N-crotylallylamine | 97206-58-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-crotylallylamine
• 英文别名: (2E)-N-Allylbut-2-en-1-amine；(E)-N-prop-2-enylbut-2-en-1-amine
• CAS: 97206-58-1
• 化学式: C₇H₁₃N
• 分子量: 111.187
• InChiKey: IJXDSBWQEQWQNX-HWKANZROSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-crotylallylamine 在 正丁基锂 、 zirconocene dichloride 、 potassium carbonate 作用下， 以 四氢呋喃 、 正己烷 、 乙腈 为溶剂， 反应 4.0h， 生成 trans-1-Benzyl-4-vinylpyrrolidin-3-ylacetaldehyde
  参考文献：
  名称：

  使用钛和锆介导的二烯金属环化方法立体选择性地制备取代的吡咯烷：（-）-α-海藻酸的全合成

  摘要：

  锆和钛介导的二烯金属环化-消除-官能化已被比较，对比和用于制备3,4-二取代和2,3,4-三取代 吡咯烷具有高收率和出色的立体选择性。锆介导的方法已被用作部分合成（-）-α-海藻酸的关键步骤，从D-丝氨酸，但关键的金属环化顺序进行时立体声控制较差。相比之下，（-）-α-海藻酸的总合成从大号丝氨酸使用钛介导的环化序列完成了该反应，该序列进行了出色的立体控制。新型类胡萝卜素和哌啶 也有报道。

  DOI：

  10.1039/b005853j
• 作为产物：
  描述：

  (E)-巴豆氯 、 丙烯胺 以73%的产率得到N-crotylallylamine
  参考文献：
  名称：

  Crozet, Michel P.; Kaafarani, Mustapha; Surzur, Jean-Marie, Bulletin de la Societe Chimique de France, 1984, vol. 2, # 9-10, p. 390 - 398

  摘要：

  DOI：

文献信息

• CROZET, M. P.;KAAFARANI, MUSTAPHA;SURZUR, J. M., BULL. SOC. CHIM. FR., 1984, N 9-10, 390-398
  作者：CROZET, M. P.、KAAFARANI, MUSTAPHA、SURZUR, J. M.

  DOI：——

  日期：——
• METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS
  申请人：SCHRODI Yann

  公开号：US20170022232A1

  公开（公告）日：2017-01-26

  Synthetic methods for the in-situ formation of olefin metathesis catalysts are disclosed, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. In one aspect, a method is provided for synthesizing an organometallic compound of the formula comprising contacting a precursor compound of the formula (X 1 X 2 ML j L 1 k L 3 m ) i with an acetylenic compound comprising a chelating moiety, optionally, in the presence of a neutral electron donor, wherein M is a Group 8 transition metal, L, L 1 , L 2 , and L 3 are neutral electron donors, X 1 and X 2 are anionic ligands, j is 1, 2, or 3; k is zero, 1, or 2; m is zero or 1; n is 1 or 2; and i is an integer; with the proviso that k is zero when the precursor compound is contacted with the acetylenic compound in the presence of the neutral electron donor, and R 1 and R 2 are independently selected from hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, substituted heteroatom-containing hydrocarbyl, and functional groups, wherein R 1 and R 2 are linked and together form one or more cyclic groups, R 2 and L 2 are linked and together form one or more cyclic groups, and any other two or more of X 1 , X 2 , L 1 , L 2 , L 3 , R 1 , and R 2 can be taken together to form one or more cyclic groups. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.
• CATIONIC POLYMERS AND POROUS MATERIALS
  申请人：Saudi Arabian Oil Company

  公开号：US20170114157A1

  公开（公告）日：2017-04-27

  According to one or more embodiments, cationic polymers may be produced which include one or more monomers containing cations. Such cationic polymers may be utilized as structure directing agents to form mesoporous zeolites. The mesoporous zeolites may include micropores as well as mesopores, and may have a surface area of greater than 350 m 2 /g and a pore volume of greater than 0.3 cm 3 /g. Also described are core/shell zeolites, where at least the shell portion includes a mesoporous zeolite material.
• Crozet, Michel P.; Kaafarani, Mustapha; Surzur, Jean-Marie, Bulletin de la Societe Chimique de France, 1984, vol. 2, # 9-10, p. 390 - 398
  作者：Crozet, Michel P.、Kaafarani, Mustapha、Surzur, Jean-Marie

  DOI：——

  日期：——
• The stereoselective preparation of substituted pyrrolidines using titanium- and zirconium-mediated diene metallabicyclisation methodology: the total synthesis of (−)-α-kainic acid
  作者：Andrew D. Campbell、Tony M. Raynham、Richard J. K. Taylor

  DOI：10.1039/b005853j

  日期：——

  employed as the key step in a partial synthesis of (−)-α-kainic acid starting from D-serine, but the key metallabicyclisation sequence proceeded with poor stereocontrol. By contrast, the total synthesis of (−)-α-kainic acid starting from L-serine was accomplished using a titanium-mediated cyclisation sequence which proceeded with excellent stereocontrol. Novel kainoids and piperidines are also reported

  锆和钛介导的二烯金属环化-消除-官能化已被比较，对比和用于制备3,4-二取代和2,3,4-三取代 吡咯烷具有高收率和出色的立体选择性。锆介导的方法已被用作部分合成（-）-α-海藻酸的关键步骤，从D-丝氨酸，但关键的金属环化顺序进行时立体声控制较差。相比之下，（-）-α-海藻酸的总合成从大号丝氨酸使用钛介导的环化序列完成了该反应，该序列进行了出色的立体控制。新型类胡萝卜素和哌啶 也有报道。