1-丙铵,N,N,N-三丙基-,碳酸盐(1:1) | 112306-93-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1-丙铵,N,N,N-三丙基-,碳酸盐(1:1)
• 英文名称: tetrapropylammonium bicarbonate
• 英文别名: tetrapropylammonium hydrogencarbonate；Hydron;tetrapropylazanium;carbonate；hydron;tetrapropylazanium;carbonate
• CAS: 112306-93-1
• 化学式: CHO₃*C₁₂H₂₈N
• 分子量: 247.378
• InChiKey: HBRMHZKBZZGJFF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.33
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  60.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二氧化碳 、 四丙基氢氧化铵 以 水 为溶剂， 生成 1-丙铵,N,N,N-三丙基-,碳酸盐(1:1)
  参考文献：
  名称：

  烯烃与过氧化氢水溶液和碳酸氢季铵催化剂的环氧化反应

  摘要：

  摘要合成了一系列含有碳酸氢根阴离子的固体和液体催化剂，并测试了烯烃与过氧化氢水溶液的环氧化反应。碳酸氢根阴离子和季铵阳离子的结合为新的催化系统开辟了道路，有助于克服催化剂分离和再利用方面的挑战。图形概要

  DOI：

  10.1007/s10562-013-1088-1

文献信息

• CO₂ capture from ambient air <i>via</i> crystallization with tetraalkylammonium hydroxides
  作者：Manish Kumar Mishra、Volodymyr Smetana、Ethan A. Hiti、Hannah B. Wineinger、Fengrui Qu、Anja-Verena Mudring、Robin D. Rogers

  DOI：10.1039/d2dt02262a

  日期：——

  ([(HCO3)2·(H2O)]24−) or chains ([H(HCO3)2]nn− or [H2(tpa)(HCO3)2]n2n−) to water-bicarbonate associates ([(HCO3)2·6H2O]2− and [(H2CO3·(HCO3)2)2·6H2O·2H2O]2−) and three-component anionic layers ([H(Cyt)(HCO3)·H2O]nn− and [H2(Cyt)2(HCO3)·H2O]nn−) frequently showing proton sharing. While some hydroxides themselves can maintain a high CO2/[Nnnnn][OH] ratio, particularly 2 and 4, the presence of secondary hydrogen

  偶然发现了一系列短碳链四（正烷基）氢氧化铵 [N nnnn ][OH] 的水溶液，其中n = 2：正乙基，3：正丙基，4：正丁基当在更复杂的反应中用作试剂时，成为直接空气碳捕获 (DAC) 的潜在候选者。[N 3333 ][OH]、[N 2222 ][OH]或[N 3333 ][OH]与UO 2 SO 4 ·3H 2 O和1,4-二氨基肟基苯的水溶液，以及[N 4444 ][OH ] 用胞嘧啶（HCyt）直接吸收CO 2在开放大气中温和加热后从大气中结晶成复合物，达到 2 : 1 CO 2 /[N nnnn ]OH 比率。[N 2222 ][HCO 3 ]·3H 2 O ( 1 ), [N 2222 ] 2 [H(HCO 3 ) 3 ]·5H 2 O ( 2 ), [N 3333 ][HCO 3 ]·0.5H 2 O ( 3 ), [N 3333 ][H(HCO 3 ) 2 ] ( 4 )
• METHOD FOR MANUFACTURING CHEMICAL COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3037398A1

  公开（公告）日：2016-06-29

  A method for producing a compound, comprising mixing a compound (1) having one or two leaving groups, a compound (2) having one or two boron atom-containing leaving groups, an organic base (P), and at least one selected from the group consisting of a phase transfer catalyst and an organic base (Q) larger in the number of carbon atoms than the above-mentioned organic base in the presence of a transition metal catalyst, thereby performing a coupling reaction between the above-mentioned compound (1) and the above-mentioned compound (2).

  一种生产化合物的方法，包括在过渡金属催化剂存在下，将具有一个或两个离去基团的化合物（1）、具有一个或两个含硼原子离去基团的化合物（2）、有机碱（P）和至少一种选自相转移催化剂和碳原子数大于上述有机碱的有机碱（Q）组成的组中的一种混合，从而在上述化合物（1）和上述化合物（2）之间进行偶联反应。
• METHOD FOR MANUFACTURING COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3225610A1

  公开（公告）日：2017-10-04

  Provided is a method for producing a compound which is excellent in reaction rate (having higher reaction rate). A method for producing a compound comprising a step of supplying a compound (1) having at least one atom group selected from Group A, a compound (2) having at least one group selected from Group B, a transition metal catalyst, an organic base and a compound having two or more hydroxyl groups into a reaction vessel, and a step of, in the reaction vessel, reacting the compound (1) with the compound (2) in the presence of the transition metal catalyst, the organic base and the compound having two or more hydroxyl groups. a chlorine atom, a bromine atom, an iodine atom or the like, a group represented by -B(RC2)2, a group represented by -B(ORC2)2 or the like. (wherein, RC2 represents a hydrogen atom, an alkyl group or the like. The plurality of RC2 may be the same or different and may be combined together to form a ring together with a boron atom or an oxygen atom to which they are attached.)

