1,2,4,5-四氯-3,6-二(异氰酸甲基)苯 | 16325-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2,4,5-四氯-3,6-二(异氰酸甲基)苯
• 英文名称: 1,4a-bis(isocyanatomethyl)-2,3,5,6-tetrachlorobenzene
• 英文别名: 1,4-bis(isocyanatomethyl)-2,3,5,6-tetrachlorobenzene；1,4-di(isocyanatomethyl)-2,3,5,6-tetrachlorobenzene；Benzene, 1,2,4,5-tetrachloro-3,6-bis(isocyanatomethyl)-；1,2,4,5-tetrachloro-3,6-bis(isocyanatomethyl)benzene
• CAS: 16325-38-5
• 化学式: C₁₀H₄Cl₄N₂O₂
• 分子量: 325.966
• InChiKey: UXIKMAOGSBQRNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2929109000

反应信息

• 作为产物：
  描述：

  1,4-二氨基甲基-2,3,5,6-四氯苯 、 光气 生成 1,2,4,5-四氯-3,6-二(异氰酸甲基)苯
  参考文献：
  名称：

  ENDGLAENDER F.; FUENTEN H. AUS DER; STEFFEN K.-D.; WEISGERBER G.; ZOCHE G+, CHEM.-ZTG., 1979, 103, NO 1, 9-17

  摘要：

  DOI：

文献信息

• PHOTOCHROMIC COMPOSITION AND OPTICAL ARTICLE USING PHOTOCHROMIC COMPOSITION
  申请人：Tokuyama Corporation

  公开号：EP2700694A1

  公开（公告）日：2014-02-26

  To provide a photochromic composition which functions as an adhesive layer for bonding two optical sheets that are formed of a polycarbonate resin or the like, so that a laminate that is obtained by bonding two optical sheets with the composition being sandwiched therebetween has excellent adhesion, heat resistance and photochromic properties. In particular, to provide a photochromic composition which is capable of forming an adhesive layer that is not decreased in the adhesion between the optical sheets even in cases where the adhesive layer is in contact with hot water. Provided is a photochromic composition which contains a urethane polymer having a polymerizable group (component A) and a photochromic compound (component B).

  提供一种光致变色组合物，该组合物可用作粘合聚碳酸酯树脂或类似材料制成的两片光学薄膜的粘合层，从而使夹有该组合物的两片光学薄膜粘合而成的层压板具有优异的粘合性、耐热性和光致变色性能。特别是，提供一种光致变色组合物，该组合物能够形成粘合层，即使在粘合层与热水接触的情况下，光学薄膜之间的粘合力也不会降低。本发明提供了一种光致变色组合物，它包含一种具有可聚合基团的聚氨酯聚合物（成分 A）和一种光致变色化合物（成分 B）。
• ADHESIVE COMPOSITION, LAMINATE, AND OPTICAL ARTICLE INCLUDING SAID LAMINATE
  申请人：Tokuyama Corporation

  公开号：EP3495441A1

  公开（公告）日：2019-06-12

  To provide an adhesive composition capable of firmly bonding polymer sheets together, comprising: (I) 100 parts by mass of an end-unreactive urethane urea resin; and (III) 4.0 to 20 parts by mass of a polyisocyanate compound having at least two isocyanate groups in the molecule, wherein the polyisocyanate compound (III) contains (IIIA) a polyisocyanate compound having an isocyanate group bonded to secondary carbon and (IIIB) a polyisocyanate compound having 4 to 30 carbon atoms in the molecule other than the component (IIIA), and the amount of the component (IIIB) is 10 to 500 parts by mass based on 100 parts by mass of the component (IIIA).

  提供一种能够将聚合物片材牢固粘合在一起的粘合剂组合物，该组合物包括 (I) 100 份（按重量计）端非反应型聚氨酯脲树脂；和 (III) 4.0至20份（质量份）分子中至少有两个异氰酸酯基团的多异氰酸酯化合物，其中多异氰酸酯化合物（III）包含（IIIA）分子中具有与仲碳键合的异氰酸酯基团的多异氰酸酯化合物和（IIIB）分子中除组分（IIIA）外具有4至30个碳原子的多异氰酸酯化合物，组分（IIIB）的用量以100份（质量份）组分（IIIA）为基准，为10至500份（质量份）。
• AQUEOUS DISPERSION
  申请人：Covestro Deutschland AG

