1,3,3-三氯丁烷 | 15187-71-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1,3,3-三氯丁烷
• 英文名称: 1,3,3-trichloro-butane
• 英文别名: 2,2,4-trichloro-butane；1,3,3-Trichlor-butan；1,3,3-Trichlorbutan；1,3,3-Trichlorobutane
• CAS: 15187-71-0
• 化学式: C₄H₇Cl₃
• mdl: MFCD19232477
• 分子量: 161.459
• InChiKey: VHRSGZSWEJBMSI-UHFFFAOYSA-N

物化性质

• 熔点：
  -46 °C
• 沸点：
  156 °C
• 密度：
  1.2725 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氯乙烯 、 三氯乙烷 在 4-苯基吡啶 、 铜 作用下， 以 二甲基亚砜 为溶剂， 90.0 ℃ 、1.0 MPa 条件下， 反应 1.0h， 生成 1,3,3-三氯丁烷
  参考文献：
  名称：

  一种制备多卤代烃的方法及反应器

  摘要：

  本发明公开了一种制备多卤代烃的方法及反应器。该方法氯代烃与烯烃在配体、溶剂或无溶剂的存在下，于铜管反应器中反应制备多卤代烃，反应温度为25～100℃，反应温度为30～120℃，反应压力为0.5～2.5MPa，物料流速为0.1～3m/min，氯代烃和烯烃摩尔比为1～10:1。本发明具有工艺简单、反应条件温和、可连续操作、反应效率高的特点，可用于催化合成许多有价值的多卤代烃，比如CCl3CH2CHCl2、CCl3CH2CH2Cl、CCl3CH2CCl3、CCl3CH2CCl2CH3、CF3CCl2CH2CH2Cl、CF3CCl2CH2CCl3、CF3CH2ClCH2CCl3和CCl3CHClCH2CCl3等，上述化合物是HFC‑245fa、HFC‑365mfc、HFO‑1243zf、HFO‑1336mzz等重要的含氟商业品的中间体。

  公开号：

  CN114349594A

文献信息

• MIKTO-ARM BRANCHED POLYMERS
  申请人：COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION

  公开号：US20160375143A1

  公开（公告）日：2016-12-29

  The invention relates to branched polymer comprising a support moiety and at least three homopolymer chains each covalently coupled to and extending from the support moiety, wherein the at least three homopolymer chains include a cationic homopolymer chain, a hydrophilic homopolymer chain, and a hydrophobic homopolymer chain.

  本发明涉及一种分支聚合物，包括支撑基团和至少三条同源聚合物链，每条聚合物链都与支撑基团共价耦合并延伸出来，其中至少三条同源聚合物链包括阳离子聚合物链、亲水性聚合物链和疏水性聚合物链。
• Process for preparing glyphosate and glyphosate derivatives
  申请人：Monsanto Company

  公开号：EP0186647A1

  公开（公告）日：1986-07-02

  A process for preparing glyphosate and derivatives of related structure. A precursor primary or secondary amine, such as glycine, is condensed with a carbonyl compound, such as formylphosphonic acid or its acetais, and the condensation product is reduced to produce the desired product.

  一种制备草甘膦及相关结构衍生物的工艺。 前体伯胺或仲胺（如甘氨酸）与羰基化合物（如甲酰基膦酸或其乙酰基）缩合，缩合产物经还原生成所需的产品。
• Process for the preparation of glyphosate and glyphosate derivatives
  申请人：Monsanto Company

  公开号：EP0186648A1

  公开（公告）日：1986-07-02

  A process for preparing glyphosate and other secondary or tertiary amines of related structure in which a precursor primary or secondary amine, such as aminomethylphosphonic acid, is condensed with glyoxylic acid, glyoxal, or a related carbonyl compound, and the condensation product is reduced without isolation to produce the desired product.

  一种制备草甘膦和其他相关结构的仲胺或叔胺的工艺，在该工艺中，前体伯胺或仲胺（如氨甲基膦酸）与乙醛酸、乙二醛或相关的羰基化合物缩合，缩合产物在不分离的情况下被还原，生成所需的产物。
• Polyurethane biasable transfer members having improved moisture stability
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0690359A2

  公开（公告）日：1996-01-03

  The invention provides rolls, belts and other biasable members having at least one layer or coating of an elastomeric resilient polyurethane formed by reacting: (a) a polyisocyanate prepolymer comprising the reaction product of: (i) a saturated aliphatic polyisocyanate, a saturated cycloaliphatic polyisocyanate, or an aromatic polyisocyanate; and (ii) a polyol free of aliphatic unsaturation; and (b) a hardening mixture comprising: (i) a polyol of (a) (ii) or a diamine free of aliphatic unsaturation, or a mixture thereof; and, (ii)as a conductivity control agent for controlling the resistivity of the elastomeric polyurethane, from 0.001 to 5.0 weight percent, based on the total weight of the polyurethane, of an ammonium tetrahaloferrate salt having the formula:    wherein R, R¹, R and R³ are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, alkoxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, alkoxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; or wherein any two or more of R, R¹, R, or R³ can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, and X, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine. The biasable members find use in the transfer of electrostatographic toner images from a photoconductor to a final support sheet where the member electrically cooperates with a photoconductor to establish a directional force field therebetween.

  本发明提供的辊子、传送带和其他可偏置部件至少有一层或一层通过反应形成的弹性回弹聚氨酯涂层： (a) 多异氰酸酯预聚物，包括以下物质的反应产物 (i) 饱和脂肪族多异氰酸酯、饱和环脂族多异氰酸酯或芳香族多异 氰酸酯；和 (ii) 不含脂肪族不饱和度的多元醇；以及 (b) 一种硬化混合物，包括 (i) (a)(ii)的多元醇或不含脂肪族不饱和物的二胺，或它们的混合物；以及 (ii) 作为控制弹性聚氨酯电阻率的传导性控制剂，以聚氨酯总重量为基准，加入 0.001 至 5.0 重量百分数的四卤铁酸铵盐，其式如下 其中 R、R¹、R 和 R³ 相同或不同，且独立选自氢；具有 1 至 24 个碳原子的未取代烷基；具有 1 至 24 个碳原子的被一个或多个羟基、烷氧基、硝基、氰基、酮基或卤基取代的取代烷基；具有 3 至 7 个碳原子的环烷基； 具有 6 至 14 个碳原子的未取代芳基； 具有 6 至 14 个碳原子的被一个或多个羟基、烷氧基、氨基、硝基、氰基、酮基或卤素基取代的取代芳基；在烷基中具有 1 至 20 个碳原子、在芳基中具有 6 至 14 个碳原子的烷芳基； 在烷基中具有 1 至 4 个碳原子、在芳基中具有 6 至 14 个碳原子的芳烷基； 或其中任意两个或多个 R、R¹、R 或 R³ 可相互连接，形成 5 至 14 个成员的饱和或不饱和环系统，且 X（可以相同或不同）选自氟、氯、溴或碘。 这种可偏置构件可用于将电致发光调色剂图像从感光导体转移到最终支持片材上，在此过程中，构件与感光导体电性配合，在两者之间建立定向力场。
• Polyurethane biasable transfer members
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0690360A2

  公开（公告）日：1996-01-03

  The invention provides rolls, belts and other biasable members having at least one layer or coating of an elastomeric resilient polyurethane formed by reacting: (a) a polyisocyanate prepolymer comprising the reaction product of: (i) a saturated aliphatic polyisocyanate, a saturated cycloaliphatic polyisocyanate, or an aromatic polyisocyanate; and (ii) a polyol free of aliphatic unsaturation; and (b) a hardening mixture comprising: (i) a polyol of (a) (ii) or a diamine free of aliphatic unsaturation, or a mixture thereof; and, (ii) as a conductivity control agent for controlling the resistivity of the elastomeric polyurethane, from 0.001 to 5.0 weight percent, based on the total weight of the polyurethane, of a phosphonium tetrahaloferrate salt represented by the formula:    Wherein    R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, alkoxy-, carboalkoxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group is substituted with one or more alkyl groups containing from 1 to 18 carbon atoms, one or more alkoxy groups containing from 1 to 12 carbon atoms, one or more hydroxy-, halo-, cyano-, amino-, or nitro-groups; or phenyl;    R¹, R and R³, which can be the same or different, are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy groups, alkoxy groups containing from 1 to 12 carbon atoms, carboalkoxy groups containing from 1 to 12 carbon atoms, acyloxy groups containing from 1 to 12 carbon atoms, nitro-, cyano-, keto- or halo-groups; phenyl substituted with one or more hydroxy groups, alkoxy groups containing from 1 to 12 carbon atoms, carboalkoxy groups containing from 1 to 12 carbon atoms, acyloxy groups containing from 1 to 12 carbon atoms, nitro-, cyano-keto-, or halo-groups; and    X, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine. The biasable members find use in the transfer of electrostatographic toner images from a photoconductor to a final support sheet where the member electrically cooperates with a photoconductor to establish a directional force field therebetween.

  本发明提供的辊子、传送带和其他可偏置部件至少有一层或一层通过反应形成的弹性回弹聚氨酯涂层： (a) 多异氰酸酯预聚物，包括以下物质的反应产物 (i) 饱和脂肪族多异氰酸酯、饱和环脂族多异氰酸酯或芳香族多异 氰酸酯；和 (ii) 不含脂肪族不饱和度的多元醇；以及 (b) 一种硬化混合物，包括 (i) (a)(ii)的多元醇或不含脂肪族不饱和物的二胺，或它们的混合物；以及 (ii) 作为控制弹性聚氨酯电阻率的传导性控制剂，以聚氨酯总重量为基数，含 0.001 至 5.0 重量百分数的四卤铁酸鏻盐，其分子式如下： 其中 R 选自具有 1 至 24 个碳原子的未取代烷基；具有 1 至 24 个碳原子、被一个或多个羟基、烷氧基、碳烷氧基、硝基、氰基、酮基或卤基取代的取代烷基；具有 3 至 7 个碳原子的环烷基；烷基中具有 1 至 20 个碳原子、芳基中具有 6 至 14 个碳原子的烷芳基；在烷基中具有 1 至 4 个碳原子、在芳基中具有 6 至 14 个碳原子的芳烷基； 在烷基中具有 1 至 4 个碳原子、在芳基中具有 6 至 14 个碳原子的芳烷基，其中芳烷基被一个或多个含 1 至 18 个碳原子的烷基、一个或多个含 1 至 12 个碳原子的烷氧基、一个或多个羟基、卤基、氰基、氨基或硝基取代；或苯基取代； R¹、R 和 R³（可以相同或不同）独立选自氢；具有 1 至 24 个碳原子的未取代烷基；具有 1 至 24 个碳原子的被一个或多个羟基、含有 1 至 12 个碳原子的烷氧基、含有 1 至 12 个碳原子的羧基、含有 1 至 12 个碳原子的酰氧基、硝基、氰基、酮基或卤基取代的取代烷基；被一个或多个羟基、含 1 至 12 个碳原子的烷氧基、含 1 至 12 个碳原子的羧基、含 1 至 12 个碳原子的酰氧基、硝基、氰基、酮基或卤基取代的苯基；以及 X（可以相同或不同）独立地选自氟、氯、溴或碘。 这种可偏置构件可用于将电静电墨粉图像从光电导体转移到最终支持片材上，在这种情况下，构件与光电导体电性配合，在两者之间建立定向力场。

表征谱图