2-(tributylstannyl)-4-(pyrrolidin-1-yl)pyridine | 868254-44-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(tributylstannyl)-4-(pyrrolidin-1-yl)pyridine
• 英文别名: 4-pyrrolidin-1-yl-2-tributylstannanyl-pyridine；4-(1-Pyrrolidinyl)-2-(tributylstannyl)pyridine；tributyl-(4-pyrrolidin-1-ylpyridin-2-yl)stannane
• CAS: 868254-44-8
• 化学式: C₂₁H₃₈N₂Sn
• 分子量: 437.256
• InChiKey: HBAZKIDNTCCSFT-UHFFFAOYSA-N

物化性质

• 沸点：
  477.7±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.74
• 重原子数：
  24
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  16.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(tributylstannyl)-4-(pyrrolidin-1-yl)pyridine 、 2,6-二氯吡啶 在 bis-triphenylphosphine-palladium(II) chloride 三苯基膦 作用下， 以 xylene 为溶剂， 反应 20.0h， 以20%的产率得到4-(pyrrolidin-1-yl)-2-(6-(4-(pyrrolidin-1-yl)pyridin-2-yl)pyridin-2-yl)pyridine
  参考文献：
  名称：

  Pyrrolidine-Containing Polypyridines: New Ligands for Improved Visible Light Absorption by Ruthenium Complexes

  摘要：

  A range of new electron-releasing pyrrolidine-containing bipyridines and terpyridines has been prepared via selective metalation-cross-coupling sequences. The obtained ligands have been involved in microwave-assisted ruthenium complexation leading to homoleptic complexes in high yield. The electron-donor effect of the pyrrolidine nucleus led to a notable improvement of visible light absorption and strong changes in the electrochemical behavior, opening new opportunities for the design of photovoltaic devices.

  DOI：

  10.1021/jo051994k

文献信息

• Pyrrolidine-Containing Polypyridines: New Ligands for Improved Visible Light Absorption by Ruthenium Complexes
  作者：David Martineau、Marc Beley、Philippe C. Gros

  DOI：10.1021/jo051994k

  日期：2006.1.1

  A range of new electron-releasing pyrrolidine-containing bipyridines and terpyridines has been prepared via selective metalation-cross-coupling sequences. The obtained ligands have been involved in microwave-assisted ruthenium complexation leading to homoleptic complexes in high yield. The electron-donor effect of the pyrrolidine nucleus led to a notable improvement of visible light absorption and strong changes in the electrochemical behavior, opening new opportunities for the design of photovoltaic devices.