1-(二丙-2-基硫代氨基甲酰巯基)-N,N-二丙-2-基-硫代甲酰胺 | 4376-86-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 中文名称: 1-(二丙-2-基硫代氨基甲酰巯基)-N,N-二丙-2-基-硫代甲酰胺
• 英文名称: tetraisopropylthiuram monosulfide
• 英文别名: N,N,N',N'-Tetraisopropylthiurammonosulfid；Tetraisopropylthiuram-monosulfid；n,n,n',n'-Tetrapropan-2-yldicarbonotrithioic diamide；di(propan-2-yl)carbamothioyl N,N-di(propan-2-yl)carbamodithioate
• CAS: 4376-86-7
• 化学式: C₁₄H₂₈N₂S₃
• 分子量: 320.588
• InChiKey: OBBSBBMAXANVAZ-UHFFFAOYSA-N

物化性质

• 熔点：
  117.5-118.5 °C(Solv: ethanol (64-17-5))
• 沸点：
  372.9±25.0 °C(Predicted)
• 密度：
  1.070±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  96
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(二丙-2-基硫代氨基甲酰巯基)-N,N-二丙-2-基-硫代甲酰胺 在 一水合肼 作用下， 生成 4,4-Diisopropylthiosemicarbazid
  参考文献：
  名称：

  Jensen,K.A. et al., Acta Chemica Scandinavica (1947), 1968, vol. 22, p. 1 - 50

  摘要：

  DOI：
• 作为产物：
  描述：

  四异丙基二硫化秋兰姆 在 氰化钠 作用下， 以 乙醇 为溶剂， 生成 1-(二丙-2-基硫代氨基甲酰巯基)-N,N-二丙-2-基-硫代甲酰胺
  参考文献：
  名称：

  Jensen,K.A. et al., Acta Chemica Scandinavica (1947), 1968, vol. 22, p. 1 - 50

  摘要：

  DOI：

文献信息

• The reaction of copper(II) halides and tetraalkylthiuram monosulphides
  作者：Luis I. Victoriano、Ximena A. Wolf、Hernán Cortés

  DOI：10.1016/0277-5387(94)00501-5

  日期：1995.8

  Abstract Tetraalkylthiuram monosulphides reacted with copper(II) chloride and bromide to yield 3,5-bis( N,N -dialkylimonium)-1,2,4-trithiolane trihalocuprate(I) and a neutral halogenobis-( N,N -dialkylthiocarbamoyl)sulphidocopper(l). The products were characterized by elemental analyses, IR spectroscopy and magnetic susceptibility measurements.

  摘要四烷基秋兰姆单硫化物与氯化铜（II）和溴化物反应生成3,5-双（N，N-二烷基亚铵）-1,2,4-三硫杂环戊酸酯三卤代戊酸酯（I）和中性卤代双-（N，N-二烷基硫代氨基甲酰基）磺基铜（l）。产品通过元素分析，红外光谱和磁化率测量进行表征。
• Method of curing rubbers without forming nitrosamines
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0591632A2

  公开（公告）日：1994-04-13

  Branched and cyclic N,N-dialkyldithiocarbamyl accelerators for the sulfur vulcanization of rubber have been found to generally perform as well as the corresponding straight chain N,N-dialkyldithiocarbamyl accelerators, but surprisingly do not produce detectable amounts of environmentally undesirable N-nitrosamines. The branched N,N-alkyldithiocarbamyl accelerators are generally represented by the formula: where R is a branched alkyl group, R' is an alkyl group which may or may not be branched or a cyclic alkyl group or an alkaryl or aryl group, X is another thiocarbamyl group of the same general structure, a primary alkylamino group, an alkylthio group, a 2-benzothiazyl group, or a metal ion, and n is an integer of from 1 to 6. The cyclic dithiocarbamyl accelerators of the invention are generally represented by the formula where X is another thiocarbamyl group of the same general structure, a primary alkylamino group, an alkylthio group, a 2-benzothiazyl group, or a metal ion, and n is an integer of from 1 to 6.

  研究发现，用于橡胶硫化的支链和环状 N,N-二烷基二硫代氨基甲烷促进剂的性能通常与相应的直链 N,N-二烷基二硫代氨基甲烷促进剂相同，但令人惊讶的是，它们不会产生可检测到的对环境有害的 N-亚硝胺。 支链 N,N-二烷基二硫代氨基甲烷促进剂一般用式表示： 其中 R 是支链烷基，R'是烷基（可以是或不是支链烷基或环状烷基）或烷芳基或芳基，X 是具有相同一般结构的另一个硫代氨基甲酰基、伯氨基烷基、烷硫基、2-苯并噻吩基或金属离子，n 是 1 到 6 的整数。 本发明的环状二硫代氨基甲烷促进剂一般由式表示 其中 X 是具有相同一般结构的另一个硫代氨基甲酰基、伯氨基烷基、烷硫基、2-苯并噻 嗪基或金属离子，n 是 1 至 6 的整数。
• METHOD FOR PRODUCING RUBBER COMPOSITION
  申请人：Bridgestone Corporation

  公开号：EP2703428A1

  公开（公告）日：2014-03-05

  The invention is a process for producing a rubber composition containing at least one rubber component (A) selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C) and a vulcanization accelerator (D), wherein the rubber composition is kneaded in multiple stages, the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C) and the vulcanization accelerator (D) are added and kneaded in the first stage of kneading, and the specific energy for kneading in the first stage is from 0.05 to 1.50 kWh/kg. The specific energy is obtained by dividing the power consumption by the motor in the kneading device in the first stage of kneading by the total mass of the rubber composition therein. In the process, the coupling function activity can be further increased and a rubber composition favorably having a low-heat-generation property and having good abrasion resistance can be obtained.

