2,4-二氯-N-[(2,4-二氯苯基)甲基]-N-羟基苯甲胺 | 51850-95-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4-二氯-N-[(2,4-二氯苯基)甲基]-N-羟基苯甲胺
• 英文名称: N,N-Bis(2,4-dichlorobenzyl)hydroxylamine
• 英文别名: N,N-bis[(2,4-dichlorophenyl)methyl]hydroxylamine
• CAS: 51850-95-4
• 化学式: C₁₄H₁₁Cl₄NO
• 分子量: 351.0
• InChiKey: UCOJEGLSMUGXIF-UHFFFAOYSA-N

物化性质

• 沸点：
  482.3±45.0 °C(Predicted)
• 密度：
  1.490±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2928000090

文献信息

• Spandex having low heat-set temperature and materials for their production
  申请人：Bayer MaterialScience LLC

  公开号：EP1671992A1

  公开（公告）日：2006-06-21

  Segmented polyurethane/ureas useful in the production of spandex with improved heat set are produced by chain extending an isocyanate-terminated prepolymer with a diamine chain extender that includes: (1) greater than 25 to 75 equivalent percent of an asymmetric aliphatic and/or cycloaliphatic diamine and (2) a linear diamine such as ethylene diamine in the presence of a solvent. The isocyanate-terminated prepolymer having an isocyanate group content of from about 2.25 to about 4 is produced by reacting a stoichiometric excess of an isocyanate with an isocyanate-reactive component that includes: (1) from about 25 to about 75 equivalent percent of a polyoxypropylene diol having a molecular weight in excess of 1500 Da and an average unsaturation level of less than about 0.03 meq/g and (2) from about 25 to about 75 equivalent percent of a polytetramethylene ether glycol having a molecular weight of at least 600 Da.

  用于生产热固性更好的氨纶的分段聚氨酯/氨纶是通过用二胺扩链剂对异氰酸酯封端预聚物进行扩链而生产的，扩链剂包括：(1) 25%至 75%的不对称脂肪族和/或环脂肪族二胺；(2) 线性二胺，如乙二胺：(1) 超过 25% 至 75% 的不对称脂肪族和/或环脂族二元胺；(2) 在溶剂存在下的线性二元胺，如乙二胺。异氰酸酯封端预聚物具有约 2.25 至约 4 的异氰酸酯基含量，是通过使按化学计量过量的异氰酸酯与异氰酸酯反应组分反应制得的，该反应组分包括：(1) 约 25 至约 4 的异氰酸酯基含量；(2) 约 25 至约 4 的异氰酸酯基含量；(3) 约 25 至约 4 的异氰酸酯基含量：(1)分子量超过 1500 Da 且平均不饱和度低于约 0.03 meq/g 的聚氧丙烯二元醇的约 25%至约 75%的当量；(2)分子量至少为 600 Da 的聚四亚甲基醚二醇的约 25%至约 75%的当量。
• Spandex compositions
  申请人：——

  公开号：US20030088049A1

  公开（公告）日：2003-05-08

  The invention provides an improved spandex that is prepared from a polyurethane that is the reaction product of organic diisocyanates, polymeric glycols, and polyols that have an aromatic functionality, such as alkoxylated phenols. The spandex has improved resistance to high temperature dyeing with minimal loss of physical properties, such as elastic recovery.

  本发明提供了一种改进型氨纶，该氨纶由聚氨酯制备而成，聚氨酯是有机二异氰酸酯、聚合乙二醇和具有芳香族官能团的多元醇（如烷氧基化苯酚）的反应产物。这种氨纶具有更强的耐高温染色性，而弹性恢复等物理性能的损失却很小。
• IMPROVED SPANDEX COMPOSITIONS
  申请人：RADICISPANDEX CORPORATION

  公开号：EP1409564A1

  公开（公告）日：2004-04-21
• EP1409564A4
  申请人：——

  公开号：EP1409564A4

  公开（公告）日：2006-05-03
• US6780958B2
  申请人：——

  公开号：US6780958B2

  公开（公告）日：2004-08-24