2,4,6-三(吗啉-4-基甲基)苯酚 | 5464-87-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4,6-三(吗啉-4-基甲基)苯酚
• 英文名称: 2,4,6-Tris-morpholinomethyl-phenol
• 英文别名: 2,4,6-tris-morpholin-4-ylmethyl-phenol；2,4,6-Tris(morpholin-4-ylmethyl)phenol
• CAS: 5464-87-9
• 化学式: C₂₁H₃₃N₃O₄
• 分子量: 391.511
• InChiKey: JGTWRXHFXRFYTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  57.6
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  吗啉 、 聚合甲醛 、 苯酚 生成 2,4,6-三(吗啉-4-基甲基)苯酚
  参考文献：
  名称：

  Condensation of Phenols with Amines and Formaldehyde

  摘要：

  DOI：

  10.1021/ja01846a066

文献信息

• Polyester-epoxide polymer compositions
  申请人：STEPAN COMPANY

  公开号：US10882946B2

  公开（公告）日：2021-01-05

  Polyester-epoxide polymer (PEEP) compositions are disclosed. The PEEP compositions comprise a reaction product of a polyepoxide compound (eq. wt. 125 to 250 g/eq.) and a polyester polyol composition. The ratio of epoxy equivalents to hydroxyl equivalents is within the range of 0.8 to 3.5. The PEEP composition has a Tg within the range of −40° C. to 60° C. Elevated temperature-cure and low temperature-cure processes for making the PEEP compositions are also disclosed. In a simple yet innovative approach, a new class of polymers useful for adhesives, coatings, elastomers, and other valuable products is assembled from readily available starting materials without reliance on polyisocyanates or polyamines. The PEEP compositions have increased elongation and lower Tg when compared with traditional epoxy products.

  本发明公开了聚酯环氧聚合物（PEEP）组合物。PEEP 组合物包括聚环氧化合物（当量重量 125 至 250 克/当量）和聚酯多元醇组合物的反应产物。环氧当量与羟基当量的比例在 0.8 至 3.5 之间。PEEP 组合物的 Tg 在 -40°C 至 60°C 范围内。还公开了用于制造 PEEP 组合物的高温固化和低温固化工艺。通过这种简单而又创新的方法，可以利用现成的起始材料，不依赖多异氰酸酯或多胺，组装出一类可用于粘合剂、涂料、弹性体和其他有价值产品的新型聚合物。与传统的环氧产品相比，PEEP 合成物的伸长率更高，Tg 更低。
• Isocyanate-modified polyester-epoxide polymer compositions
  申请人：STEPAN COMPANY

  公开号：US11059933B2

  公开（公告）日：2021-07-13

  Isocyanate-modified polyester-epoxide polymer (i-PEEP) compositions are disclosed. The i-PEEP compositions comprise a reaction product of a polyepoxide compound, a polyisocyanate, and a polyester polyol composition. The ratio of epoxy equivalents to hydroxyl equivalents is within the range of 0.2 to 2. The i-PEEP index as defined herein is within the range of 100 to 200. The i-PEEP composition has a Tg within the range of −30° C. to 35° C. Low- and elevated-temperature processes catalyzed by bases or Lewis acids for making the i-PEEP compositions are also disclosed. In a simple yet innovative approach, a new class of polymers useful for coatings, elastomers, adhesives, sealants, and other valuable products is assembled from readily available starting materials without reliance on the polyamines typically used to cure epoxy systems.

  本发明公开了异氰酸酯改性聚酯环氧聚合物（i-PEEP）组合物。i-PEEP 组合物包括聚环氧化合物、多异氰酸酯和聚酯多元醇组合物的反应产物。环氧当量与羟基当量的比例在 0.2 至 2 之间。本文定义的 i-PEEP 指数在 100 至 200 之间。还公开了在碱或路易斯酸催化下制造 i-PEEP 组合物的低温和高温工艺。通过这种简单而又创新的方法，一种可用于涂料、弹性体、粘合剂、密封剂和其他有价值的产品的新型聚合物可由容易获得的起始材料组装而成，而无需依赖通常用于固化环氧体系的多胺。
• Polyether-epoxide polymer compositions
  申请人：STEPAN COMPANY

  公开号：US11066550B2

  公开（公告）日：2021-07-20

  Polyether-epoxide polymer compositions are disclosed. The compositions comprise a reaction product of a polyepoxide compound and a polyol composition comprising a polyether polyol. The ratio of epoxy equivalents to hydroxyl equivalents is within the range of 0.5:1 to 3:1. The polyether-epoxide composition has a Tg within the range of −40° C. to 60° C. The polyether polyol has a hydroxyl value within the range of 150 to 800 mg KOH/g and an average hydroxyl functionality within the range of 3.5 to 8.0. In some aspects, the polyol composition further comprises a polyester polyol. Low- and elevated-temperature processes catalyzed by bases or Lewis acids for making the polyether-epoxide compositions are also disclosed. In a simple yet innovative approach, a new class of polymers useful for coatings, elastomers, adhesives, sealants, and other valuable products is assembled from readily available starting materials without reliance on polyamines or polyisocyanates.

  本发明公开了聚醚环氧化物聚合物组合物。这些组合物包括聚环氧化物化合物和由聚醚多元醇组成的多元醇组合物的反应产物。环氧当量与羟基当量之比为 0.5:1 至 3:1。聚醚多元醇的羟基值在 150 至 800 毫克 KOH/g 之间，平均羟基官能度在 3.5 至 8.0 之间。在某些方面，多元醇组合物还包括聚酯多元醇。还公开了在碱或路易斯酸催化下制造聚醚环氧化物组合物的低温和高温工艺。通过这种简单而又创新的方法，可以利用现成的起始材料合成一类新型聚合物，这种聚合物可用于涂料、弹性体、粘合剂、密封剂和其他有价值的产品，而无需依赖多胺或多异氰酸酯。
• POLYESTER-EPOXIDE POLYMER COMPOSITIONS
  申请人：Stepan Company

  公开号：EP3504258A1

  公开（公告）日：2019-07-03
• POLYETHER-EPOXIDE POLYMER COMPOSITIONS
  申请人：Stepan Company

  公开号：EP3601406B1

  公开（公告）日：2021-04-14

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