terephthal-bis-butylaniline | 10368-06-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: terephthal-bis-butylaniline
• 英文别名: N,N'-dibutyl-p-phenylenediamine；N,N'-Dibutyl-p-phenylendiamin；N,n'-di-n-butyl-p-phenylenediamine；N1,N4-Dibutyl-1,4-benzenediamine；1-N,4-N-dibutylbenzene-1,4-diamine
• CAS: 10368-06-6
• 化学式: C₁₄H₂₄N₂
• 分子量: 220.358
• InChiKey: XWHKJSDRWVTJCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  terephthal-bis-butylaniline 、 乙酸酐 生成 N,N'-dibutyl-N,N'-p-phenylene-bis-acetamide
  参考文献：
  名称：

  Horyna; Cerny, Collection of Czechoslovak Chemical Communications, 1956, vol. 21, p. 906,910

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-ditosyl-p-phenylenediamine 在 sodium hydroxide 、 硫酸 、 溶剂黄146 作用下， 生成 terephthal-bis-butylaniline
  参考文献：
  名称：

  N,N'-Di-n-butyl-p-phenylenediamine

  摘要：

  DOI：

  10.1021/ja01148a510

文献信息

• USE OF NITROGEN COMPOUNDS QUATERNISED WITH ALKYLENE OXIDE AND HYDROCARBYL-SUBSTITUTED POLYCARBOXYLIC ACID AS ADDITIVES IN FUELS AND LUBRICANTS
  申请人：BASF SE

  公开号：US20160130514A1

  公开（公告）日：2016-05-12

  The invention relates to the use of quaternized nitrogen compounds as a fuel and lubricant additive or kerosene additive, such as in particular as a detergent additive, for decreasing or preventing deposits in the injection systems of direct-injection diesel engines, in particular in common rail injection systems, for decreasing the fuel consumption of direct-injection diesel engines, in particular of diesel engines having common rail injection systems, and for minimizing the power loss in direct-injection diesel engines, in particular in diesel engines having common rail injection systems; the invention further relates to the use as an additive for petrol, in particular for operation of DISI engines.

  该发明涉及将季铵化氮化合物用作燃料和润滑剂添加剂或煤油添加剂，特别是作为清洁剂添加剂，用于减少或预防直喷柴油发动机的喷射系统中的沉积物，在特定是在共轨喷射系统中，用于降低直喷柴油发动机的燃料消耗，特别是具有共轨喷射系统的柴油发动机，并用于减少直喷柴油发动机的功率损失，特别是在具有共轨喷射系统的柴油发动机中；该发明还涉及将其用作汽油添加剂，特别是用于DISI发动机的运行。
• Efficient nickel-catalysed<i>N</i>-alkylation of amines with alcohols
  作者：Anastasiia Afanasenko、Saravanakumar Elangovan、Marc C. A. Stuart、Giuseppe Bonura、Francesco Frusteri、Katalin Barta

  DOI：10.1039/c8cy01200h

  日期：——

  selective N-alkylation of amines with alcohols, that is in situ generated from Ni(COD)2 and KOH under ligand-free conditions. This novel method is very efficient for the functionalization of aniline and derivatives with a wide range of aromatic and aliphatic alcohols as well as diols and exhibits excellent functional group tolerance including halides, benzodioxane and heteroaromatic groups. Several TEM measurements

  通过借用氢策略使胺与醇选择性地进行N烷基化反应是一种突出的可持续催化方法，该方法产生水作为唯一的副产物，非常适合可广泛衍生自可再生能源的醇反应伙伴的催化转化资源。集中研究致力于开发主要基于昂贵的贵金属的新型催化剂。但是，用于这种转化的均相或非均相非贵金属催化剂的可用性非常有限。本文中，我们提出了一种高活性且非常易于制备的镍基催化剂体系，用于将胺与醇选择性地进行N-烷基化，该反应是就地进行的。在无配体条件下由Ni（COD）2和KOH生成。这种新方法对于苯胺及其衍生物与各种芳香族和脂肪族醇以及二醇的官能化非常有效，并且具有出色的官能团耐受性，包括卤化物，苯并二恶烷和杂芳族基团。为了结合活性催化剂的性质和影响反应活性的因素，进行了几种TEM测量和元素分析的结合。
• Lubricant and fuel dispersants and methods of preparation thereof
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US10017708B2

  公开（公告）日：2018-07-10

  This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one —NH— group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.

  本公开涉及一种用作燃料和润滑剂添加剂的组合物，包括基于乙烯端基的大分子单体（VTM）为基础的醛的还原胺化产物。可选地，醛与氨基化合物在足以形成亚胺中间体的缩合条件下反应，然后在足以形成该组合物的氢化条件下反应。醛是通过在足以形成醛的羟甲基化条件下反应VTM形成的。一种用于制备用作燃料和润滑剂添加剂的组合物的还原胺化方法。该方法包括在足以形成亚胺中间体的缩合条件下，反应基于VTM的醛与至少含有一个—NH—基团的氨基化合物，并在足以形成所述组合物的氢化条件下反应亚胺中间体。醛是通过在足以形成醛的羟甲基化条件下反应VTM形成的。
• COMPOUND, LIQUID COMPOSITION, THERMAL TRANSFER RECORDING SHEET, TONER, RESIST COMPOSITION FOR COLOR FILTER, AND COLOR FILTER
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20200347007A1

  公开（公告）日：2020-11-05

  Provided is, for example, a compound excellent in light fastness and storage stability. The compound is characterized by having a structure represented by the following formula (1) or (2).

  提供的是一种在耐光性和储存稳定性方面表现优异的化合物。该化合物的特征是具有以下公式（1）或（2）所代表的结构。
• Method of indirect liquid-phase heat transfer
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0212150A2

  公开（公告）日：1987-03-04

  A method of indirect liquid phase heat transfer utilizing as a heat transfer fluid a composition comprising poly(tetramethylene oxide) or poly(trimethylene oxide) homopolymers having molecular weights of from about 300 to about 1,000.

  一种间接液相传热方法，利用一种由聚（四甲基氧化物）或聚（三甲基氧化物）均聚物组成的组合物作为传热流体，该组合物的分子量约为 300 到 1000。