1,1'-联金刚烷-3,3'-二胺 | 18220-68-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1,1'-联金刚烷-3,3'-二胺
• 英文名称: 3,3'-Diamino-1,1'-biadamantyl
• 英文别名: 3-(3-Amino-1-adamantyl)adamantan-1-amine
• CAS: 18220-68-3
• 化学式: C₂₀H₃₂N₂
• 分子量: 300.487
• InChiKey: SOKRCBPOBAYQBS-UHFFFAOYSA-N

物化性质

• 熔点：
  185-187 °C
• 沸点：
  379.7±10.0 °C(Predicted)
• 密度：
  1.217±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  8.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921300090

反应信息

• 作为产物：
  描述：

  3,3'-Dibrom-1,1'-biadamantan 在 氨 作用下， 生成 1,1'-联金刚烷-3,3'-二胺
  参考文献：
  名称：

  抗病毒药。2.与1-金刚烷胺有关的化合物的构效关系。

  摘要：

  DOI：

  10.1021/jm00288a019

文献信息

• CAGE-SHAPED CYCLOPENTANOIC DIANHYDRIDE, METHOD FOR PRODUCTION THEREOF, AND POLYIMIDE
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20140114027A1

  公开（公告）日：2014-04-24

  A cage 1,2,3,4-cyclopentanetetracarboxylic acid (1,3:2,4)-dianhydride compound represented by formula [1], and a polyimide obtained by condensing the compound with a diamine. With the compound, it is possible to provide a polyimide which shows no absorption in the ultraviolet region and is highly transparent to light, has high insulating properties, has improved heat resistance and processability, and has excellent solubility in organic solvents. (In formula [1], R 1 and R 2 each independently represents a hydrogen atom, a halogen atom, or a C 1-10 alkyl.)

  化学式为[1]的1,2,3,4-环戊烷四羧酸(1,3:2,4)-二酐化合物和通过该化合物与二胺缩合制得的聚酰亚胺。使用该化合物，可以提供一种聚酰亚胺，该聚酰亚胺在紫外线区域不吸收，并且对光高度透明，具有高绝缘性能，改善了耐热性和加工性，并且在有机溶剂中溶解性优异。(在公式[1]中，R1和R2各自独立地表示氢原子、卤素原子或C1-10烷基。)
• 1,1'-Diadamantyl carboxylic acids, medicaments containing such compounds and their use
  申请人：Eckhardt Matthias

  公开号：US20110269736A1

  公开（公告）日：2011-11-03

  The present invention relates to compounds defined by formula (I) wherein the group R is defined as in claim 1 , possessing valuable pharmacological activity. Particularly the compounds are inhibitors of 11 β-hydroxysteroid dehydrogenase (HSD) 1 and thus are suitable for treatment and prevention of diseases which can be influenced by inhibition of this enzyme, such as metabolic diseases.

  本发明涉及具有有价值的药理活性的公式（I）所定义的化合物，其中R基团如权利要求1所定义。特别地，这些化合物是11β-羟基类固醇脱氢酶（HSD）1的抑制剂，因此适用于治疗和预防可以通过抑制该酶而受到影响的疾病，例如代谢性疾病。
• Polymers prepared from 4,4'-bis-(2-(amino (halo) phenoxyphenyl) hexafluoroisopropyl) diphenyl ether
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317944A2

  公开（公告）日：1989-05-31

  The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(amino(halo)phenoxyphenyl)hexafluoroisopropyl]diphenyl ether.

  本申请涉及含氟聚酰亚胺、聚酰胺酸/酯、聚酰胺、加成聚酰亚胺和亚胺低聚物，它们具有低熔点、更好的溶解性、低介电常数、优异的热稳定性和热氧化稳定性，以及更好的加工特性。 这种应用产品的特点是它们来自 4,4'-双[2-（氨基（卤代）苯氧基苯基）六氟异丙基]二苯醚。
• Polymers prepared from 4,4'-bis-[2-(3,4-(dicarboxyphenyl) hexafluoroisopropyl] diphenyl ether dianhydride
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0317943A2

  公开（公告）日：1989-05-31

  The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(3,4-(dicarboxyphenyl)­hexafluoroisopropyl]diphenyl ether dianhydride.

  本申请涉及含氟聚酰亚胺、聚酰胺酸/酯、聚酰胺、加成聚酰亚胺和亚胺低聚物，它们具有低熔点、更好的溶解性、低介电常数、优异的热稳定性和热氧化稳定性，以及更好的加工特性。 这种应用产品的特点是它们来自 4,4'-双[2-(3,4-(二羧基苯基)六氟异丙基]二苯醚二酐。
• WINDOW FOR DISPLAY DEVICE AND DISPLAY DEVICE INCLUDING THE WINDOW
  申请人：Samsung Electronics Co., Ltd

  公开号：EP3040366A1

  公开（公告）日：2016-07-06

  A window for a display device including a plastic substrate having yield strain of greater than or equal to about 0.8% at about 85 degrees Celsius and 85% relative humidity and a hard coating layer disposed on at least one side of the plastic substrate.

  一种用于显示设备的窗口，包括在约 85 摄氏度和 85% 相对湿度条件下屈服应变大于或等于约 0.8% 的塑料基板，以及设置在塑料基板至少一侧的硬涂层。