Tri-(γ,γ-dimethylallyl)-amin | 16347-29-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Tri-(γ,γ-dimethylallyl)-amin
• 英文别名: 3-methyl-N,N-bis(3-methylbut-2-enyl)but-2-en-1-amine
• CAS: 16347-29-8
• 化学式: C₁₅H₂₇N
• 分子量: 221.386
• InChiKey: VSZZZLGWYQBMAU-UHFFFAOYSA-N

物化性质

• 沸点：
  284.2±9.0 °C(Predicted)
• 密度：
  0.839±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-甲基-2-丁烯胺 、 1-溴-3-甲基-2-丁烯 生成 Tri-(γ,γ-dimethylallyl)-amin
  参考文献：
  名称：

  细胞分裂素：结构/活性关系

  摘要：

  摘要 69 种化合物，主要是嘌呤衍生物和密切相关的物质，在烟草生物测定中测试了促进生长和调节器官形成的作用，以确定化学结构和细胞分裂素活性之间的关系。本研究共合成了 43 种物质，其中 13 种为首次报道。N 6 -烷基腺嘌呤 (I) 的活性在很宽的浓度范围内变化，这取决于烷基链的长度。从腺嘌呤开始，在 ⩾ 200 μM 处可检测到，活性随着链长的增加而增加，对于 6-戊基氨基嘌呤可在约 20 处检测到最佳。0–001 μM，然后降低到几乎检测不到 6-癸基氨基嘌呤的水平。在侧链中引入极性基团的结果不一定是活性降低。一个羟基，如在玉米素 (Id) 中一样，如果 6-(γ,γ-二甲基烯丙基氨基) 嘌呤 (Ib) 对其产生影响，则可提高其活性；两个羟基，如 6-(2,3-dihydroxy-3-methylbutylamino)purine 中的活性强烈降低。6-异戊基氨基嘌呤与 6-(γ,γ-二甲基烯丙基氨基)

  DOI：

  10.1016/s0031-9422(00)86080-x

文献信息

• PROCESS FOR PRODUCING 3-METHYLTHIOPROPANAL
  申请人：AZEMI Takushi

  公开号：US20100256419A1

  公开（公告）日：2010-10-07

  A process is provided capable of producing 3-methylthiopropanal with subgeneration of high-boiling impurities being favorably inhibited. The process for producing 3-methylthiopropanal, includes reacting acrolein with methylmercaptan in the presence of a triallylamine compound represented by the formula (I): wherein each of R 1 to R 3 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. The reaction of acrolein with methylmercaptan is preferably performed further in the presence of an organic acid. The triallylamine compound represented by the formula (I) is preferably used in an amount of from 0.01 to 1.0 mol based on one mole of the organic acid and in an amount of from 0.1 to 2.0 mmoles based on one mole of methylmercaptan.

  提供了一种能够在有利地抑制高沸点杂质的情况下生产3-甲基硫代丙醛的过程。生产3-甲基硫代丙醛的过程包括在三烯丙胺化合物的存在下，用丙烯醛和甲硫醇反应，所述三烯丙胺化合物由式(I)表示：其中，R1至R3中的每一个表示氢原子或1至4个碳原子的烷基。丙烯醛和甲硫醇的反应最好在有机酸的存在下进一步进行。式(I)表示的三烯丙胺化合物最好以每摩尔有机酸0.01至1.0摩尔的量和每摩尔甲硫醇0.1至2.0毫摩尔的量使用。
• PROCESS FOR PREPARING 3-(METHYLTHIO)PROPANAL
  申请人：AZEMI Takushi

  公开号：US20120022295A1

  公开（公告）日：2012-01-26

  The present invention provides a process for preparing 3-(methylthio)propanal which can sufficiently decrease the production of high-boiling impurities as a by-product. The process comprises reacting acrolein and methyl mercaptan in the presence of Allylamines (I), Triallylamines (II), and preferably an optional organic acid. The preferred amount of Allylamines (I) is 0.001 to 0.50 mol per 1 mol of Triallylamines (II).

  本发明提供了一种制备3-(甲硫基)丙醛的方法，该方法可以充分降低高沸点杂质的产生。该方法包括在Allylamines (I)、Triallylamines (II)和（优选的）有机酸的存在下，使丙烯醛和甲硫醇反应。所述Allylamines (I)的优选量为每1摩尔Triallylamines (II)中0.001至0.50摩尔。
• GOLD CATALYZED HYDROAMINATION OF ALKYNES AND ALLENES
  申请人：Bertrand Guy

  公开号：US20110166349A1

  公开（公告）日：2011-07-07

  Methods are provided for the catalytic hydroamination of compounds having an alkyne or allene functional group, in which the compound is contacted with ammonia or an amine in the presence of a catalytic amount of a gold complex under conditions sufficient for hydroamination to occur.

