次氮基三乙氧化铝 | 76962-58-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 次氮基三乙氧化铝
• 英文名称: alumantrane
• 英文别名: alumatrane；tris-(2-hydroxy-ethyl)-amine; aluminium-compound；Tris-(2-hydroxy-aethyl)-amin; Aluminium-Verbindung；2,8,9-Trioxa-5-aza-1-alumina-bicyclo[3.3.3]undecan；2,8,9-trioxa-5-aza-1-aluminabicyclo[3.3.3]undecane
• CAS: 76962-58-8
• 化学式: C₆H₁₂AlNO₃
• 分子量: 173.148
• InChiKey: IRMOUQGSNFXEJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.01
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  72.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  hydrogentetrathiocyanatodiamminechromate(III) 、 次氮基三乙氧化铝 以 丙酮 为溶剂， 生成 (aluminiumtriethanolammonium)tetrathiocyanatodiamminechromate(III)
  参考文献：
  名称：

  Hein, F.; Albert, P. W., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为产物：
  描述：

  三乙醇胺 、 aluminum tri-sec-butoxide 以 not given 为溶剂， 生成 次氮基三乙氧化铝
  参考文献：
  名称：

  Combinatorial Nanopowder Synthesis Along the ZnO-Al₂O₃Tie Line Using Liquid-Feed Flame Spray Pyrolysis

  摘要：

  Liquid‐feed flame spray pyrolysis (LF‐FSP) of mixtures of alumatrane [Al(OCH2CH2)3N]/zinc acetate dihydrate [Zn(O2CCH3)2·2(H2O)] or zinc propionate [Zn(O2CCH2CH3)2]/aluminum acetylacetonate [Al(Acac)3] dissolved in EtOH in known molar ratios can be used to combinatorially generate nanopowders along the ZnO–Al2O3tie‐line. LF‐FSP was used to produce (ZnO)x(Al2O3)1−xpowders withx=0–1.0. Powders were characterized by X‐ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared, thermal gravimetric analysis, differential thermal analysis, and BET. The resulting powders had average particle sizes (APSs) <100 nm with the majority being <50 nm. Analytical data suggest that at concentrations of interest for transparent conducting oxides, <10 mol% Al2O3the particle morphologies are combinations of plates and rods that grow withc/aratios close to 1. The spinel phase dominates at (ZnO)x(Al2O3)1−x(x=0.5 and 0.3). In the latter case, the currently accepted phase diagram for the ZnO–Al2O3couple indicates that phase separation should occur to form zinc spinel (ZnAl2O4) and α‐alumina. It appears that the rapid quenching during LF‐FSP helps to preserve the spinel phase at ambient temperature giving rise to kinetic nanopowder products along the ZnO2–Al2O3tie‐line. Finally, the solubility of ZnO in Al2O3and vice versa in the materials produced by LF‐FSP suggest apparent flame temperatures reached before quenching are 1700°–1800°C. Efforts to re‐pass the spinel phase powders, (ZnO)x(Al2O3)1−x,x=0.5 and 0.3 through the LF‐FSP system were made with the hope of generating core shell materials. However, instead thex=0.5 material generated materials closer to thex=0.3 composition and pure ZnO nanoparticles that coat the former materials. These results suggest that at LF‐FSP flame temperatures ZnO remains in the vapor phase for sufficient times that Al3+oxy‐ions generated promote nucleation of finer particles leaving essentially phase pure ZnO still in the vapor phase to condense giving the two distinct particle morphologies observed.

  DOI：

  10.1111/j.1551-2916.2011.04585.x

文献信息

• Flame Spray Pyrolysis of Precursors as a Route to Nano-mullite Powder: Powder Characterization and Sintering Behavior
  作者：Rita Baranwal、Maria P. Villar、Rafael Garcia、Richard M. Laine

  DOI：10.1111/j.1151-2916.2001.tb00774.x

  日期：2001.5

  The flame spray pyrolysis of alcohol-soluble precursors allows the synthesis of mullite-composition nanopowders (average size of ;60 ‐100 nm) that, when annealed carefully, provide processable nano-mullite powders. The powders have been characterized using several spectroscopic and microscopy methods, including thermal gravimetric analysis, differential thermal analysis, diffuse reflectance infrared

