2-(4'-二乙基氨基苯基)苯并噻唑 | 10205-57-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 中文名称: 2-(4'-二乙基氨基苯基)苯并噻唑
• 英文名称: 4-(2-benzothiazolyl)-N,N-diethylbenzenamine
• 英文别名: 2-(p-Diethylamino-phenyl)-benzothiazol；2-(4-Diethylaminophenyl)benzothiazol；N,N-diethyl-4-benzothiazol-2-yl-aniline；N,N-Diaethyl-4-benzothiazol-2-yl-anilin；2-(4-Diethylaminophenyl)benzothiazole；2-(4'-Diethylaminophenyl)benzothiazole；4-(1,3-benzothiazol-2-yl)-N,N-diethylaniline
• CAS: 10205-57-9
• 化学式: C₁₇H₁₈N₂S
• 分子量: 282.409
• InChiKey: ADRCREMWPUFGDU-UHFFFAOYSA-N

物化性质

• 熔点：
  125 °C(Solv: ethanol (64-17-5))
• 沸点：
  436.8±47.0 °C(Predicted)
• 密度：
  1.164±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  44.4
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2934999090

反应信息

• 作为产物：
  描述：

  N,N-二乙基-4-氨基苯甲醛 、 2-氨基苯硫醇 在 对甲苯磺酸 作用下， 以 PEG-200/400 为溶剂， 反应 0.17h， 以97%的产率得到2-(4'-二乙基氨基苯基)苯并噻唑
  参考文献：
  名称：

  在 Peg 200 或 Peg 400 中微波辐射下合成 2-芳基苯并噻唑的新型绿色工艺

  摘要：

  已经开发了一种改进的绿色程序，用于通过在微波辐射下在 PEG 200/400 中缩合等量的 2,2'-二氨基二苯基二硫化物或 2-氨基苯硫酚和各种芳香醛来合成 2-芳基和 2-杂芳基苯并噻唑。无论起始化合物的状态（液体或固体）或芳环中取代基的性质如何，该方法都允许以高产率和高纯度合成 2-芳基苯并噻唑。

  DOI：

  10.1080/10426501003598648

文献信息

• Novel Green Procedure for the Synthesis of 2-Arylbenzothiazoles Under Microwave Irradiation in Peg 200 Or Peg 400
  作者：Todor G. Deligeorgiev、Stefka Kaloyanova、Aleksey Vasilev、Juan J. Vaquero

  DOI：10.1080/10426501003598648

  日期：2010.10.28

  An improved green procedure for the synthesis of 2-aryl- and 2-hetarylbenzothiazoles by condensation of equivalent amounts of 2,2′-diaminodiphenyldisulfides or 2-aminothiophenols and various aromatic aldehydes in PEG 200/400 under microwave irradiation has been developed. This method allows the synthesis of 2-arylbenzothiazoles in high yields and with high purity regardless of the state of the starting

  已经开发了一种改进的绿色程序，用于通过在微波辐射下在 PEG 200/400 中缩合等量的 2,2'-二氨基二苯基二硫化物或 2-氨基苯硫酚和各种芳香醛来合成 2-芳基和 2-杂芳基苯并噻唑。无论起始化合物的状态（液体或固体）或芳环中取代基的性质如何，该方法都允许以高产率和高纯度合成 2-芳基苯并噻唑。
• One-pot Synthesis of Benzimidazoles and Benzothiazoles in the Presence of Fe(HSO₄)₃as a New and Efficient Oxidant
  作者：Hossein Eshghi、Mohammad Rahimizadeh、Ali Shiri、Parisa Sedaghat

  DOI：10.5012/bkcs.2012.33.2.515

  日期：2012.2.20

  December 7, 2011A series of substituted benzimidazoles and benzothiazoles were prepared through the one-pot reaction of o-phenylenediamine and o-aminothiophenol with various aldehydes in the presence of ferric hydrogensulfateboth in EtOH and water as solvent. The reactions proceed smoothly in excellent yield, high chemoselectivityand with an easy work-up.Key Words : Benzimidazole, Benzothiazole, Fe(HSO

