2,4,6-三溴二苯醚 | 155999-95-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4,6-三溴二苯醚
• 英文名称: 2,4,6-tribromodiphenyl ether
• 英文别名: PBDE-30；1,3,5-tribromo-2-phenoxybenzene
• CAS: 155999-95-4
• 化学式: C₁₂H₇Br₃O
• 分子量: 406.899
• InChiKey: TVZAPPGLBLTACB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二苯基溴化碘 、 三溴苯酚 在 sodium hydroxide 作用下， 以 水 为溶剂， 以25%的产率得到2,4,6-三溴二苯醚
  参考文献：
  名称：

  Synthesis and Characterization of 32 Polybrominated Diphenyl Ethers

  摘要：

  DOI：

  10.1021/es9902266

文献信息

• Multifunctional substituted monomers and polyarylene compositions therefrom
  申请人：Hahnfeld L Jerry

  公开号：US20070027280A1

  公开（公告）日：2007-02-01

  A compound useful in the formation of polymeric dielectric films for semiconductor devices and the resulting cured films and devices, said compound comprising i) three or more dienophile groups (A-functional groups) and ii) a single ring structure comprising two conjugated carbon-to-carbon double bonds and a leaving group L (collectively referred to as a B-functional group), characterized in that one A-functional group of one molecule of the compound is capable of reaction under cycloaddition reaction conditions with the B-functional group of a second molecule and elimination of the leaving group L, to thereby form a polymer.

  该化合物在半导体器件的聚合介电膜的形成以及所得到的固化膜和器件中有用，该化合物包括：i) 三个或更多的二烯基基团（A-官能团），和ii) 一个单环结构，其中包括两个共轭的碳-碳双键和一个离去基团L（统称为B-官能团）。其特征在于，该化合物的一个分子的一个A-官能团能够在环加成反应条件下与第二个分子的B-官能团发生反应并消除离去基团L，从而形成聚合物。
• [EN] MULTIFUNCTIONAL SUBSTITUTED MONOMERS AND POLYARYLENE COMPOSITIONS THEREFROM<br/>[FR] MONOMERES SUBSTITUES MULTIFONCTIONNELS ET COMPOSITIONS DE POLYARYLENE COMPRENANT CES MONOMERES
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2004090018A1

  公开（公告）日：2004-10-21

  A compound useful in the formation of polymeric dielectric films for semiconductor devices and the resulting cured films and devices, said compound comprising i) three or more dienophile groups (A-functional groups) and ii) a single ring structure comprising two conjugated carbon-to-carbon double bonds and a leaving group L (collectively referred to as a B-functional group), characterized in that one A-functional group of one molecule of the compound is capable of reaction under cycloaddition reaction conditions with the B-functional group of a second molecule and elimination of the leaving group L, to thereby form a polymer.
• Synthesis and Characterization of 32 Polybrominated Diphenyl Ethers
  作者：Göran Marsh、Jiwei Hu、Eva Jakobsson、Sara Rahm、Ȧke Bergman

  DOI：10.1021/es9902266

  日期：1999.9.1