10-乙基-吩噻嗪-4-羧酸 | 60411-11-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 中文名称: 10-乙基-吩噻嗪-4-羧酸
• 英文名称: 10-ethyl-phenothiazine-4-carboxylic acid
• 英文别名: 10-ethyl-4-phenothiazinecarboxylic acid；10-ethyl-10H-phenothiazine-4-carboxylic acid；10-Aethyl-phenothiazin-4-carbonsaeure；10-ethyl-10H-phenothiazine-4-carboxylic acid；10-ethylphenothiazine-4-carboxylic acid
• CAS: 60411-11-2
• 化学式: C₁₅H₁₃NO₂S
• 分子量: 271.34
• InChiKey: BETLSGXAHKBRAR-UHFFFAOYSA-N

物化性质

• 熔点：
  182 °C(Solv: ethanol (64-17-5))
• 沸点：
  457.1±44.0 °C(Predicted)
• 密度：
  1.312±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  65.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  10-乙基-吩噻嗪-4-羧酸 在 双氧水 、 溶剂黄146 作用下， 生成 10-乙基-5,5-二氧代吩噻嗪-4-羧酸
  参考文献：
  名称：

  SOME DERIVATIVES OF 10-ALKYLPHENOTHIAZINES

  摘要：

  DOI：

  10.1021/jo01369a013
• 作为产物：
  描述：

  10-乙基-10H-吩噻嗪-4-羧酸甲酯 在 氢氧化钾 作用下， 生成 10-乙基-吩噻嗪-4-羧酸
  参考文献：
  名称：

  一些吩噻嗪衍生物；Friedel-Crafts反应的过程。

  摘要：

  DOI：

  10.1021/ja01216a078

文献信息

• Preparation of 4-substituted 10-ethylphenothiazines
  作者：Søren Ebdrup、Marianne Schou Jensen、Per Vedsø

  DOI：10.1039/a704120i

  日期：——

  Under appropriate reaction conditions 10-ethylphenothiazine 1 undergoes lithiation at C-4 using an excess of sec-butyllithium–N,N,N′,N′-tetramethylethane-1,2-diamine in diethyl ether. Reaction of the lithiated intermediate with a variety of carbon, halogen, sulfur and silicon electrophiles affords several new 4-substituted 10-ethylphenothiazines 3a–i in good yields.

  在适当的反应条件下，10-乙基吩噻嗪 1 在二乙醚中使用过量的仲丁基锂-N,N,N′,N′-四甲基乙烷-1,2-二胺在 C-4 发生石化作用。锂化的中间体与各种碳、卤素、硫和硅亲电体反应，可以得到几种新的 4-取代的 10-乙基吩噻嗪 3a-i，收率很高。
• NON-AQUEOUS, LIQUID, ENZYME-CONTAINING COMPOSITIONS
  申请人：NOVOZYMES A/S

  公开号：US20010006636A1

  公开（公告）日：2001-07-05

  A substantially water-free, liquid, enzyme-containing composition comprises: (A) an enzyme; (B) a substance selected from (i) substances which in aqueous medium are substrates for said enzyme, (ii) substances which in aqueous medium are precursors for substrates for said enzyme, and (iii) substances which are cofactors for said enzyme; and (C) a non-aqueous liquid phase.

  一种含有酶的基本无水、液体组合物，包括：(A)酶；(B)从(i)在水介质中是该酶底物的物质，(ii)在水介质中是该酶底物的前体的物质，和(iii)是该酶辅因子的物质中选择的物质；以及(C)非水液相。
• Bleach boosting components, compositions and laundry methods
  申请人：The Procter & Gamble Company

  公开号：US20040220069A1

  公开（公告）日：2004-11-04

  Formulation components such as bleach boosting compounds selected from the group consisting of bleach boosters comprising quaternary imine cations, zwitterions, polyions having a net charge of from about +3 to about 3 and mixtures thereof, bleaching species comprising oxariridinium cations, zwitterions, polyions having a net charge of from about +3 to about −3 and mixtures thereof, and mixtures thereof are disclosed. The bleach boosting compounds increase bleaching effectiveness even in lower temperature solutions and provides improved stability toward unwanted boosting compound decomposition. The bleach boosting compounds are ideally suited for inclusion into bleaching compositions including those with detersive surfactants and enzymes. Also provided is a method for laundering a fabric employing the bleach compounds, a laundry additive product employing the bleach boosting compounds.

  本发明揭示了一种包括漂白增强剂的组合物，所述漂白增强剂从以下组合中选择：包含季铵亚胺阳离子、双性离子、净电荷约为+3到约3的聚离子及其混合物的漂白增强剂；包括氧杂环丙铵阳离子、双性离子、净电荷约为+3到约-3的聚离子及其混合物的漂白物种；以及其混合物。漂白增强剂即使在较低温度溶液中也能提高漂白效果，并提供对不需要的增强剂分解的改进稳定性。漂白增强剂非常适合包括具有洗涤表面活性剂和酶的漂白组成物中。还提供了一种使用漂白剂的方法来洗涤织物，以及一种使用漂白增强剂的洗涤添加剂产品。
• Fast-acting formulation components, compositions and laundry methods employing same
  申请人：Dykstra Richard Robert

  公开号：US20050256017A1

  公开（公告）日：2005-11-17

  The present invention relates to formulation components, such as organic catalyst compounds designed with time-controlled bleaching to increase color safety, compositions and laundry methods employing such organic catalyst compounds. More particularly, this invention relates to organic catalysts compounds such as quaternary imine bleach boosting compounds, quaternary oxaziridinium bleaching species, modified amines and amine oxides, imines, and/or oxaziridines, compositions and laundry methods employing such organic catalyst compounds.

  本发明涉及制剂组分，例如设计有时间控制漂白的有机催化剂化合物，以增加颜色安全性，以及应用此类有机催化剂化合物的组合物和洗涤方法。更具体地说，本发明涉及有机催化剂化合物，例如季铵亚胺漂白增白剂、季铵氧杂环丙烷漂白物种、改性胺和胺氧化物、亚胺和/或氧杂环丙烷，以及应用此类有机催化剂化合物的组合物和洗涤方法。
• Method for dyeing dry hair
  申请人：Novozymes A/S

  公开号：US20020007524A1

  公开（公告）日：2002-01-24

  The present invention relates to methods for dyeing keratinous fibers, without significantly damaging the hair. According to the method of the present invention the fibers are treated in a dry state by contacting said fibers with at least one oxidoreductase and at least one dye precursor. In this way it is possible to dye, e.g. human hair, in a simple and efficient manner.

  本发明涉及一种染色角蛋白纤维的方法，而不会显着损伤头发。根据本发明的方法，通过将纤维与至少一种氧化还原酶和至少一种染料前体接触，以干燥状态处理纤维。通过这种方式，可以简单高效地染色，例如人类头发。

表征谱图