  E-mail: [e-mail] 2011年9月5日接收，2011年12月7日接受 邻苯二胺和邻氨基苯硫酚与各种醛类在苯二胺存在下的一锅反应制备一系列取代苯并咪唑和苯并噻唑硫酸氢铁在乙醇和水中作为溶剂。反应顺利进行，收率高，化学选择性高，后处理简单。关键词：苯并咪唑，苯并噻唑，Fe(HSO)
• COLORED RESIN COMPOSITIONS FOR COLOR FILTER, COLOR FILTER, ORGANIC EL DISPLAY, AND LIQUID-CRYSTAL DISPLAY DEVICE
  申请人：SAKO Naoki

  公开号：US20110049444A1

  公开（公告）日：2011-03-03

  A colored resin composition is provided which is capable of providing blue pixels of a color filter that have excellent light resistance and which satisfies heat resistance required in color display production steps. A color filter having blue pixels with excellent color purity and transmittance and an organic EL display and a liquid-crystal display device both having satisfactory blue purity are also provided by using the colored resin composition. The colored resin composition for color filter includes (a) a binder resin, (b) a solvent, and a triarylmethane type coloring matter of a specific structure represented by general formula (I). The color filter, organic EL display, and liquid-crystal display device are produced using the colored resin composition.

  提供了一种彩色树脂组合物，能够提供具有优异光稳定性的蓝色像素的颜色滤光片，并满足彩色显示生产步骤所需的耐热性。通过使用该彩色树脂组合物，还提供了具有优异色纯度和透过率的蓝色像素的颜色滤光片，以及具有令人满意的蓝色纯度的有机EL显示器和液晶显示器设备。颜色滤光片的彩色树脂组合物包括（a）粘合剂树脂，（b）溶剂，以及由通式（I）表示的具有特定结构的三芳基甲烷型着色物。使用该彩色树脂组合物制备了颜色滤光片、有机EL显示器和液晶显示器设备。
• Photopolymerizable composition
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0138187A2

  公开（公告）日：1985-04-24

  A photopolymerizable composition comprising an addition-polymerizable compound having at least one ethylenically unsaturated double bond and a photopolymerization initiator, characterized in that the initiator comprises (a) a compound of the formula: wherein R1 and R2 are alkyl group, n is 1, 2 or 3 and ring A is an aromatic ring containing nitrogen atom, and (b) hexaarylbiimidazole. The initiator may additionally contain a thiol of the formula: wherein Z is -0-, -S- or -NH-. The composition is not only highly sensitive to ultraviolet ray but also highly stable in storage.

  一种可光聚合的组合物，包括至少有一个乙烯不饱和双键的可加成聚合的化合物和一种光聚合引发剂，其特征在于引发剂包括(a)式中R1和R2为烷基，n为1、2或3，环A为含氮原子的芳香环的化合物，和(b)六芳基比咪唑。 引发剂还可含有式中Z为-0-、-S-或-NH-的硫醇。 该组合物不仅对紫外线高度敏感，而且在储存中高度稳定。
• POLYMERIZABLE COMPOSITION FOR COLOR FILTER
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0758097A1

  公开（公告）日：1997-02-12

  The present invention provides a polymerizable composition for a color filter, which comprises a (meth)acrylate copolymer containing alicyclic (meth)acryloyl groups in its side chains, a compound having at least one ethylenically unsaturated double bond, a photopolymerization initiator and a colorant, a color filter obtained by coating the composition on a glass substrate, followed by exposure and development; and a method for producing a color filter, which comprises coating the composition on a glass substrate, followed by exposure and development. The polymerizable composition of the present invention is highly sensitive and excellent in chemical resistance. Accordingly, according to the present invention, it is possible to produce a color filter of a high quality without a protective layer such as an oxygen-shielding film.

  本发明提供了一种用于彩色滤光片的可聚合组合物，该组合物包括侧链中含有脂环族（甲基）丙烯酰基的（甲基）丙烯酸酯共聚物、具有至少一个乙烯不饱和双键的化合物、光聚合引发剂和着色剂；通过将该组合物涂在玻璃基板上，然后进行曝光和显影而获得彩色滤光片；以及一种生产彩色滤光片的方法，该方法包括将该组合物涂在玻璃基板上，然后进行曝光和显影。 本发明的可聚合组合物具有高灵敏度和优异的耐化学性。因此，根据本发明，可以在不使用氧屏蔽膜等保护层的情况下生产出高质量的彩色滤光片。