  本发明提供了一种生产反应速率优异（反应速率更高）的化合物的方法。 一种生产化合物的方法，包括以下步骤：将具有至少一个选自 A 组的原子团的化合物（1）、具有至少一个选自 B 组的原子团的化合物（2）、过渡金属催化剂、有机碱和具有两个或两个以上羟基的化合物放入反应容器中；在过渡金属催化剂、有机碱和具有两个或两个以上羟基的化合物存在的情况下，在反应容器中使化合物（1）与化合物（2）反应。 氯原子、溴原子、碘原子或类似物、 由-B(RC2)2 表示的基团、由-B(ORC2)2 表示的基团或类似基团。 (其中，RC2 代表氢原子、烷基或类似基团。多个 RC2 可以相同或不同，并可结合在一起，与所连接的硼原子或氧原子一起形成一个环)。
• POLYMER COMPOUND PRODUCTION METHOD
  申请人：Sumitomo Chemical Company Limited

  公开号：EP3489274A1

  公开（公告）日：2019-05-29

  To provide a polymer compound production method capable of efficiently producing a polymer compound in which the content of a halogen atom and the content of a hydroxyl group are sufficiently reduced. A production method of a polymer compound containing a constitutional unit represented by the formula (1), a constitutional unit represented by the formula (2) and a structure represented by the formula (3), comprising a first step of reacting a compound represented by the formula (M-1) and a compound represented by the formula (M-2), in the presence of a solvent, a base and a first palladium compound, to obtain a reaction product and a second step of reacting the above-described reaction product and a compound represented by the formula (M-3), in the presence of a second palladium compound different from the first palladium compound, to obtain a polymer compound:         Z1-Ar1-Z2     (M-1)         Z3-Ar2-Z4     (M-2)         Ar3-Z5     (M-3) [wherein, Ar1 and Ar2 represent an arylene group or the like, and Ar3 represents an aryl group or the like. Z1 to Z5 represent a group selected from Group A of substituent and Group B of substituent.] a chlorine atom and the like: a group represented by -B(ORC2)2 (wherein, RC2 represents a hydrogen atom or the like.):         ⁅Ar1⁆     (1)         ⁅Ar2⁆     (2)         -Ar3     (3)

  目的 提供一种聚合物化合物的生产方法，该方法能够有效地生产出一种卤原子含量和羟基 含量充分降低的聚合物化合物。 一种含有由式（1）表示的构型单元、由式（2）表示的构型单元和由式（3）表示的结构的聚合物化合物的生产方法，包括第一步，由式（M-1）表示的化合物和由式（M-2）表示的化合物反应、第二步：在不同于第一种钯化合物的第二种钯化合物存在下，使上述反应产物和式 (M-3)代表的化合物反应，得到聚合物化合物： Z1-Ar1-Z2 (M-1) Z3-Ar2-Z4 (M-2) Ar3-Z5 (M-3) [其中，Ar1 和 Ar2 代表芳烯基团或类似基团，Ar3 代表芳基或类似基团。Z1 至 Z5 代表选自取代基 A 组和取代基 B 组的基团]。 氯原子等： 由-B(ORC2)2 代表的基团（其中，RC2 代表氢原子或类似物）： ⁅Ar1⁆ (1) ⁅Ar2⁆ (2) -⁅Ar3 (3)
• METHOD FOR PRODUCING POLYMER COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP3636690A1

  公开（公告）日：2020-04-15

  An object of the present invention is to provide a method for producing a polymer compound having a crosslinkable group, the polymer compound having a low content of low-molecular-weight compounds and sufficiently low polydispersity. The method for producing a polymer compound having a crosslinkable group comprises the steps of: (1) polymerizing a monomer component in a solvent in the presence of a transition metal complex to thereby obtain a first polymer compound having a crosslinkable group, wherein the monomer component comprises a monomer having a crosslinkable group; and (2) mixing a solution containing a first solvent and the first polymer compound with a second solvent, followed by separation into two or more layers, and selecting a layer containing a polymer compound having the largest polystyrene-equivalent weight average molecular weight to thereby obtain a second polymer compound having a crosslinkable group, wherein the first solvent contains a solvent of the same kind as the solvent used in step (1), the second solvent is a poor solvent for the first polymer compound, and the solvent contained in each of the two or more layers is substantially an organic solvent.

  本发明的目的是提供一种生产具有可交联基团的聚合物化合物的方法，该聚合物化合物具有较低的低分子量化合物含量和足够低的多分散性。生产具有可交联基团的聚合物化合物的方法包括以下步骤：(1) 在过渡金属复合物存在下，在溶剂中聚合单体组分，从而获得第一种具有可交联基团的聚合物化合物，其中单体组分包括具有可交联基团的单体；(2) 将含有第一种溶剂和第一种聚合物化合物的溶液与第二种溶剂混合，然后分离成两层或多层，并选择含有聚苯乙烯当量重平均分子量最大的聚合物化合物的一层，从而得到具有可交联基团的第二种聚合物化合物，其中第一种溶剂含有与步骤(1)中所用溶剂相同种类的溶剂，第二种溶剂是第一种聚合物化合物的劣溶剂，两层或多层中每一层所含的溶剂基本上是有机溶剂。