1-咪唑烷甲酰胺,N-(1-甲基乙基)-2,4-二羰基-3-苯基- | 104700-58-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 中文名称: 1-咪唑烷甲酰胺,N-(1-甲基乙基)-2,4-二羰基-3-苯基-
• 英文名称: 3-phenyl-N-(1-methylethyl)-2,4-dioxo-1-imidazolidinecarboxamide
• 英文别名: 2,4-Dioxo-3-phenyl-N-(propan-2-yl)imidazolidine-1-carboxamide；2,4-dioxo-3-phenyl-N-propan-2-ylimidazolidine-1-carboxamide
• CAS: 104700-58-5
• 化学式: C₁₃H₁₅N₃O₃
• 分子量: 261.28
• InChiKey: YAPYMCOIVZGZTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  69.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  异丙醇 、 异菌脲 以 异丙醇 为溶剂， 反应 5.0h， 生成 1-咪唑烷甲酰胺,N-(1-甲基乙基)-2,4-二羰基-3-苯基- 、 3-(3-chlorophenyl)-N-(1-methylethyl)-2,4-dioxo-1-imidazolidinecarboxamide 、 3-<3-(1-hydroxy-1-methylethyl)phenyl>-N-(1-methylethyl)-2,4-dioxo-1-imidazolidinecarboxamide 、 3-<3-chloro-5-(1-hydroxy-1-methylethyl)phenyl>-N-(1-methylethyl)-2,4-dioxo-1-imidazolidinecarboxamide
  参考文献：
  名称：

  Fungicides and photochemistry photodegradation of the dicarboximide fungicide iprodione

  摘要：

  To examine the potential of the fungicide iprodione (1) (3-(3, 5-dichlorophenyl)-N-( 1-methylethyl)-2,4-dioxo-1 -imidazolidinecarboxamide) to undergo photochemical reactions on plant surfaces model experiments (lambda > 280 nm) were performed in various organic solvents simulating the plant cuticle environment. Photodegradation of iprodione was more efficient in isopropanol than in a saturated (cyclohexane) or an unsaturated hydrocarbon medium (cyclohexene). In isopropanol and cyclohexane mainly photodehalogenation reactions of the fungicide were observed whereby in side reactions substitutions of the chlorines by solvent molecules took place. On the other hand, in cyclohexene solutions, substitutions of the chlorines by solvent molecules were mainly observed.

  DOI：

  10.1016/0045-6535(95)00159-6

文献信息

• Fungicides and photochemistry photodegradation of the dicarboximide fungicide iprodione
  作者：W. Schwack、B. Bourgeois、F. Walker

  DOI：10.1016/0045-6535(95)00159-6

  日期：1995.8

  To examine the potential of the fungicide iprodione (1) (3-(3, 5-dichlorophenyl)-N-( 1-methylethyl)-2,4-dioxo-1 -imidazolidinecarboxamide) to undergo photochemical reactions on plant surfaces model experiments (lambda > 280 nm) were performed in various organic solvents simulating the plant cuticle environment. Photodegradation of iprodione was more efficient in isopropanol than in a saturated (cyclohexane) or an unsaturated hydrocarbon medium (cyclohexene). In isopropanol and cyclohexane mainly photodehalogenation reactions of the fungicide were observed whereby in side reactions substitutions of the chlorines by solvent molecules took place. On the other hand, in cyclohexene solutions, substitutions of the chlorines by solvent molecules were mainly observed.