1,2-苯二羧酸,4-氯-,盐(1:?)钠 | 3325-09-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2-苯二羧酸,4-氯-,盐(1:?)钠
• 英文名称: Disodium 4-chlorophthalate
• 英文别名: disodium;4-chlorophthalate
• CAS: 3325-09-5；74543-14-9
• 化学式: C8H3ClNa2O4
• 分子量: 244.54
• InChiKey: LWXGAQHPDMUTQE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -6.92
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Process for dimerization of aromatic halide compounds
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0318634A1

  公开（公告）日：1989-06-07

  A method of dehalogeno-dimerizing an aromatic halide compound substituted by at least one halogen atom substi­tuted on the aromatic ring using a palladium catalyst on support in the presence of water, a reducing agent and a halogen acceptor is disclosed. The method is characterized by using the palladium catalyst on support immersed in a hydrohalogenic acid prior to the dehalogeno-dimerization reaction.

  本发明公开了一种在水、还原剂和卤素受体存在下，使用载体上的钯催化剂使芳香环上被至少一个卤原子取代的芳香卤化物化合物脱卤二聚化的方法。该方法的特点是在进行脱卤二聚反应之前，将载体上的钯催化剂浸入氢卤酸中。
• Process for producing highly pure 3,3',4,4' - biphenyltetra- carboxylic acid or dianhydride thereof
  申请人：HITACHI, LTD.

  公开号：EP0421046A1

  公开（公告）日：1991-04-10

  Highly pure 3,3′,4,4′-biphenyltetracarboxylic acid (BPTA) and dianhydride thereof (BPDA) are produced by heating crude BPTA to give BPDA, treating the BPDA with hot water to give highly pure BPTA, and in the case of highly pure BPDA, heat treating the pure BPTA to give highly pure BPDA.

  高纯度的 3,3′,4,4′-联苯四羧酸（BPTA）及其二酸酐（BPDA）是通过加热粗 BPTA 得到 BPDA，用热水处理 BPDA 得到高纯度的 BPTA，如果是高纯度的 BPDA，则对纯 BPTA 进行热处理得到高纯度的 BPDA。
• PROCESS FOR PRODUCING BIPHENYLTETRACARBOXYLIC ACID
  申请人：JFE Chemical Corporation

  公开号：EP1801092A1

  公开（公告）日：2007-06-27

  A method for producing a biphenyltetracarboxylic acid is to perform dimerization of a bromophthalate under the presence of a palladium catalyst and at least one reducing agent selected from the group consisting of saccharides and aliphatic monoalcohols having at least two carbon atoms. By this production method, since a side reaction is suppressed, a biphenyltetracarboxylic acid useful as a starting material for a polyimide resin having superior heat resistance and mechanical properties can be obtained in higher yield than ever.

  一种生产联苯四羧酸的方法是在钯催化剂和至少一种还原剂的存在下，对溴邻苯二甲酸盐进行二聚反应，还原剂选自糖类和至少有两个碳原子的脂肪族一元醇。通过这种生产方法，由于抑制了副反应，因此可以获得比以往产量更高的联苯四羧酸，这种联苯四羧酸可用作具有优异耐热性和机械性能的聚酰亚胺树脂的起始原料。
• Process for dimerizing aromatic halogen compounds
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0409172B1

  公开（公告）日：1994-05-04
• Method for producing biphenyltetracarboxylic acid
  申请人：Mori Hiroaki

  公开号：US20090048462A1

  公开（公告）日：2009-02-19

  A method for producing a biphenyltetracarboxylic acid is to perform dimerization of a bromophthalate under the presence of a palladium catalyst and at least one reducing agent selected from the group consisting of saccharides and aliphatic monoalcohols having at least two carbon atoms. By this production method, since a side reaction is suppressed, a biphenyltetracarboxylic acid useful as a starting material for a polyimide resin having superior heat resistance and mechanical properties can be obtained in higher yield than ever.