1-Isopropyl-4,4-dimethyl-2-azabutadien | 5339-41-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-Isopropyl-4,4-dimethyl-2-azabutadien
• 英文别名: isobutylidene-(2-methyl-propenyl)-amine；Isobutyliden-(β.β-dimethyl-vinyl)-amin；Isobutyliden-(2-methyl-propenyl)-amin；N-(2,2-Dimethylethyliden)-2,2-dimethylvinylamin；N-Isopropyliden-methyl-N-isobutyliden-amin；2-Methyl-N-isobutyliden-propenylamin；Propenylamine, N-isobutylidene-2-methyl-；2-methyl-N-(2-methylprop-1-enyl)propan-1-imine
• CAS: 5339-41-3
• 化学式: C₈H₁₅N
• 分子量: 125.214
• InChiKey: SXSKAWDSYGQTAC-UHFFFAOYSA-N

物化性质

• 保留指数：
  892;892

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-Isopropyl-4,4-dimethyl-2-azabutadien 在 copper-zinc catalyst 、 氨 作用下， 生成 异丁腈
  参考文献：
  名称：

  US2731488

  摘要：

  公开号：
• 作为产物：
  描述：

  N,N'-Diisobutyliden-1,1-diamino-2-methyl-propan 生成 1-Isopropyl-4,4-dimethyl-2-azabutadien
  参考文献：
  名称：

  Lipp, Justus Liebigs Annalen der Chemie, 1882, vol. 211, p. 352

  摘要：

  DOI：

文献信息

• Volatile corrosion inhibitors for gas lift
  申请人：Petrolite Corporation

  公开号：US05197545A1

  公开（公告）日：1993-03-30

  A method is disclosed for volatile inhibition and transport of inhibitor in the volatile phase to produced liquids of corrosion in a gas lift process in which a lift gas is pumped into a well to facilitate petroleum production of the well. The method comprises introducing to the lift gas a corrosion-inhibiting amount of a dihydrothiazole of the formula ##STR1## wherein R, R', R", R'", and R.sup.4 are independently selected from among hydrogen and alkyl groups of up to about 3 carbon atoms, provided that the total number of carbon atoms of R, R', R", R'" does not exceed about 14.

  本发明公开了一种用于气举过程中抑制挥发性和将抑制剂在挥发性相中输送到生产液体以防止腐蚀的方法。该气举过程中，将举升气体泵入井中以促进井的石油生产。该方法包括向举升气体中引入一定量的抑制腐蚀的二氢噻唑，其化学式为##STR1##其中R、R'、R"、R'"和R4分别独立地选自氢和碳原子数不超过14的烷基，前提是R、R'、R"、R'"的总碳原子数不超过14。
• Substituted 1,11-diaminoundecanes, processes for producing them, and
  申请人：Ciba-Geigy Corporation

  公开号：US04460790A1

  公开（公告）日：1984-07-17

  There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for prducing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.

  描述了一种新型的取代的1,11-二氨基十一烷，特别是公式##STR1##中的那些[R.sub.1是1-12个碳原子的烷基，R.sub.2是氢或1-12个碳原子的烷基，R.sub.3是1-12个碳原子的烷基，4-12个碳原子的环烷基，7或8个碳原子的芳基烷基，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，1-12个碳原子的烷基，4-12个碳原子的环烷基，或未取代或取代的芳基，或R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是3-11个碳原子的亚烷基]，以及生产它们的过程。公式I的化合物例如可用于生产聚合物，特别是聚酰胺。它们也可用作环氧树脂的固化剂。
• 1-Aza-1,5,9-cyclododecatrienes
  申请人：Ciba-Geigy Corporation

  公开号：US04213901A1

  公开（公告）日：1980-07-22

  Compounds of the formula ##STR1## and a process for their preparation by reacting azabutadienes with dienes, especially 1,3-butadiene, in the presence of catalysts are described. In the formula I, R.sub.1 and R.sub.3 independently of one another are hydrogen or alkyl having 1-8 C atoms and R.sub.2 and R.sub.4 independently of one another are alkyl having 1-8 C atoms, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together with the bonding C atom form a cycloaliphatic ring having 4-8 C atoms, and R.sub.5 and R.sub.6 independently of one another are hydrogen or alkyl having 1-4 C atoms. The compounds of the formula I are valuable intermediates for the preparation of active compounds for combating plant pests.

  本文描述了式 ##STR1## 的化合物及其制备方法，所述方法是通过在催化剂的存在下将氮丁二烯与二烯（特别是1,3-丁二烯）反应而得。在公式I中，R.sub.1和R.sub.3分别独立地为氢或具有1-8个碳原子的烷基，R.sub.2和R.sub.4分别独立地为具有1-8个碳原子的烷基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4与键合的碳原子一起形成具有4-8个碳原子的环脂肪环，而R.sub.5和R.sub.6分别独立地为氢或具有1-4个碳原子的烷基。公式I的化合物是制备用于防治植物害虫的活性化合物的有价值的中间体。
• Substituted 1,11-diaminoundecanes, processes for producing them and
  申请人：Ciba-Geigy Corporation

  公开号：US04484004A1

  公开（公告）日：1984-11-20

  There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for producing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.

  描述了新型的取代的1,11-二氨基十一烷，特别是公式##STR1##中的那些[R.sub.1是具有1-12个C原子的烷基，R.sub.2是氢或具有1-12个C原子的烷基，R.sub.3是具有1-12个C原子的烷基，具有4-12个C原子的环烷基，具有7或8个C原子的芳基烷基，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，具有1-12个C原子的烷基，具有4-12个C原子的环烷基，或未取代或取代的芳基，或R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是具有3-11个C原子的亚烷基]，以及制备它们的过程。公式I的化合物例如可用于生产聚缩酸酐产品，特别是聚酰胺。它们也可用作环氧树脂的固化剂。
• Transparent copolyamide from 1,10-disubstituted C.sub.11 diamine
  申请人：Ciba-Geigy Corporation

  公开号：US04258176A1

  公开（公告）日：1981-03-24

  There are described transparent copolyamides which are obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine ##STR1## and isophthalic acid or terephthalic acid, or a mixture of isophthalic acid and terephthalic acid, with a mixture (B) consisting of essentially stoichiometric amounts of a diamine ##STR2## and terephthalic acid or a mixture of terephthalic acid and isophthalic acid, or with a mixture (C) consisting of essentially stoichiometric amounts of a diamine ##STR3## and terephthalic acid or isophthalic acid or mixtures thereof, wherein R', R" and R.sub.1 to R.sub.11 have the meanings given in claim 1. The novel copolyamides are distinguished by good thermoplastic processing characteristics, by low water absorption and by good stability to hydrolysis, and are suitable for producing transparent moulded articles.

  描述了一种透明的共聚酰胺，该共聚酰胺是通过反应混合物(A)获得的，该混合物包含本质上等量的二胺##STR1##和苯二甲酸或对苯二甲酸，或对苯二甲酸和苯二甲酸的混合物，与本质上等量的二胺混合物(B)反应，该混合物包含苯二甲酸或对苯二甲酸或对苯二甲酸和苯二甲酸的混合物，或与本质上等量的混合物(C)反应，该混合物包含二胺##STR3##和苯二甲酸或对苯二甲酸或其混合物，其中R'，R"和R1到R11具有权利要求1中给出的含义。这种新型共聚酰胺具有良好的热塑性加工特性，低吸水性和良好的耐水解稳定性，适用于生产透明的模制品。