  醇溶性前体的火焰喷雾热解允许合成莫来石组成的纳米粉末（平均尺寸为 60 - 100 nm），当仔细退火时，可提供可加工的纳米莫来石粉末。粉末已使用几种光谱和显微镜方法进行表征，包括热重分析、差热分析、漫反射红外傅里叶变换光谱和透射电子显微镜。介绍了这些粉末的无压烧结行为的初步研究。无需添加剂或任何优化工艺的努力，粉末压块可以在 1600°C 下烧结至 >90% 的相对密度，晶粒尺寸 <500 nm。
• Synthesis and Characterization of Mixed-Metal Oxide Nanopowders Along the CoOx-Al2O3 Tie Line Using Liquid-Feed Flame Spray Pyrolysis
  作者：Jose Azurdia、Julien Marchal、Richard M. Laine

  DOI：10.1111/j.1551-2916.2006.01155.x

  日期：——

  We report here the use of liquid‐feed flame spray pyrolysis (LF‐FSP) to produce a series of nanopowders along the CoOx–Al2O3 tie line. The process is a general aerosol combustion synthesis route to a wide range of lightly agglomerated oxide nanopowders. The materials reported here were produced by aerosolizing ethanol solutions of alumatrane [Al(OCH2CH2)3N] and a cobalt precursor, made by reacting Co(NO3)2·6H2O crystals with propionic acid. The compositions of the as‐produced nanopowders were controlled by selecting the appropriate ratios of the precursors. Nine samples with compositions (CoO)y(Al2O3)1−y, y=0−1 along the CoOx–Al2O3 tie line were prepared and studied. The resulting nanopowders were characterized by X‐ray fluorescence, BET, scanning electron microscopy, high‐resolution transmission electron micrographs, X‐ray diffraction (XRD), thermogravimetric analysis (TGA), and FTIR. The powders typically consist of single‐crystal particles <40 nm diameter and specific surface areas (SSAs) of 20–60 m2/g. XRD studies show a gradual change in powder patterns from δ‐Al2O3 to Co3O4. The cobalt aluminate spinel phase is observed at stoichiometries (21 and 37 mol%) not seen in published phase diagrams, likely because LF‐FSP processing involves a quench of >1000°C in microseconds frequently leading to kinetic rather than thermodynamic products. Likewise, the appearance of Co3O4 rather than CoO as the end member in the tie line is thought to be a consequence of the process conditions. TGA studies combined with diffuse reflectance FTIR spectroscopic studies indicate that both physi‐ and chemi‐sorbed H2O are the principal surface species present in the as‐processed nanopowders. The only sample that differs is Co3O4, which has some carbonate species present that are detected and confirmed by a sharp mass loss event at ∼250°C. The thermal behavior of the high cobalt content samples differs greatly from the low cobalt content samples. The latter behave like most LF‐FSP‐derived nanopowders exhibiting typical 1%–4% mass losses over the 1400°C range due mostly to loss of water and some CO2. The high cobalt content samples exhibit a sharp mass loss event that can be attributed to the decomposition of Co3O4 to CoO.

