1-N,2-N-二丁基丙烷-1,2-二胺 | 37480-97-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1-N,2-N-二丁基丙烷-1,2-二胺
• 英文名称: 1,2-bis-(n-butylamino)-propan
• 英文别名: N,N'-dibutyl-1-methyl-ethanediyldiamine；N,N'-Dibutyl-1-methyl-aethandiyldiamin；1,2-dibutylaminopropane；N~1~,N~2~-Dibutylpropane-1,2-diamine；1-N,2-N-dibutylpropane-1,2-diamine
• CAS: 37480-97-0
• 化学式: C₁₁H₂₆N₂
• 分子量: 186.341
• InChiKey: ROXPGFDJPLXRRZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  葡萄糖 、 正丁胺 在 甲醇 、 氢气 、 镍 作用下， 100.0~200.0 ℃ 、19.61 MPa 条件下， 生成 1-N,2-N-二丁基丙烷-1,2-二胺
  参考文献：
  名称：

  DE624443

  摘要：

  公开号：

文献信息

• PROCESS FOR PREPARING A 1,2-ETHYLENEDIAMINE OR 1,2-PROPYLENEDIAMINE
  申请人：Fazio Michael J.

  公开号：US20110092741A1

  公开（公告）日：2011-04-21

  The present invention generally relates to a process for preparing a 1,2-ethylenediamine; 1,2-propylenediamine; or a mixture thereof by way of a catalyzed reductive amination reaction employing hydrogen, a reductive amination catalyst, (C 3 -C 40 )polyhydric alcohol having at least three hydroxy groups on consecutive carbon atoms thereof, and primary amine, the catalyzed reductive amination reaction employing reaction conditions that are effective for reductively aminating at least two of the hydroxy groups of the (C 3 -C 40 )polyhydric alcohol and reductively eliminating at least one other of the hydroxy groups of the (C 3 -C 40 )polyhydric alcohol in such a way so as to give a 1,2-ethylenediamine; 1,2-propylenediamine; or a mixture thereof.

  本发明通常涉及通过使用氢气、还原胺催化剂、至少具有三个羟基的(C3-C40)多羟基醇和初级胺进行催化还原胺反应，从而制备1,2-乙二胺；1,2-丙二胺；或它们的混合物的方法。催化还原胺反应应用的反应条件有效地对(C3-C40)多羟基醇的至少两个羟基进行还原胺化，并还原性地消除(C3-C40)多羟基醇的至少另一个羟基，以便给出1,2-乙二胺；1,2-丙二胺；或它们的混合物。
• ANTISTATIC AGENT, ANTISTATIC AGENT COMPOSITION, ANTISTATIC RESIN COMPOSITION, AND MOLDED BODY
  申请人：Adeka Corporation

  公开号：EP2949721A1

  公开（公告）日：2015-12-02

  Provided are: an antistatic agent which is capable of imparting excellent antistatic effect in a small amount and has sufficient persistence and wiping resistance; an antistatic agent composition; an antistatic resin composition; and a molded article. The antistatic agent comprises a polymer compound (E) having a structure in which a block polymer (C) and an epoxy compound (D) are bound via an ester bond formed by a carboxyl group of the block polymer (C) and an epoxy group of the epoxy compound (D), the block polymer (C) having a structure comprising carboxyl groups at both ends, in which structure a block constituted by a polyester (A) having carboxyl groups at both ends and a block constituted by a compound (B) having hydroxyl groups at both ends are repeatedly and alternately bound via ester bonds formed by the carboxyl groups and the hydroxyl groups, and the epoxy compound (D) comprising two or more epoxy groups.

  本发明提供了：一种抗静电剂，该抗静电剂能够以少量提供优异的抗静电效果，并具有足够的持久性和耐擦拭性；一种抗静电剂组合物；一种抗静电树脂组合物；以及一种成型制品。抗静电剂包括聚合物化合物（E），其结构是嵌段聚合物（C）和环氧化合物（D）通过由嵌段聚合物（C）的羧基和环氧化合物（D）的环氧基形成的酯键结合在一起，嵌段聚合物（C）具有两端包含羧基的结构、在该结构中，由两端具有羧基的聚酯（A）构成的嵌段和由两端具有羟基的化合物（B）构成的嵌段通过由羧基和羟基形成的酯键反复交替结合，环氧化合物（D）包括两个或多个环氧基团。
• ANTISTATIC AGENT, ANTISTATIC AGENT COMPOSITION, ANTISTATIC RESIN COMPOSITION, AND MOLDED ARTICLE
  申请人：Adeka Corporation

