1,1'-二烯丙基-[4,4'-联吡啶]-1,1'-二鎓 | 46903-42-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 1,1'-二烯丙基-[4,4'-联吡啶]-1,1'-二鎓
• 英文名称: 1,1'-Diallyl-4,4'-bipyridylium-Dikation
• 英文别名: 1,1'-Diallyl-[4,4'-bipyridine]-1,1'-diium；1-prop-2-enyl-4-(1-prop-2-enylpyridin-1-ium-4-yl)pyridin-1-ium
• CAS: 46903-42-8
• 化学式: C₁₆H₁₈N₂
• 分子量: 238.332
• InChiKey: NMESRSUVCRMIIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  7.8
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• [EN] SELF-ASSEMBLED POLYCATIONIC CYCLOPHANE<br/>[FR] CYCLOPHANE POLYCATIONIQUE AUTO-ASSEMBLÉ
  申请人：UNIV CORUNA

  公开号：WO2020119983A1

  公开（公告）日：2020-06-18

  The present invention relates to a self-assembled polycationic cyclophane of formula (I), wherein: each R1 is a single bond, O, NH, CH2, CH2NH, CONH and CSNH; each R2 is H, (C1-C6) alkyl, (C1-C6) alkenyl, (C1-C6) alkynyl and (C6-C12) aryl; each R3 is (C1-C6) alkylene, (C1-C6) alkenylene, (C1-C6) alkynylene and (C6-C12) arylene; each R4 is H, (C1-C6) alkyl, (C1-C6) alkenyl, (C1-C6) alkynyl, (C6-C12) aryl, -O- (C1-C6) alkyl, OH, N(R6)2, SH, F, Cl, Br, I, P(R6)2, CHO, -COOR6, CH2OR6, OR6, NHCOR6, CONHR6, CON(R6)2, N3, NO2, B(OR6)2, CN and PO(R6)2; each R6 is independently selected from the group consisting of H, (C1-C6) alkyl and (C6-C12) aryl; X- is an organic or inorganic negatively charged ion selected from the group consisting of X1 - and X2 -; X1 - is selected from the group consisting of CIO-, BF4 -, CF3CO2 - and PF6 - and X2 - is selected from the group consisting of Cl-, Br-, I-, and NO3 -. Particularly a self-assembled polycationic cyclophane of formula (I) wherein each R4 is independently selected from the group consisting of H, (C1-C6) alkyl, (C1-C6) alkenyl, (C1-C6) alkynyl, (C6-C12) aryl, -O- (C1-C6) alkyl, OH, SH, F, Cl, Br, I, CHO, N3, NO2 and CN. It also relates to processes for its preparation and its use for sequestering, chromatographic separation and detecting the presence of aromatic compounds from a sample.

  本发明涉及一种公式（I）的自组装多阳离子环烷，其中：每个R1是单键，O，NH，CH2，CH2NH，CONH和CSNH；每个R2是H，（C1-C6）烷基，（C1-C6）烯基，（C1-C6）炔基和（C6-C12）芳基；每个R3是（C1-C6）亚烷基，（C1-C6）亚烯基，（C1-C6）亚炔基和（C6-C12）芳亚基；每个R4是H，（C1-C6）烷基，（C1-C6）烯基，（C1-C6）炔基，（C6-C12）芳基，-O-（C1-C6）烷基，OH，N（R6）2，SH，F，Cl，Br，I，P（R6）2，CHO，-COOR6，CH2OR6，OR6，NHCOR6，CONHR6，CON（R6）2，N3，NO2，B（OR6）2，CN和PO（R6）2；每个R6是从H，（C1-C6）烷基和（C6-C12）芳基组成的群体中独立选择的；X-是从X1-和X2-组成的群体中选择的有机或无机负离子；X1-从CIO-，BF4-，CF3CO2-和PF6-组成的群体中选择，X2-从Cl-，Br-，I-和NO3-组成的群体中选择。特别是一种公式（I）的自组装多阳离子环烷，其中每个R4是独立选择的H，（C1-C6）烷基，（C1-C6）烯基，（C1-C6）炔基，（C6-C12）芳基，-O-（C1-C6）烷基，OH，SH，F，Cl，Br，I，CHO，N3，NO2和CN。它还涉及其制备方法及其用于从样品中固定、色谱分离和检测芳香化合物存在的用途。
• CRYSTALLINE BIPYRIDINIUM RADICAL COMPLEXES AND USES THEREOF
  申请人：NORTHWESTERN UNIVERSITY

  公开号：US20150191470A1

  公开（公告）日：2015-07-09

  Described herein are methods of generating 4,4′-bipyridinium radical cations (BIPY •+ ), and methods for utilizing the radical-radical interactions between two or more BIPY •+ radical cations that ensue for the creation of novel materials for applications in nanotechnology. Synthetic methodologies, crystallographic engineering techniques, methods of physical characterization, and end uses are described.

  本文描述了生成4,4′-联吡啶正离子（BIPY•+）的方法，以及利用两个或更多BIPY•+正离子之间的自由基-自由基相互作用来创造用于纳米技术应用的新材料的方法。描述了合成方法、晶体工程技术、物理特性表征方法和最终用途。
• Process for Preparing Substituted 2-Nitrobiphenyls
  申请人：Korte Alexander

  公开号：US20110319665A1

  公开（公告）日：2011-12-29

  The present invention relates to a process for preparing substituted 2-nitrobiphenyls and to specific 2-nitrobiphenyls. The invention further relates to a process for preparing 2-aminobiphenyls from such 2-nitrobiphenyls and to a process for preparing (het)arylamides of such 2-aminobiphenyls.

  本发明涉及一种制备取代2-硝基联苯的方法，以及具体的2-硝基联苯。本发明还涉及一种从这些2-硝基联苯制备2-氨基联苯的方法，以及制备这些2-氨基联苯的（杂）芳基酰胺的方法。
• Electroactive ionic liquids and surface-modified substrates containing them
  申请人：Centre National de la Recherche Scientifique (CNRS)

  公开号：US10910634B2

  公开（公告）日：2021-02-02

  The present invention relates an electro-active polymeric ionic liquid including imidazolium-based molecules, said imidazolium-based molecule comprising each at least: —one imidazolium moiety associated with a negatively-charged counter-ion, and —one reducible group selected from: Formula (IV), —an anthraquinone derivative of formula (IV): with R1 representing a hydrogen atom or a C1-C6-alkyl group, —a viologen group, and —a metallocene reducible group such as a cobaltocene group.

  本发明涉及一种电活性聚合物离子液体，包括咪唑基分子，所述咪唑基分子至少包括： -个与带负电荷的反离子相关联的咪唑分子，以及 -个选自式（IV）的可还原基团； -个式（IV）的蒽醌衍生物：其中 R1 代表氢原子或 C1-C6 烷基； -个紫胶基团；以及 -个茂金属可还原基团，如茂金属钴基团。
• Mixed-valence crystal superstructures
  申请人：Northwestern University

  公开号：US11254678B2

  公开（公告）日：2022-02-22

  Disclosed herein is a mixed-valence crystal superstructure assembled from a 2:1 host-guest inclusion complex. The complex comprises an aromatic guest encircled by two macrocycles, wherein the complex has an empirical charge greater than 0 and less than 1. Methods of preparing the compositions described herein are also disclosed.

  本文公开了一种由 2:1 主-客体包合复合物组装而成的混价晶体上层结构。该复合物包括由两个大环包围的芳香族客体，其中该复合物的经验电荷大于 0 小于 1。 本文还公开了制备所述组合物的方法。