  本文报道了液态进料火焰喷涂热解法（LF-FSP）在合成一系列沿CoO_x–Al₂O₃连线的纳米粉末中的应用。此工艺是一种广泛适用于多种适度团聚氧化物纳米粉末的气溶胶燃烧合成路线。 文中所述材料通过乙醇溶液中铝基前驱体[Al(OCH₂CH₂)₃N]和钴基前驱体（由Co(NO₃)₂·6H₂O晶体与丙酸反应制得）的气溶胶化实现制备。通过选择合适的前驱体比例，可调控产物纳米粉末的组成。沿CoO_x–Al₂O₃连线，共制备并研究了九种组成样品，其化学式为(CoO)_y(Al₂O₃)^(1−y)，其中y的取值范围为0−1。 所制备的纳米粉末经X射线荧光光谱、BET比表面积分析、扫描电子显微镜、高分辨率透射电子显微镜、X射线衍射（XRD）、热重分析（TGA）以及傅里叶红外光谱表征。粉末典型特征为：单晶颗粒直径小于40 nm，比表面积（SSA）为20–60 m²/g。 XRD研究结果显示，随着Al₂O₃向Co₃O₄的转变，粉末衍射图谱呈现渐进式变化。在化学计量比为21%和37%（未见于已发表的相图）的铝酸钴自旋相被观察到，这一现象或与LF-FSP工艺中微秒级别内逾千摄氏度的快速冷却有关，从而倾向于生成动力学而非热力学产物。同理，Co₃O₄而非CoO作为系线终产物，亦被归因于工艺条件的影响。 结合热重分析与漫反射傅里叶红外光谱研究，发现加工制备的纳米粉末表面主要存在物理吸附和化学吸附水。唯一例外的是Co₃O₄样品，其在约250°C时出现显著失重峰，证实表面存在碳酸盐物种。高钴含量样品与低钴含量样品的热行为存在显著差异：后者与绝大多数LF-FSP制备纳米粉末热行为类似，于1400°C范围内呈现典型的1%-4%失重率，主要归因于水和CO₂的释放；而前者则呈现剧烈失重，此现象可归结于Co₃O₄向CoO的分解。
• Pressureless Sintering<i>t</i>-zirconia@δ-Al₂O₃(54 mol%) Core-Shell Nanopowders at 1120°C Provides Dense<i>t</i>-Zirconia-Toughened α-Al₂O₃Nanocomposites
  作者：Min Kim、Richard M. Laine

  DOI：10.1111/j.1551-2916.2009.03498.x

  日期：2010.3

  Zirconia‐toughened alumina (ZTA) is of growing importance in a wide variety of fields exemplified by ZTA prosthetic implants. Unfortunately, ZTA composites are generally difficult to process because of the need to preserve the tetragonal zirconia phase in the final dense ceramic, coincident with the need to fully densify the α‐Al2O3 component. We report here that liquid‐feed flame spray pyrolysis of mixtures of metalloorganic precursors of alumina and zirconia at varying compositional ratios provide access in one step to core–shell nanoparticles, wherein the shell is δ‐Al2O3 and the core is a perfect single crystal of tetragonal (t‐) zirconia. Pressureless sintering studies provided parameters whereby these nanopowder compacts could be sintered to full density (>99%) at temperatures just above 1100°C converting the shell component to α‐Al2O3 but preserving the t‐ZrO2 without the need for any dopants. The final average grain sizes of these sintered compacts are ≤200 nm. The resulting materials exhibit the expected response to mechanical deformation with the subsequent production of monoclinic ZrO2. These materials appear to offer a low‐temperature, low‐cost route to fine‐grained ZTA with varied Al2O3:t‐ZrO2 compositions.

  氧化锆增韧氧化铝（ZTA）在人工关节植入物等多个领域中具有越来越重要的应用。然而，由于需要在最终致密陶瓷中保持四方氧化锆相，同时需要完全致密氧化铝相，ZTA 复合材料的制备一般较为困难。我们在此报道，通过金属有机物前驱体（氧化铝和氧化锆）在不同配比下的液态供料火焰喷涂方法，可以一步法制得核-壳纳米颗粒，其中壳层为 δ-Al₂O₃，而核层为完美的四方（t-）氧化锆单晶。无压烧结实验给出了这些纳米粉体坯料只需升温至 1100°C 即可烧结致密（>99% 的理论相对密度）的工艺参数，在烧结过程中可以将壳层完全转化为 α-Al₂O₃ 并保留四方氧化锆核而无需添加任何掺杂剂。最终烧结体的平均粒径均≤ 200 nm。这些材料在受力变形后形成单斜氧化锆，表现出了预期的性能。这些材料提供了一条低成本、低温制备具有不同 Al₂O₃:t-ZrO₂ 成分比的细晶 ZTA 的途径。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cr: MVol.C, 111, page 252 - 253
  作者：

  DOI：——

  日期：——
• Hein, F.; Albert, P. W., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Hein, F.、Albert, P. W.

  DOI：——

  日期：——