  公开号：EP3546493A1

  公开（公告）日：2019-10-02

  The invention relates to a polyurethane polymer-based aqueous dispersion and a method for preparing the same, a composition comprising the aqueous dispersion, use of the composition, and a coated article. The aqueous dispersion comprises a polyurethane polymer and water, wherein the polyurethane polymer is obtained by reacting a system comprising the following components: an isocyanate compound comprising a pentamethylene diisocyanate, wherein the amount of the pentamethylene diisocyanate is not less than 25 wt.% based on that the amount of the isocyanate compound is 100 wt.%; a polymer polyol having a number average molecular weight of not less than 400 g/mol, wherein the polymer polyol comprises a carbon dioxide-derived polyether carbonate polyol, the amount of which is not less than 40 wt.% based on that the amount of the polymer polyol is 100 wt.%; an amino compound having an amino functionality of greater than 1; and a compound comprising at least one isocyanate-reactive group and at least one ionic or potentially ionic hydrophilic group.

  本发明涉及一种基于聚氨酯聚合物的水性分散体及其制备方法、一种包含该水性分散体的组合物、该组合物的用途以及一种涂层制品。水性分散体由聚氨酯聚合物和水组成，其中聚氨酯聚合物是通过与包含以下成分的体系反应而得 到的：由五亚甲基二异氰酸酯组成的异氰酸酯化合物，其中五亚甲基二异氰酸酯的含量不低于 25 wt.%，而异氰酸酯化合物的含量为 100 wt.其中，聚合物多元醇包括二氧化碳衍生的聚醚碳酸酯多元醇，以聚合物多元醇的用量为 100 重量％计，其用量不小于 40 重量％；具有大于 1 的氨基官能度的氨基化合物；以及包含至少一个异氰酸酯反应基团和至少一个离子或潜在离子亲水基团的化合物。
• IONICALLY HYDROPHILIZED POLYISOCYANATES WITH IMPROVED DRYING
  申请人：Covestro Deutschland AG

  公开号：EP3599255A1

  公开（公告）日：2020-01-29

  The invention relates to a polyisocyanate mixture comprising a polyisocyanate component A) having aliphatically and/or cycloaliphatically bonded isocyanate groups and a polyisocyanate component B) having araliphatically and/or aromatically bonded isocyanate groups, characterized in that the polyisocyanate component A) comprises at least 0.85% by weight of sulfonate groups (calculated as SO3; molar weight = 80 g/mol) in chemically bonded form and the proportion of the polyisocyanate component B) is 7 to 43% by weight of the total amount of the components A) and B). The invention further relates to the use thereof and also coating compositions comprising the polyisocyanate mixture and also the substrates coated with these coating compositions.

  本发明涉及一种多异氰酸酯混合物，包括具有脂肪族和/或环脂肪族键合异氰酸酯基团的多异氰酸酯组分 A)和具有芳香族和/或芳香族键合异氰酸酯基团的多异氰酸酯组分 B)，其特征在于多异氰酸酯组分 A)包括至少 0.85%(重量)的磺酸基团(以 SO3 计算；摩尔重量 = 80 g/mol)以化学键形式结合，多异氰酸酯组分 B)的比例为组分 A)和 B)总量的 7%至 43%(重量)。本发明还涉及其用途、包含该多异氰酸酯混合物的涂料组合物以及涂有这些涂料组合物的基材。
• PRIMER COMPOSITION FOR OPTICAL ARTICLES, AND LAMINATE
  申请人：Tokuyama Corporation

  公开号：EP3640686A1

  公开（公告）日：2020-04-22

  This primer composition for optical articles is characterized by containing (A) a urethane prepolymer which is a reaction product of an aromatic polyisocyanate compound and a polyol compound, and which has a reactive group at an end, said reactive group being selected from among an isocyanate group and a hydroxyl group, (B) a light absorbing compound which has a maximum absorption wavelength within the range of from 320 nm to 650 nm (inclusive) and (C) an organic solvent which has a solubility parameter of 8 (cal/cm3)1/2 or more, while containing no active hydrogen.

  这种用于光学产品的底层涂料组合物的特点是含有 (A) 聚氨酯预聚物，它是芳香族多异氰酸酯化合物和多元醇化合物的反应产物，末端带有活性基团，所述活性基团可从异氰酸酯基团和羟基基团中选择、(B) 最大吸收波长在 320 纳米至 650 纳米（含）范围内的光吸收化合物；以及 (C) 溶解度参数为 8 (cal/cm3)1/2 或更高，但不含活性氢的有机溶剂。