N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine | 875634-85-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine
• 英文别名: 6-phenyl-2-N,4-N-dipyridin-2-yl-1,3,5-triazine-2,4-diamine
• CAS: 875634-85-8
• 化学式: C₁₉H₁₅N₇
• 分子量: 341.375
• InChiKey: VDHYNSAGBHIAOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.5
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine 在 potassium tert-butylate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 26.0h， 生成
  参考文献：
  名称：

  铬催化甲基酮与环酮的交叉偶联选择性合成 β-支链 β,γ-不饱和酮

  摘要：

  据报道，甲基酮与环酮在铬催化下交叉偶联生成 β-支链 β,γ-不饱和酮。有趣的是，即使在可能存在产物混合物的反应中，也会形成单交叉羟醛缩合产物。该反应具有高度化学选择性和区域选择性。这种催化路线提供了一个独特的机会，将酮的合成挑战交叉偶联反应和烯烃迁移反应的化学集成到反应釜中。

  DOI：

  10.1021/acs.orglett.3c03960
• 作为产物：
  描述：

  苯基溴化镁 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 生成 N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine
  参考文献：
  名称：

  铬催化甲基酮与环酮的交叉偶联选择性合成 β-支链 β,γ-不饱和酮

  摘要：

  据报道，甲基酮与环酮在铬催化下交叉偶联生成 β-支链 β,γ-不饱和酮。有趣的是，即使在可能存在产物混合物的反应中，也会形成单交叉羟醛缩合产物。该反应具有高度化学选择性和区域选择性。这种催化路线提供了一个独特的机会，将酮的合成挑战交叉偶联反应和烯烃迁移反应的化学集成到反应釜中。

  DOI：

  10.1021/acs.orglett.3c03960

文献信息

• Three copper(II) complexes constructed from a new 1,3,5-triazine derivative ligand
  作者：Ya-Pan Wu、Cui-Juan Wang、Yao-Yu Wang、Ping Liu、Wei-Ping Wu、Qi-Zhen Shi、Shie-Ming Peng

  DOI：10.1016/j.poly.2006.07.012

  日期：2006.12

  Three new complexes [Cu(dpdapt)(Hhbd)] center dot 6H(2)O}(n), (1) (dpdapt = N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine, Hhbd = 2-hydroxybutanedioicate dianion), [Cu(dpdaPt)(SO4)]center dot 2H(2)O (2) and [Cu(dpdapt)(oxa)] center dot H2O (3) (oxa = oxalate dianion) have been synthesized and structurally characterized. The non-covalent interactions of pi-pi stacking and hydrogen bonding extend complexes 1-3 into supramolecular architectures, where 1 self-assembles into a ID polymeric chain by dicarboxylate bridges and exhibits a 3D framework with 1D open channels, while complexes 2 and 3 display 2D wavelike networks. Interestingly, in 1, the host framework encapsulates hexameric water clusters that are connected into ID arrays by supramolecular association along the ID open channels. The UV/vis, IR spectra, fluorescence and TG analysis for complexes 1, 2 and 3 are also discussed. (c) 2006 Elsevier Ltd. All rights reserved.
• A novel ligand N,N′-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine (dpdapt) and its complexes: [Cu(dpdapt)Cl2] and [Cu(dpdapt)(NO3)(H2O)]·NO3·H2O
  作者：Cui-Juan Wang、Yao-Yu Wang、Hai-Rui Ma、Hui Wang、Qi-Zhen Shi、Shie-Ming Peng

  DOI：10.1016/j.poly.2005.06.061

  日期：2006.1

  The novel ligand N,N'-di(2-pyridyl)-2,4-diamino-6-phenyl-1,3,5-triazine (dpdapt) has been synthesized and the reactions of CuCl2 center dot 2H(2)O and Cu(NO3)(2) - 8H(2)O with the new ligand afforded two crystalline forms [Cu(dpdapt)Cl-2] (1) and (Cu(dpdapt)(NO3)(H2O)] center dot NO3 center dot H2O (2), respectively. The molecular structures of 1 and 2 were established by single-crystal X-ray diffraction studies. The copper(II) atoms in complexes 1 and 2 are both five-coordinated in trigonal bipyramidal environments. In 1, antiparallel dimers construct a two-dimensional supramolecular architecture by pi-pi stacking and hydrogen bonding, whereas 2 is connected by the same interactions to form a three-dimensional supramolecular framework. Quantum chemical calculations have been performed using Density Functional Theory (DFT) in order to gain some insight about the coordination behavior of dpdapt and complex 1. (c) 2005 Elsevier Ltd. All rights reserved.
• Chromium-Catalyzed Cross-Coupling of Methyl Ketones with Cyclic Ketones toward the Selective Synthesis of β-Branched β,γ-Unsaturated Ketones
  作者：Priyanka Adhikari、Nitumoni Hazarika、Kalishankar Bhattacharyya、Animesh Das

  DOI：10.1021/acs.orglett.3c03960

  日期：2024.1.12

  Chromium-catalyzed cross-coupling of methyl ketones with cyclic ketones to β-branched β,γ-unsaturated ketones are reported. Interestingly, single-crossed aldol condensation products are formed, even in reactions in which a mixture of products is possible. The reaction is highly chemoselective and regioselective. This catalytic route gives a unique opportunity to integrate the chemistry of the synthetic

  据报道，甲基酮与环酮在铬催化下交叉偶联生成 β-支链 β,γ-不饱和酮。有趣的是，即使在可能存在产物混合物的反应中，也会形成单交叉羟醛缩合产物。该反应具有高度化学选择性和区域选择性。这种催化路线提供了一个独特的机会，将酮的合成挑战交叉偶联反应和烯烃迁移反应的化学集成到反应釜中。