  本发明提供了一种催化氢胺化具有炔基或联烯基团的化合物的方法，其中在催化金配合物的催化作用下，将化合物与氨或胺接触，在足够的氢胺化条件下进行反应。
• METHODS OF COATING A LOW SURFACE ENERGY SUBSTRATE
  申请人：Allen Warrick James David

  公开号：US20140370279A1

  公开（公告）日：2014-12-18

  According to the invention there is provided a method of coating a low surface energy substrate including the steps of: a) providing a polymeric precursor which includes a group of sub-formula (I) where R 1 is i) CR a , where R a is hydrogen or alkyl, ii) a group S(0) p R 13 , or SiR 14 where R 13 and R 14 are independently selected from hydrogen or hydrocarbyl, p is 0, 1 or 2 and q is 1 or 2, iii) C(0)N, S(0) 2 N, C(0)ON, CH 2 ON, or CH═CHR C N where R c is an electron withdrawing group, or iv) OC(0)CH, C(0)OCH or S(0)2CH; in which R 12 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or formula (II) R 2 and R 3 are independently selected from (CR 7 R 8 )n, or a group CR 9 R 10 , CR 7 R 8 CR 9 R 10 or CR 9 R 10 CR 7 R 8 where n is 0, 1 or 2, R 7 and R 8 are independently selected from hydrogen or alkyl, and either one of R 9 or R 10 is hydrogen and the other is an electron withdrawing group, or R 9 and R 10 together form an electron withdrawing group; R 4 and R 5 are independently selected from CH or CR 11 where CR 11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X 1 is a group CX 2 X 3 where the dotted line bond to which it is attached is absent and a group CX 2 where the dotted line to which it is attached is present, Y 1 is a group CY 2 Y 3 where the dotted line to which it is attached is absent and a group CY 2 where the dotted line to which it is attached is present, and X 2, X 3 , Y 2 and Y 3 are independently selected from hydrogen, fluorine or other substituents; and b) either (i) coating the low surface energy substrate with the polymeric precursor and polymerising the polymeric precursor to form a polymeric coating, or (ii) polymerising the polymeric precursor and contacting the polymerised polymeric precursor with a low surface energy substrate to form a polymeric coating on the low surface energy substrate.

  根据本发明提供了一种涂覆低表面能基材料的方法，包括以下步骤：a）提供一个聚合物前体，其中包括一个亚公式（I）的基团，其中R1是i）CRa，其中Ra是氢或烷基，ii）一个S（0）pR13基团，或SiR14，其中R13和R14独立选择自氢或烃基，p为0、1或2，q为1或2，iii）C（0）N，S（0）2N，C（0）ON，CH2ON或CH═CHRCN，其中Rc是一个电子提取基团，或iv）OC（0）CH，C（0）OCH或S（0）2CH；其中R12选择自氢、卤素、硝基、烃基（可选择性地取代或插入功能基团）或公式（II）R2和R3独立选择自（CR7R8）n，或一个CR9R10基团，CR7R8CR9R10或CR9R10CR7R8基团，其中n为0、1或2，R7和R8独立选择自氢或烷基，R9或R10之一为氢，另一个为电子提取基团，或R9和R10一起形成电子提取基团；R4和R5独立选择自CH或CR11，其中CR11是电子提取基团，虚线表示有或无化学键，X1是一个CX2X3基团，其中它所附着的虚线键不存在，以及一个CX2基团，其中它所附着的虚线存在，Y1是一个CY2Y3基团，其中它所附着的虚线键不存在，以及一个CY2基团，其中它所附着的虚线存在，X2、X3、Y2和Y3独立选择自氢、氟或其他取代基团；和b）或者（i）用聚合物前体涂覆低表面能基材料并聚合聚合物前体形成聚合物涂层，或者（ii）聚合聚合物前体并将聚合后的聚合物前体与低表面能基材料接触以形成低表面能基材料上的聚合物涂层。
• Process for producing 3-methylthiopropanal
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2239252A1

  公开（公告）日：2010-10-13

  An object of the present invention is to provide a process capable of producing 3-methylthiopropanal with subgeneration of high-boiling impurities being favorably inhibited. The present invention provides a process for producing 3-methylthiopropanal, comprising reacting acrolein with methylmercaptan in the presence of a triallylamine compound represented by the formula (I): wherein each of R1 to R3 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. The reaction of acrolein with methylmercaptan is preferably performed further in the presence of an organic acid. The triallylamine compound represented by the formula (I) is preferably used in an amount of from 0.01 to 1.0 mol based on one mole of the organic acid and in an amount of from 0.1 to 2.0 mmoles based on one mole of methylmercaptan.

  本发明的目的是提供一种能够生产3-甲硫基丙醛的工艺，该工艺能够有效地抑制高沸点杂质的亚生成。 本发明提供了一种生产 3-甲硫基丙醛的工艺，包括在式 (I) 所代表的三烯丙基胺化合物存在下，使丙烯醛与甲硫醇反应： 其中 R1 至 R3 各代表一个氢原子或一个具有 1 至 4 个碳原子的烷基。丙烯醛与甲硫醇的反应最好在有机酸存在下进一步进行。式 (I) 所代表的三烯丙基胺化合物的用量最好为 0.01 至 1.0 摩尔（以一摩尔有机酸计）和 0.1 至 2.0 毫摩尔（以一摩尔甲硫醇计）。