where Y − is an anion selected from the group of the cyanoborates, fluoroalkylphosphates, fluoroalkylborates or imidates and CAT + is a cation selected from the group of the azine, xanthene, polymethine, styryl, azo, tetrazolium, pyrylium, benzopyrylium, thiopyrylium, benzothiopyrylium, thiazine, oxazine, triarylmethane, diarylmethane, methine, acridine, quinoline, isoquinoline or quaternary azafluorenone dyes, for colouring plastics and plastic fibres, for the preparation of flexographic printing inks, as ball-point pen pastes, as stamp ink, for colouring leather and paper, for use in data acquisition systems, reprography, in ink microfilters, in photogalvanics, laser technology and the photo industry.

  本发明涉及一般公式CAT+Y-（I）的染料，其中Y-是从氰硼酸盐、氟烷基磷酸盐、氟烷基硼酸盐或咪唑盐组中选择的阴离子，CAT+是从吖嗪、黄色素、聚甲烯、苯乙烯、偶氮、四唑、吡啶杂环、苯并吡喃杂环、硫吡喃杂环、苯并硫吡喃杂环、噻吩、噁吩、三芳基甲烷、二芳基甲烷、甲烯、花菁、喹啉、异喹啉或季铵氮杂花菁染料组中选择的阳离子，用于染色塑料和塑料纤维，用于制备凹版印刷油墨，作为圆珠笔浆料、邮票墨水，用于染色皮革和纸张，用于数据采集系统、复印、油墨微滤器、光电镀、激光技术和照相产业。
• POLYMERIC DYES
  申请人：Cremer Christian

  公开号：US20100192312A1

  公开（公告）日：2010-08-05

  A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C 1 -C 18 alkylene, C 2 -C 12 alkenylene, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene, —C 5 -C 10 arylene-(C 1 -C 10 alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, SO 2 , C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or T is C 3 -C 18 alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, —SO 2 —, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or is CO; (CH 2 CH 2 —O) 1-5 ; COO; N(R 1 ); CON(R 1 ); O; S; SO; SO 2 ; R 1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.

  一种高度交联的聚硅氧烷染料，包括至少10个硅原子，其中至少有一个公式（I）的基团，其开放的硅键分别与氧原子相连，开放的O键与聚硅氧烷中的硅原子相连，其中T是直接键或有机间隔基团，例如C1-C18烷基，C2-C12烯基，C5-C10环烷基，C5-C10芳基，-C5-C10芳基-(C1-C10烷基)-，每个基团都可以通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，SO2，C5-C10环烷基，C5-C10芳基端盖连接到染料；或T是C3-C18烷基中断，并且可以通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，-SO2-，C5-C10环烷基，C5-C10芳基端盖连接到染料；或是CO;（CH2CH2-O）1-5; COO; N（R1）; CON（R1）; O; S; SO; SO2; R1是氢; 未取代或取代的，直链或支链，单环或多环，中断或未中断的C1-C14烷基; C2-C14烯基; C6-C10芳基; C6-C10芳基-C1-C10烷基; 或C5-C10烷基（C5-C10芳基）;染料是有机染料的残基，用于有机材料的染色，例如角蛋白含量的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺。