1,3,6-三氮杂双环[4.2.1]壬烷 | 736179-85-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 中文名称: 1,3,6-三氮杂双环[4.2.1]壬烷
• 英文名称: 1,3,6-Triazabicyclo[4.2.1]nonane
• CAS: 736179-85-4
• 化学式: C₆H₁₃N₃
• 分子量: 127.19
• InChiKey: KPQPVUVFJQYJAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Fast-curing epoxy systems
  申请人：Evonik Operations GmbH

  公开号：US11286335B2

  公开（公告）日：2022-03-29

  The present invention provides a composition comprising a) at least one epoxy resin, b) at least one cyclic amine of the formula (I) in which R1 to R4 is H or an organic radical and X═—(Y1)m-(A1)n-(Y2)o-(A2)p-(Y3)q-(A3)r-(Y4)s—,  (II) where, independently of one another, m, n, o, p, q, r and s=0 or 1, A1, A2, A3=alkylene or alkenylene radical and Y1, Y2, Y3, Y4=NR5, PR5, O or S, where R5 independently=organic radical, where any two organic radicals selected from R1 to R5 and any radicals present in the alkylene and/or alkenylene radicals A1, A2, A3 may also form one or more further rings, with the proviso that at least one of the radicals selected from R1 to R5 present and any radicals present in the alkylene and/or alkenylene radicals A1, A2, A3 is substituted by at least one —NHR6 or —NH2 group, where R6=organic radical, and c) at least one salt of a very strong Brønsted acid with a counterion selected from metal ions, metal-containing ions, phosphonium ions and unsubstituted ammonium ions, and to processes for production thereof and use thereof.

  本发明提供了一种组合物，其中包括 a) 至少一种环氧树脂、 b) 至少一种式 (I) 的环胺 其中 R1 至 R4 是 H 或有机基，以及 X═-(Y1)m-(A1)n-(Y2)o-(A2)p-(Y3)q-(A3)r-(Y4)s-, (II) 其中 m、n、o、p、q、r 和 s=0 或 1、 A1、A2、A3=亚烷基或烯基且 Y1、Y2、Y3、Y4=NR5、PR5、O 或 S，其中 R5 独立地=有机基、 其中选自 R1 至 R5 的任意两个有机基和亚烷基和/或烯基中的任意基 A1、A2、A3 还可形成一个或多个环、 但至少有一个选自 R1 至 R5 的基和亚烷基和/或烯基 A1、A2、A3 中的任何基被至少一个 -NHR6 或 -NH2 基团取代，其中 R6=有机基，以及 c) 至少一种非常强的布氏酸与选自金属离子、含金属离子、鏻离子和未取代铵离子的反离子的盐、 及其生产工艺和用途。
• SCHNELL HÄRTENDE EPOXYSYSTEME
  申请人：Evonik Operations GmbH

  公开号：EP3569631B1

  公开（公告）日：2022-07-13
• FAST-CURING EPOXY SYSTEMS
  申请人：Evonik Degussa GmbH

  公开号：US20190352450A1

  公开（公告）日：2019-11-21

  The present invention provides a composition comprising a) at least one epoxy resin, b) at least one cyclic amine of the formula (I) in which R 1 to R 4 is H or an organic radical and X═—(Y 1 ) m -(A 1 ) n -(Y 2 ) o -(A 2 ) p -(Y 3 ) q -(A 3 ) r -(Y 4 ) s —,   (II) where, independently of one another, m, n, o, p, q, r and s= 0 or 1, A 1 , A 2 , A 3 =alkylene or alkenylene radical and Y 1 , Y 2 , Y 3 , Y 4 =NR 5 , PR 5 , O or S, where R 5 independently=organic radical, where any two organic radicals selected from R 1 to R 5 and any radicals present in the alkylene and/or alkenylene radicals A 1 , A 2 , A 3 may also form one or more further rings, with the proviso that at least one of the radicals selected from R 1 to R 5 present and any radicals present in the alkylene and/or alkenylene radicals A 1 , A 2 , A 3 is substituted by at least one —NHR 6 or —NH 2 group, where R 6 =organic radical, and c) at least one salt of a very strong Brønsted acid with a counterion selected from metal ions, metal-containing ions, phosphonium ions and unsubstituted ammonium ions, and to processes for production thereof and use thereof.