  公开号：EP2977424A1

  公开（公告）日：2016-01-27

  Provided are: an antistatic agent which is capable of imparting excellent antistatic effect in a small amount and has sufficient persistence and wiping resistance; an antistatic agent composition; an antistatic resin composition; and a molded article. The antistatic agent comprises a polymer compound (E) having a structure in which a block polymer (C) and a polyhydric alcohol compound (D) are bound via an ester bond formed by a carboxyl group of the block polymer (C) and a hydroxyl group of the polyhydric alcohol compound (D), the block polymer (C) having a structure comprising carboxyl groups at both ends, in which structure a block constituted by a polyester (A) having carboxyl groups at both ends and a block constituted by a compound (B) having hydroxyl groups at both ends are repeatedly and alternately bound via ester bonds formed by the carboxyl and hydroxyl groups, and the polyhydric alcohol compound (D) comprising three or more hydroxyl groups.

  本发明提供了：一种抗静电剂，该抗静电剂能够以少量提供优异的抗静电效果，并具有足够的持久性和耐擦拭性；一种抗静电剂组合物；一种抗静电树脂组合物；以及一种成型制品。 抗静电剂包括一种聚合物化合物（E），其结构是嵌段聚合物（C）和多元醇化合物（D）通过由嵌段聚合物（C）的羧基和多元醇化合物（D）的羟基形成的酯键结合在一起，嵌段聚合物（C）具有在两端包含羧基的结构、在该结构中，由两端具有羧基的聚酯（A）和由两端具有羟基的化合物（B）构成的嵌段通过羧基和羟基形成的酯键反复交替结合，多羟基化合物（D）包括三个或三个以上的羟基。
• ANTI-STATIC AGENT, ANTI-STATIC AGENT COMPOSITION, ANTI-STATIC RESIN COMPOSITION, AND MOLDING
  申请人：Adeka Corporation

  公开号：EP3184598A1

  公开（公告）日：2017-06-28

  Provided are: an antistatic agent and an antistatic agent composition which are capable of providing excellent antistatic effect in a small amount and have sufficient persistence and wiping resistance; and an antistatic resin composition and a molded article using the same. The antistatic agent includes a polymer compound (E) having a structure in which a diol, a dicarboxylic acid, a compound (B) which comprises at least one group represented by the following Formula (1) and has hydroxyl groups at both ends, and a polycarboxylic acid compound (D) are bound via ester bonds:         -CH2-CH2-O-     (1)

  本发明提供了：一种抗静电剂和一种抗静电剂组合物，它们能够以少量提供优异的抗静电效果，并具有足够的持久性和耐擦拭性；以及一种抗静电树脂组合物和一种使用该抗静电剂和组合物的模塑制品。 抗静电剂包括一种聚合物化合物 (E)，其结构是通过酯键结合二元醇、二羧酸、化合物 (B)（其中至少包括一个由下式 (1) 表示的基团且两端带有羟基）和聚羧酸化合物 (D) 的结构：-CH2-CH2-O- (1)
• POLYOLEFIN RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP3235864A1

  公开（公告）日：2017-10-25

  Provided are: a polyolefin resin composition which has excellent antistatic properties with sufficient persistence and wiping resistance but without impairment of the intrinsic mechanical properties of a resin; and an automotive interior/exterior material containing the same. The polyolefin resin composition contains: 50 to 90 parts by mass of a polyolefin resin; 3 to 40 parts by mass of a thermoplastic elastomer; and 3 to 30 parts by mass of a filler, the polyolefin resin composition further containing an antistatic agent composed of a polymer compound (E) in an amount of 3 to 20 parts by mass with respect to a total amount of 100 parts by mass of the polyolefin resin, the thermoplastic elastomer and the filler, wherein the polymer compound (E) has a structure in which a diol, an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, a compound (B) which contains at least one group represented by the Formula (1) and has hydroxyl groups at both ends, and an epoxy compound (D) having two or more epoxy groups are bound via ester bonds:

  本文提供了：一种聚烯烃树脂组合物，它具有优异的抗静电性能、足够的持久性和耐擦拭性，但不会损害树脂的固有机械性能；以及一种含有该组合物的汽车内饰/外饰材料。聚烯烃树脂组合物含有50 至 90 质量份的聚烯烃树脂； 3 至 40 质量份的热塑性弹性体；聚烯烃树脂组合物还含有抗静电剂，该抗静电剂由聚合物化合物 (E) 组成，相对于聚烯烃树脂、热塑性弹性体和填料的总质量 100 份，抗静电剂的质量为 3 至 20 份、其中聚合物化合物（E）的结构为：二元醇、脂肪族二羧酸、芳香族二羧酸、至少含有一个由式（1）表示的基团且两端具有羟基的化合物（B）和具有两个或两个以上环氧基团的环氧化合物（D）通过酯键结合在一起：