2,6-二新戊基苯胺 | 1196157-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,6-二新戊基苯胺
• 英文名称: 2,6-Dineopentylaniline
• 英文别名: 2,6-bis(2,2-dimethylpropyl)aniline
• CAS: 1196157-86-4
• 化学式: C₁₆H₂₇N
• 分子量: 233.39
• InChiKey: MVMYJQKKCVQHEN-UHFFFAOYSA-N

物化性质

• 熔点：
  41-46°C
• 闪点：
  >110℃

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• WGK Germany：
  3

文献信息

• RUBBER COMPOSITION, RUBBER COMPOSITION FOR TIRE SIDE USE, CROSSLINKED RUBBER COMPOSITION AND TIRE
  申请人：Matsushita Junko

  公开号：US20130324660A1

  公开（公告）日：2013-12-05

  The present invention provides a rubber composition that is used for manufacturing a rubber excellent in weather resistance, fracture resistance and crack growth resistance, and that contains a conjugated diene compound/non-conjugated olefin copolymer, a conjugate diene-based polymer and a non-conjugated diene compound/non-conjugated olefin copolymer, a rubber composition for tire side use using the rubber composition for tire sidewall members, a crosslinked rubber composition obtained by crosslinking the rubber composition, and a tire. The rubber composition includes: (A) a conjugated diene compound/non-conjugated olefin copolymer containing a conjugated diene compound-derived unit by at least 40 mol %; (B) a conjugated diene-based polymer; and (C) a non-conjugated diene compound/non-conjugated olefin copolymer containing an ethylene-propylene-diene rubber.

  本发明提供了一种橡胶组合物，用于制造具有耐候性、抗断裂性和裂纹生长抗性的橡胶，并包含共轭二烯化合物/非共轭烯烃共聚物、共轭二烯基聚合物和非共轭二烯化合物/非共轭烯烃共聚物，用于轮胎侧壁成员的轮胎侧壁使用的橡胶组合物，通过交联橡胶组合物获得的交联橡胶组合物和轮胎。该橡胶组合物包括：(A)含有至少40摩尔％共轭二烯化合物衍生单元的共轭二烯化合物/非共轭烯烃共聚物；(B)共轭二烯基聚合物；和(C)含有乙烯-丙烯-二烯基橡胶的非共轭二烯化合物/非共轭烯烃共聚物。
• POLYMERIZATION CATALYST
  申请人：RIKEN

  公开号：EP1512700A1

  公开（公告）日：2005-03-09

  The present invention relates to a catalyst for polymerization of a conjugated diene or the like, which is composed of a metallocene-type cation complex of a gadolinium compound. Examples of such catalyst include a metallocene-type cation complex of a trivalent gadolinium compound represented by the general formula (I): RaGdXb (wherein, Gd represents gadolinium; R represents a cyclopentadienyl group, a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a fluorenyl group, or a substituted fluorenyl group; X represents an anion; "a" represents an integer of 1 or 2; and "b" represents an integer of 1 or 2). The present invention provides a catalyst by which polymerization of a conjugated diene or copolymerization of a conjugated diene and an aromatic vinyl compound can be carried out efficiently and inexpensively.

  本发明涉及一种用于共轭二烯或类似物聚合的催化剂，该催化剂由钆化合物的茂金属阳离子络合物组成。这种催化剂的例子包括通式 (I) 所代表的三价钆化合物的茂金属阳离子络合物：RaGdXb（其中，Gd 代表钆；R 代表环戊二烯基、取代的环戊二烯基、茚基、取代的茚基、芴基或取代的芴基；X 代表阴离子；"a "代表 1 或 2 的整数；"b "代表 1 或 2 的整数）。本发明提供了一种催化剂，通过该催化剂可以高效、廉价地进行共轭二烯的聚合或共轭二烯与芳香族乙烯基化合物的共聚。
• AROMATIC VINYL COMPOUND-CONJUGATED DIENE COMPOUND COPOLYMER, METHOD FOR PRODUCING THE SAME, RUBBER COMPOSITION AND TIRE
  申请人：Bridgestone Corporation

