1,4:3,6-二脱水-2-脱氧-2-[甲基(3-苯基丙基)氨基]-5-O-硝基-L-艾杜糖醇盐酸 | 73188-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,4:3,6-二脱水-2-脱氧-2-[甲基(3-苯基丙基)氨基]-5-O-硝基-L-艾杜糖醇盐酸
• 中文别名: 铜(2+)二(2-甲基苯磺酸酯)
• 英文名称: Copper bis(methylbenzenesulphonate)
• 英文别名: copper;2-methylbenzenesulfonate
• CAS: 73188-73-5
• 化学式: C14H14CuO6S2
• 分子量: 405.9
• InChiKey: SGYSNRGEYVWMQE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  131
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• [EN] PROCESSES FOR THE PREPARATION OF ARTEMISININ AN ITS PRECURSORS<br/>[FR] PROCÉDÉ DE PRÉPARATION D'ARTÉMISININE ET DE SES PRÉCURSEURS
  申请人：AMYRIS BIOTECHNOLOGIES INC

  公开号：WO2009088404A1

  公开（公告）日：2009-07-16

  The present invention provides processes for the preparation of artemisinin and its precursors including amorphadiene, amorphadiene epoxide, dihydroartemisinic alcohol and dihydroartemisinic acid. Specifically, artemisinin is prepared by multi-step synthetic processes from amorphadiene, amorphadiene epoxide, dihydroartemisinic alcohol or dihydroartemisinic acid. Processes for the preparation of amorphadiene, amorphadiene epoxide, dihydroartemisinic alcohol and dihydroartemisinic acid are also disclosed.

  本发明提供了制备青蒿素及其前体的方法，包括阿莫菲二烯、阿莫菲二烯环氧化物、二氢青蒿醇和二氢青蒿酸。具体来说，青蒿素通过从阿莫菲二烯、阿莫菲二烯环氧化物、二氢青蒿醇或二氢青蒿酸进行多步合成过程而制备。还公开了制备阿莫菲二烯、阿莫菲二烯环氧化物、二氢青蒿醇和二氢青蒿酸的方法。
• Process for preparing linear organic oligomers
  申请人：——

  公开号：US20040138476A1

  公开（公告）日：2004-07-15

  The present invention relates to a process for preparing compounds of the formula (I), 1 where n is an integer from 2 to 5, R 1 is H or a C 1 -C 20 -alkyl group which may be interrupted by one or more O or S atoms, silylene, phosphonoyl or phosphoryl groups and Ar is substituted or unsubstituted 1,4-phenylene, 2,7-fluorene or 2,5-thiophene, with Ar being able to be identical or different, semiconductive layers comprising these compounds and their use in semiconductor technology.

  本发明涉及一种制备式(I)化合物的过程，其中n为2至5的整数，R1为H或C1-C20烷基，其可被一个或多个O或S原子中断，也可为硅烷基、膦酰基或磷酰基，Ar为取代或未取代的1,4-苯撑、2,7-芴或2,5-噻吩，Ar可以相同也可以不同，包括这些化合物的半导体层以及它们在半导体技术中的应用。
• Preparation process of cinnamate esters
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0177354A2

  公开（公告）日：1986-04-09

  A cinnamate ester is prepared by reacting carbon monoxide, oxygen, and its corresponding styrene compound and alcohol in the presence of a catalyst which contains, as essential components, (a) a platinum goup metal or a compound thereof; (b) a copper or iron compound; and (c) a compound of at least one metal selected from Groups 4A, 5A, 7A, εA(the iron group only), 1B(exclusive of copper) and 2B. E.g. a catalyst of palladium chloride, copper"chloride and basic zinc carbonate was used to produce methyl cinnamate in 75% yield. In the absence of the zinc carbonate the yield was 2%. (Example 17 and comparative example 1.)

  肉桂酸酯是通过一氧化碳、氧气及其相应的苯乙烯化合物和醇在催化剂存在下进行反应制备的，催化剂的基本成分包括：(a)铂族金属或其化合物；(b)铜或铁化合物；(c)至少一种选自 4A、5A、7A、εA（仅铁族）、1B（不含铜）和 2B 族的金属化合物。 例如，使用氯化钯、氯化铜和碱式碳酸锌催化剂生产肉桂酸甲酯，收率为 75%。 在不使用碳酸锌的情况下，收率为 2%（例 17 和比较例 1）。
• Electroplating bath
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：EP2770087A1

  公开（公告）日：2014-08-27

  Compositions suitable for the electrodeposition of copper on substrates, such as electronic device substrates, are provided. Methods of depositing copper layers on surfaces and filling apertures with copper are also provided.

  提供了适用于在基底（如电子设备基底）上电沉积铜的组合物。此外，还提供了在表面上沉积铜层和用铜填充孔隙的方法。
• POLYTHIOPHENE DERIVATIVE, METHOD FOR PRODUCING SAME, POSITIVE ELECTRODE ACTIVE MATERIAL FOR SECONDARY BATTERIES, AND SECONDARY BATTERY
  申请人：Ricoh Company, Ltd.

  公开号：EP3101048A1

  公开（公告）日：2016-12-07

  A polythiophene derivative including a repeating unit represented by General Formula (1) below: where R1 and R2 each independently denote a group having from 2 through 9 carbon atoms represented by -(R3-S)p-R4 (where R3 denotes an alkylene group having from 1 through 4 carbon atoms, R4 denotes an alkyl group having from 1 through 6 carbon atoms or an aromatic group having from 5 through 6 carbon atoms, and p denotes an integer of 1 or 2), Ar denotes an optionally substituted divalent or monovalent aromatic ring moiety or aromatic heterocyclic moiety, m denotes a natural number of 2 or more, and n denotes a natural number of 0 or 2 or more.

  一种聚噻吩衍生物，包括 下式（1）所代表的重复单元： 其中 R1 和 R2 分别独立地表示具有 2 至 9 个碳原子的基团，由-(R3-S)p-R4 表示（其中 R3 表示具有 1 至 4 个碳原子的亚烷基，R4 表示具有 1 至 6 个碳原子的烷基或具有 5 至 6 个碳原子的芳香基），Ar 表示任选取代的二价或一价芳香环、Ar 表示任选取代的二价或一价芳香环分子或芳香杂环分子，m 表示 2 或以上的自然数，n 表示 0 或 2 或以上的自然数。