Determination of tetragonal-cubic phase boundary of ZrRO (R = Nd, Sm, Y, Er and Yb) BY Raman scattering
作者:Masatomo Yashima、Katsuya Ohtake、Masato Kakihana、Haruo Arashi、Masahiro Yoshimura
DOI:10.1016/0022-3697(95)00085-2
日期:1996.1
Abstract Existing phases of arc-melted ZrO2-X mol%RO1.5 specimens were investigated mainly by Raman spectroscopy, which is sensitive to the phase transition induced by the oxygen displacements (0≤X≤24) R = Nd, Sm, Y, Er and Yb). The tetragonal and monoclinic phases coexisted at X = 2 and 4 for R = Nd, Y, Er and Yb, and at X = 2 for R = Sm. Tetragonal single phase is obtained in the specimens with higher
摘要 电弧熔化 ZrO2-X mol%RO1.5 试样的现有相主要通过拉曼光谱进行研究,拉曼光谱对氧位移引起的相变敏感 (0≤X≤24) R = Nd, Sm, Y,呃和Yb)。对于 R = Nd、Y、Er 和 Yb,四方相和单斜晶相在 X = 2 和 4 处共存,对于 R = Sm,在 X = 2 处共存。在具有较高含量的试样中获得四方单相。轴比ca随着RO1.5含量的增加而降低,在RO1.5含量为14或16mol%时趋于一致。470 cm-1 附近的拉曼峰强度是四方相的特征,随着 RO1.5 含量的增加而降低。由拉曼散射确定的立方-四方相界位于约 X = 18-19 mol%,与掺杂剂种类 R 无关。轴比ca为1的四方相出现在约X=16mol%处。相界的组成位置几乎与掺杂物质 R 无关。