1',3',3'-三甲基螺环-8-硝基(2H-1-苯并吡喃-2',2'-吲哚啉) | 5150-50-5

• 物质功能分类: 医药中间体 - 杂环化合物 - 吡喃类化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 中文名称: 1',3',3'-三甲基螺环-8-硝基(2H-1-苯并吡喃-2',2'-吲哚啉)
• 中文别名: 1,3,3-三甲基螺环-8-硝基(2H-1-苯并吡喃-2,2-吲哚啉)
• 英文名称: s.F.
• 英文别名: Spiro-<2H-1-benzopyran-2,2'-1',3',3'-trimethyl-8-nitro-indolin>；8'-Nitro-1,3,3-trimethyl-indolin-2-spiro-2'-<2H-1>benzopyran；8'-Nitro-1,3,3-trimethyl-indolin-2-spiro-2'-<2H-1>benzopyran, 1',3',3'-Trimethyl-8-nitro-2H-1-benzopyran<2-spiro-2'>indolin；1',3',3'-Trimethyl-8-nitro-2H-chromen-2-spiro-2'-indolin；1',3'-dihydro-1',3',3'-trimethyl-8-nitrospiro(2H-1-benzopyran-2,2'-[2H]indole)；1',3',3'-trimethyl-8-nitro-1',3'-dihydro-spiro[chromene-2,2'-indole]；1',3',3'-Trimethyl-8-nitrospiro(2H-1-benzopyran-2,2'-indoline)；1',3',3'-trimethyl-8-nitrospiro[chromene-2,2'-indole]
• CAS: 5150-50-5
• 化学式: C₁₉H₁₈N₂O₃
• 分子量: 322.364
• InChiKey: AZZVYIDATNYVSN-UHFFFAOYSA-N

物化性质

• 熔点：
  148 °C
• 沸点：
  460.98°C (rough estimate)
• 密度：
  1.2336 (rough estimate)
• 稳定性/保质期：
  在常温常压下保持稳定，应避免与不相容的材料接触。

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  58.3
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 安全说明：
  S24/25
• 海关编码：
  29349990,2934999090

反应信息

• 作为产物：
  描述：

  2-Nitro-6-[2-[1,3,3-trimethyl-1,3-dihydro-indol-(2Z)-ylidene]-eth-(E)-ylidene]-cyclohexa-2,4-dienone 以 乙醇 为溶剂， 生成 1',3',3'-三甲基螺环-8-硝基(2H-1-苯并吡喃-2',2'-吲哚啉)
  参考文献：
  名称：

  1-octadecyl- and 3,3-diphenyl-substituted photochromic indolinospirochromenes

  摘要：

  DOI：

  10.1007/bf00475389

文献信息

• Synthetic resin laminate having both polarization characteristic and photochromism characteristic
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1162482A2

  公开（公告）日：2001-12-12

  A synthetic resin laminate having both phtochromism characteristic and polarization characteristic consisting essentially of two transparent synthetic resin layers, a resin layer having phtochromism characteristic and a resin layer having polarization characteristic interposed between said two transparent synthetic resin layers and an adhesive layer to adhere said resin layer having polarization characteristic to said one transparent synthetic resin layer, wherein said one transparent synthetic resin layer to contact said resin layer having phtochromism characteristic has a thickness of 50 µm or above and a retardation value of 150 nm or below, or 3000 nm or above.

  一种具有变色特性和偏振特性的合成树脂层压板，主要由两个透明合成树脂层、一个具有变色特性的树脂层和一个具有偏振特性的树脂层组成，所述两个透明合成树脂层之间有一个粘合层，用于将所述具有偏振特性的树脂层粘在所述一个透明合成树脂层上，其中与所述具有变色特性的树脂层接触的所述一个透明合成树脂层的厚度为 50 微米或以上，延迟值为 150 纳米或以下，或 3000 纳米或以上。
• A non-glaring laminated body, a coated non-glaring laminated body, a non-glaring material, and a method for producing the non-glaring material
  申请人：MGC Filsheet Co., Ltd.

  公开号：EP1916097A2

  公开（公告）日：2008-04-30

  [Problem to be solved] The present invention provides a non-glaring material having an excellent property to cut ultraviolet rays, and having an excellent appearance and optical property as well as easy producibility and processibility, and a method for producing the non-glaring material. [Means to solve the problem] A non-glaring laminated body consisting of two transparent plastic material layers, a polarizing film layer which is held between the two transparent plastic material layers, and a synthetic adhesive layer which adheres the plastic material layer to the polarizing film layer, wherein at least one of the adhesive layers includes a fluorescent whitening agent and an ultraviolet ray absorber.

  [有待解决的问题］ 本发明提供了一种具有优异的紫外线切割性能、优异的外观和光学性能以及易于生产和加工的不刺眼材料，以及生产这种不刺眼材料的方法。 [解决问题的方法］ 一种不刺眼层压体，由两层透明塑料材料层、夹在两层透明塑料材料层之间的偏光膜层和将塑料材料层粘在偏光膜层上的合成粘合剂层组成，其中至少一层粘合剂层包括荧光增白剂和紫外线吸收剂。
• Organic light-emitting display apparatus
  申请人：Samsung Display Co., Ltd.

  公开号：US10249693B2

  公开（公告）日：2019-04-02

  An organic light-emitting display apparatus for selectively realizing circular polarization according to external light conditions, including a substrate; an organic light-emitting device on the substrate; a sealing member on the organic light-emitting device; a phase retardation layer on a surface of the substrate, the organic light-emitting device, or the sealing member; and a linear polarization layer on another surface of the substrate, the organic light-emitting device, or the sealing member, wherein the linear polarization layer is located to be closer to a source of external light than the phase retardation layer, and wherein the linear polarization layer comprises a photochromic material.

  一种根据外部光照条件选择性实现圆偏振的有机发光显示装置，包括基板；基板上的有机发光器件；有机发光器件上的密封部件；基板、有机发光器件或密封部件的一个表面上的相位延迟层，以及基板、有机发光器件或密封部件的另一个表面上的线性偏振层；以及位于基板、有机发光器件或密封部件的另一表面上的线性偏振层，其中线性偏振层的位置比相位延迟层更靠近外部光源，并且线性偏振层包括光致变色材料。
• TRANSPARENT SYNTHETIC RESIN LAMINATE HAVING PHOTOCHROMISM
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1273935B1

  公开（公告）日：2004-06-30
• PLASTIC MOLDED PRODUCT HAVING PHOTOCHROMIC CHARACTERISTICS AND/OR POLARIZING CHARACTERISTICS
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1394595B1

  公开（公告）日：2013-05-01