(2,6-diethylphenyl)(2,6-dimesitylphenyl)GeH2 | 330583-45-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,6-diethylphenyl)(2,6-dimesitylphenyl)GeH2
• 英文别名: (2,6-dimesitylphenyl)(2,6-diethylphenyl)GeH2；[2,6-Bis(2,4,6-trimethylphenyl)phenyl]-(2,6-diethylphenyl)germane；[2,6-bis(2,4,6-trimethylphenyl)phenyl]-(2,6-diethylphenyl)germane
• CAS: 330583-45-4
• 化学式: C₃₄H₄₀Ge
• 分子量: 521.282
• InChiKey: CZHZAQFKYAWKKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.12
• 重原子数：
  35
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (2,6-diethylphenyl)(2,6-dimesitylphenyl)GeH2 以 正己烷 为溶剂， 生成 (2,6-diethylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetragermolane
  参考文献：
  名称：

  1,2,3,4,5,6,7-Hexathiagermepanes: Synthesis, Structures, and the Ring Contraction to 1,2,3,4,5-Tetrathiagermolanes

  摘要：

  通过对相应的二氢锗进行硫化，合成了首批 1,2,3,4,5,6,7-hexathiagermepanes Dmp(Ar)GeS6 [Dmp=2,6-dimesitylphenyl, Ar = Mes, Dep (2,6-diethylphenyl), Tip (2,4,6-triisopropylphenyl)] 以及 1,2,3,4,5-tetrathiagermolanees 。由于立体阻碍作用，六硫杂锗烷 Dmp(Tip)GeS6 在释放元素硫的过程中缓慢转化为四硫杂锗烷。

  DOI：

  10.1246/cl.2001.60
• 作为产物：
  描述：

  (2,6-diethylphenyl)magnesium bromide 生成 (2,6-diethylphenyl)(2,6-dimesitylphenyl)GeH2
  参考文献：
  名称：

  1,2,3,4,5,6,7-Hexathiagermepanes: Synthesis, Structures, and the Ring Contraction to 1,2,3,4,5-Tetrathiagermolanes

  摘要：

  通过对相应的二氢锗进行硫化，合成了首批 1,2,3,4,5,6,7-hexathiagermepanes Dmp(Ar)GeS6 [Dmp=2,6-dimesitylphenyl, Ar = Mes, Dep (2,6-diethylphenyl), Tip (2,4,6-triisopropylphenyl)] 以及 1,2,3,4,5-tetrathiagermolanees 。由于立体阻碍作用，六硫杂锗烷 Dmp(Tip)GeS6 在释放元素硫的过程中缓慢转化为四硫杂锗烷。

  DOI：

  10.1246/cl.2001.60

文献信息

• Sterically Protected Dipotassium Germanedithiolate
  作者：Tsuyoshi Matsumoto、Kazuyuki Tatsumi

  DOI：10.1246/cl.2001.964

  日期：2001.10

  The germanedithiols Dmp(Ar)Ge(SH)2 [Dmp=2,6-dimesitylphenyl; Ar = Dep (2,6-diethylphenyl) 1a, Tip (2,4,6-triisopropylphenyl) 1b] were synthesized by the reduction of hexathiagermepanes Dmp(Ar)GeS6 and tetrathiagermolanes Dmp(Ar)GeS4 with NaBH4. The treatment of 1awith 2 equiv of potassium hydride afforded the dipotassium germanedithiolate 2.

  合成了德罕二硫醇 Dmp(Ar)Ge(SH)2 [Dmp=2,6-二美克斯苯基；Ar = Dep (2,6-二乙基苯) 1a，Tip (2,4,6-三异丙基苯) 1b]，方法是用 NaBH4 将六硫代锗烷 Dmp(Ar)GeS6 和四硫代锗烷 Dmp(Ar)GeS4 还原。用 2 当量的氢化钾处理 1a 生成了二钾德罕二硫醇盐 2。
• Synthesis of Oxo- and Sulfido-Bridged Germanium−Ruthenium Complexes and Reactions on the Chalcogenido Bridges
  作者：Tsuyoshi Matsumoto、Yukiko Nakaya、Kazuyuki Tatsumi

  DOI：10.1021/om060449m

  日期：2006.9.1

  A series of heterodinuclear germanium-ruthenium complexes having sulfido/oxo bridges, Dmp(Dep)Ge(mu-E-1)(mu-E-2)Ru(eta(6)-arene) (E-1, E-2 = S, O; arene) benzene, p-cymene; Dmp = 2,6-dimesitylphenyl, Dep) 2,6-diethylphenyl) were synthesized by the reaction of [Ru(eta(6)-arene)Cl-2](2) and the corresponding diarylgermanedichalcogenoles, Dmp(Dep)Ge((EH)-H-1)((EH)-H-2). The reaction with tertiary phosphines gave the corresponding adducts Dmp(Dep)Ge(mu-S)(mu-E)Ru(PR3) (E = S, O; R = Ph, Et), in which the arene ligand on the ruthenium was replaced by a mesityl group of Dmp. When Dmp(Dep)Ge(mu-S)(2)Ru(PPh3) was treated with the Bronsted acids H(OEt2)(2)BAr4F and HOTf, a sulfido bridge was protonated to afford [Dmp(Dep)Ge(mu-S)(mu-SH)Ru(PPh3)]X (X = BAr4F, OTf). Likewise, the methylation reaction with Me3OBF4 proceeded at a mu-S, generating [Dmp(Dep)Ge(mu-S)(mu-SMe)Ru(PPh3)](BF4). On the other hand, protonation of Dmp(Dep)Ge(mu-S)(mu-O)Ru(PPh3) gave a mu-OH complex, [Dmp(Dep)Ge(mu-S)(mu-OH)Ru(PPh3)](+), while the analogous methylation afforded the cationic mu-SMe complex [Dmp(Dep)Ge(mu-SMe)(mu-O)Ru(PPh3)](+).
• 1,2,3,4,5,6,7-Hexathiagermepanes: Synthesis, Structures, and the Ring Contraction to 1,2,3,4,5-Tetrathiagermolanes
  作者：Tsuyoshi Matsumoto、Yosuke Matsui、Yukiko Nakaya、Kazuyuki Tatsumi

  DOI：10.1246/cl.2001.60

  日期：2001.1

  The first 1,2,3,4,5,6,7-hexathiagermepanes Dmp(Ar)GeS6 [Dmp=2,6-dimesitylphenyl, Ar = Mes, Dep (2,6-diethylphenyl), Tip (2,4,6-triisopropylphenyl)] were synthesized along with 1,2,3,4,5-tetrathiagermolanes by sulfurization of the corresponding dihydrogermanes. The hexathiagermepane Dmp(Tip)GeS6 slowly converted to the tetrathiagermolane with release of elemental sulfur owing to the steric hindrance.

  通过对相应的二氢锗进行硫化，合成了首批 1,2,3,4,5,6,7-hexathiagermepanes Dmp(Ar)GeS6 [Dmp=2,6-dimesitylphenyl, Ar = Mes, Dep (2,6-diethylphenyl), Tip (2,4,6-triisopropylphenyl)] 以及 1,2,3,4,5-tetrathiagermolanees 。由于立体阻碍作用，六硫杂锗烷 Dmp(Tip)GeS6 在释放元素硫的过程中缓慢转化为四硫杂锗烷。