  本发明是一种生产橡胶组合物的工艺，该橡胶组合物含有至少一种选自天然橡胶和合成二烯橡胶的橡胶组分（A）、一种含有无机填料（B）的填料、一种硅烷偶联剂（C）和一种硫化促进剂（D），其中橡胶组合物分多个阶段捏合、在第一阶段混炼中加入并混炼橡胶成分 (A)、全部或部分无机填料 (B)、全部或部分硅烷偶联剂 (C) 和硫化促进剂 (D)，第一阶段混炼的比能量为 0.05 至 1.50 千瓦时/千克。比能量是通过将第一阶段混炼中混炼装置中电机的耗电量除以其中橡胶组合物的总质量得出的。在此过程中，耦合功能活性可进一步提高，并可获得具有低发热特性和良好耐磨性的橡胶组合物。
• PROCESS FOR PRODUCING RUBBER COMPOSITION
  申请人：Bridgestone Corporation

  公开号：EP2695911A1

  公开（公告）日：2014-02-12

  Provided are processes for producing a rubber composition, which enable a suitably low heat-generating rubber composition to be obtained by further improving coupling function activity of a silane coupling agent. More specifically, provided is a process for producing a rubber composition comprising a rubber component (A) comprising at least one selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C), and at least two kinds of chemical agents (D) and (E) selected from guanidines, sulfenamides, thiazoles, thiurams, dithiocarbamates, thioureas, and xanthates, wherein the rubber composition is kneaded in a plurality of stages wherein, in the first stage (X) of kneading, the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C), and at least two kinds of the chemical agents (D) and (E) are added and kneaded. Also provided is a process for producing a rubber composition, wherein the rubber composition is kneaded in a kneading step comprising three or more stages wherein, in the first stage (X) of kneading, the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C) are kneaded; in a stage (Y) after the first stage but before the last stage of kneading, at least two kinds of the chemical agents (D) and (E) are added and kneaded; and, in the last stage (Z) of kneading, a vulcanizing agent is added and kneaded.

  本发明提供了生产橡胶组合物的工艺，通过进一步提高硅烷偶联剂的偶联功能活性，可获得适当低发热量的橡胶组合物。更具体地说，本发明提供了一种生产橡胶组合物的工艺，该橡胶组合物包括至少一种选自天然橡胶和合成二烯橡胶的橡胶组分（A）、一种含有无机填料的填料（B）、一种硅烷偶联剂（C）以及至少两种选自胍类、亚磺酰胺类、噻唑类、噻嗪类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类和二硫代氨基甲酸乙酯类的化学剂（D）和（E）、其中，橡胶组合物分多个阶段捏合，在捏合的第一阶段 (X) 中，加入并捏合橡胶组分 (A)、全部或部分无机填料 (B)、全部或部分硅烷偶联剂 (C) 以及至少两种化学剂 (D) 和 (E)。还提供了一种生产橡胶组合物的工艺，其中橡胶组合物的捏合步骤包括三个或三个以上阶段，在捏合的第一阶段（X），捏合橡胶组分（A）、全部或部分无机填料（B）、全部或部分硅烷偶联剂（C）；在第一阶段之后、最后阶段之前的阶段（Y）中，加入并捏合至少两种化学剂（D）和（E）；以及，在最后阶段（Z）中，加入并捏合硫化剂。
• RUBBER COMPOSITION MANUFACTURING METHOD, RUBBER COMPOSITION, AND PNEUMATIC TIRE USING SAME
  申请人：Bridgestone Corporation

  公开号：EP2799467A1

  公开（公告）日：2014-11-05

  The present invention provides a method for producing a rubber composition provided by compounding a rubber component (A) comprising at least one selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C), and at least one vulcanization accelerator (D) selected from specific compounds, wherein the rubber composition is kneaded in a plurality of stages and wherein, in the first stage (X) of kneading, a portion (A') of the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C), and all or a portion of the vulcanization accelerator (D) are added and kneaded, and in or after the second stage of kneading, the residual portion (A") of the rubber component (A) is added and kneaded, and the method for producing a rubber composition enables production of a rubber composition capable of suitably having a low-heat-generation property by further improving the coupling function activity of the silane coupling agent therein.

  本发明提供了一种生产橡胶组合物的方法，该方法通过混炼橡胶组分（A）提供，橡胶组分（A）包含至少一种选自天然橡胶和合成二烯橡胶的橡胶、一种包含无机填料（B）的填料、一种硅烷偶联剂（C）和至少一种选自特定化合物的硫化促进剂（D），其中橡胶组合物经过多个阶段混炼，并且其中在混炼的第一阶段（X）中，橡胶组分（A）的一部分（A'）、全部或部分无机填料（B）、全部或部分硅烷偶联剂（C）和全部或部分硫化促进剂（D）被加入、该橡胶组合物生产方法可通过进一步提高其中硅烷偶联剂的偶联功能活性，生产出具有适当低发热特性的橡胶组合物。