  公开号：EP2284206A1

  公开（公告）日：2011-02-16

  This invention relates to an aromatic vinyl compound-conjugated diene compound copolymer capable of giving excellent wear resistance and resistance to wet skid to a tire, and more particularly to an aromatic vinyl compound-conjugated diene compound copolymer obtained by an addition polymerization of an aromatic vinyl compound and a conjugated diene compound in the presence of a polymerization catalyst composition comprising at least one specified metallocene complex selected from the group consisting of a metallocene complex represented by the following general formula (I): (wherein M is a lanthanoid element, scandium or yttrium, and CpR is independently a non-substituted or substituted indenyl, and Ra to Rf are independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on, wherein a content of cis-1,4 bond in a conjugated diene compound portion is not less than 80%.

  本发明涉及一种芳香族乙烯基化合物-共轭二烯烃化合物共聚物，该共聚物能使轮胎具有优异的耐磨性和抗湿滑性，特别是涉及一种芳香族乙烯基化合物-共轭二烯烃化合物共聚物，该共聚物是由芳香族乙烯基化合物和共轭二烯烃化合物在聚合催化剂组合物存在下进行加成聚合而得到的，聚合催化剂组合物包括至少一种特定的茂金属络合物，该茂金属络合物选自由下式(I)表示的茂金属络合物组成的组： (其中 M 为镧系元素、钪或钇，CpR 独立地为非取代或取代的茚基，Ra 至 Rf 独立地为碳原子数为 1-3 的烷基或氢原子，L 为中性路易斯碱，w 为 0-3 的整数）等，其中共轭二烯化合物部分中顺式-1,4 键的含量不低于 80%。
• METHOD FOR PRODUCING COPOLYMER
  申请人：Bridgestone Corporation

  公开号：EP2463313A1

  公开（公告）日：2012-06-13

  This invention relates to a method for producing a copolymer of a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound having a high cis-1,4 bond content of a conjugated diene compound portion, and more particularly to a method for producing a copolymer characterized by comprising a step of polymerizing a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound in the presence of a polymerization catalyst composition including at least one complex selected from a metallocene complex represented by the following general formula (I): (wherein M is a lanthanoid element, scandium or yttrium, and CpR is independently a non-substituted or substituted indenyl, and Ra-Rf are independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on.

  本发明涉及一种共轭二烯化合物和共轭二烯化合物以外的非共轭烯烃的共聚物的生产方法，共轭二烯化合物部分具有较高的顺式-1,4键含量、特别是一种生产共聚物的方法，其特征在于包括以下步骤：在聚合催化剂组合物存在下，聚合共轭二烯化合物和共轭二烯化合物以外的未共轭烯烃，该催化剂组合物包括至少一种选自以下通式(I)代表的茂金属络合物的络合物： (其中 M 为镧系元素、钪或钇，CpR 独立地为非取代或取代的茚基，Ra-Rf 独立地为碳原子数为 1-3 的烷基或氢原子，L 为中性路易斯碱，w 为 0-3 的整数）等。
• COPOLYMER, RUBBER COMPOSITION, CROSS-LINKED RUBBER COMPOSITION, AND TIRE
  申请人：Bridgestone Corporation

  公开号：EP2599809A1

  公开（公告）日：2013-06-05

  Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a block copolymer, the conjugated diene compound unit having 1,2 adduct (including 3,4 adduct) content of 5 % or less or the conjugated diene compound unit having a cis-1,4 bond content of more than 92 %, in which preferred examples of the conjugated diene compound include 1,3-butadiene and isopropylene, and preferred examples of the non-conjugated olefin include ethylene, propylene, and 1-butene.

  本发明提供了一种共轭二烯化合物和非共轭烯烃的共聚物，该共聚物为嵌段共聚物，共轭二烯化合物单元的 1，2 加合物（包括 3，4 加合物）含量为 5 % 或以下，或共轭二烯化合物单元的顺式-1、其中共轭二烯化合物的优选实例包括 1,3-丁二烯和异丙烯，非共轭烯烃的优选实例包括乙烯、丙烯和 1-丁烯。