gadolinium vanadate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 镧系有机物
• 英文名称: gadolinium vanadate
• 英文别名: Gadolinium;vanadium;tetrahydrate；gadolinium;vanadium;tetrahydrate
• 化学式: GdO₄V
• 分子量: 272.189
• InChiKey: ZXBBMZRAGRITCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.3
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  gadolinium(III) oxide 、 vanadia 生成 gadolinium vanadate
  参考文献：
  名称：

  BixEu1−xVO4 和 BiyGd1−yVO4 混合氧化物的光谱研究

  摘要：

  摘要 讨论了Bi 3+ 的0 xyxys 2 混合氧化物Bi x Eu 1− x VO 4 和Bi y Gd 1− y VO 4 结晶为锆石型结构。介绍了这些混合氧化物的漫反射光谱研究。观察到的宽带归因于电荷转移过程，Bi x Eu 1− x VO 4 光谱中的尖峰归因于 Eu 3+ 离子的构型内 4 f – 4 f 跃迁。当 Bi 引入 LnVO 4 晶格时，BiLnVO 4 (Ln : Eu 和 Gd) 化合物在较长波长范围内的广泛吸收位移归因于 Bi-VO 4 中心的电荷转移过程，并假设 Jahn -Bi 3+ 激发态的泰勒效应。Bi 3+ 离子的内部压力的概念也用于解释宽的A带位移。

  DOI：

  10.1016/0022-3697(89)90395-8

文献信息

• Non-magnetic ions doping effects in the magnetic properties of zircon-type GdCrO4 compound
  作者：A.C.B. Jesus、J.R. Jesus、E.M. Bittar、J.G.S. Duque、C.T. Meneses

  DOI：10.1016/j.jmmm.2021.167953

  日期：2021.9
• Structural, Spectroscopic, and Magnetic Properties of Eu³⁺-Doped GdVO₄ Nanocrystals Synthesized by a Hydrothermal Method
  作者：Agata Szczeszak、Tomasz Grzyb、Zbigniew Śniadecki、Nina Andrzejewska、Stefan Lis、Michał Matczak、Grzegorz Nowaczyk、Stefan Jurga、Bogdan Idzikowski

  DOI：10.1021/ic500354t

  日期：2014.12.1

  New interesting aspects of the spectroscopic properties, magnetism, and method of synthesis of gadolinium orthovanadates doped with Eu3+ ions are discussed. Gd-1-xEuxVO(4) (x = 0, 0.05, 0.2) bifunctional luminescent materials with complex magnetic properties were synthesized by a microwave-assisted hydrothermal method. Products were formed in situ without previous precipitation. The crystal structures and morphologies of the obtained nanomaterials were analyzed by X-ray diffraction and transmission and scanning electron microscopy. Crystallographic data were analyzed using Rietveld refinement. The products obtained were nanocrystalline with average grain sizes of 70-80 nm. The qualitative and quantitative elemental composition as well as mapping of the nanocrystals was proved using energy-dispersive X-ray spectroscopy. The spectroscopic properties of red-emitting nanophosphors were characterized by their excitation and emission spectra and luminescence decays. Magnetic measurements were performed by means of vibrating sample magnetometry. GdVO4 and Gd0.8Eu0.2VO4 exhibited paramagnetic behavior with a weak influence of antiferromagnetic couplings between rare-earth ions. In the substituted sample, an additional magnetic contribution connected with the population of low-lying excited states of europium was observed.
• Le Bras, M.; Agounaou, M.; Baussart, H., Journal de Chimie Physique et de Physico-Chimie Biologique, <hi>1994</hi>, vol. 91, p. 7 - 36
  作者：Le Bras, M.、Agounaou, M.、Baussart, H.、Gengembre, L.、Leroy, J. M.

  DOI：——

  日期：——