3-[4,6-Bis(3,5-dimethylpyrazol-1-yl)-1,3,5-triazin-2-yl]-1,2-dihydropyrrolo[2,1-b][1,3]benzothiazole | 910219-88-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 3-[4,6-Bis(3,5-dimethylpyrazol-1-yl)-1,3,5-triazin-2-yl]-1,2-dihydropyrrolo[2,1-b][1,3]benzothiazole
• CAS: 910219-88-4
• 化学式: C₂₃H₂₂N₈S
• 分子量: 442.547
• InChiKey: YARZHGYMKPEWLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 三聚氯氰 、 2,3-dihydro-1H-benzo[d]pyrrolo[2,1-b]thiazol-9-ylium bromide 在 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 、 异丁酰胺 为溶剂， 以15.8%的产率得到3-[4,6-Bis(3,5-dimethylpyrazol-1-yl)-1,3,5-triazin-2-yl]-1,2-dihydropyrrolo[2,1-b][1,3]benzothiazole
  参考文献：
  名称：

  Luminous Compound Containing Lanthanide Ion

  摘要：

  一种由以下化学式（I）表示的发光化合物：Met-COG-ChHet  化学式（I）其中，Met代表含有镧系离子的基团，COG代表直接连接到Met所代表的基团中含有的镧系离子的杂环基团，ChHet代表具有杂环的基团，其中ChHet最好是与COG共轭的基团。

  公开号：

  US20090247736A1

文献信息

• Fluorescent polymer fine particle
  申请人：Fujifilm Corporation

  公开号：EP1783168A2

  公开（公告）日：2007-05-09

  The invention provides a fluorescent polymer fine particle having at least; a polymer particle having a core-shell configuration having a hydrophobic core and a hydrophilic shell; and a fluorescent lanthanoid dye that is integrated with the polymer particle and has a fluorescent lanthanoid cation, wherein a hydrophilic polymer which forms the hydrophilic shell has a polymerizable unit and at least one hydrophilic unit selected from the group consisting of a hydrophilic (meth)acrylamide unit and a hydrophilic vinyl amine unit. The invention further provides a method for forming the fluorescent polymer fine particle having at least dispersing and polymerizing a hydrophobic radical polymerizable monomer in an aqueous solvent in the presence of a radical generator and the presence of a components for forming a hydrophilic polymer which forms the hydrophilic shell; and introducing the fluorescent lanthanoid dye with the polymer particle.

  本发明提供了一种荧光聚合物微粒，该微粒至少具有；具有芯壳构型的聚合物微粒，该聚合物微粒具有疏水芯和亲水壳；以及与聚合物微粒结合并具有荧光镧系阳离子的荧光镧系染料，其中形成亲水壳的亲水聚合物具有可聚合单元和至少一个亲水单元，该亲水单元选自由亲水(甲基)丙烯酰胺单元和亲水乙烯基胺单元组成的组。本发明进一步提供了一种形成荧光聚合物微粒的方法，该方法至少在水性溶剂中，在自由基发生器和形成亲水聚合物的组分存在的情况下，分散和聚合疏水自由基可聚合单体，形成亲水外壳；并将荧光镧系染料引入聚合物微粒。
• Fluorescent polymer fine particle set, fluorescence detecting complex member set, fluorescent polymer fine particle composition and fluorescence detecting method
  申请人：FUJIFILM Corporation

  公开号：EP1903075A1

  公开（公告）日：2008-03-26

  The invention provides a fluorescent polymer fine particle set including at least a first fluorescent polymer fine particle including a polymer fine particle having a core-shell configuration formed by a hydrophobic core and a hydrophilic shell, and a first fluorescent lanthanoid dye incorporated in the polymer fine particle and containing a lanthanoid cation, and a second fluorescent polymer fine particle including the polymer fine particle, and a second fluorescent lanthanoid dye different from the first fluorescent lanthanoid dye, a fluorescence detecting complex member set, a fluorescent polymer fine particle composition, and a fluorescence detecting method utilizing the same.

  本发明提供了一种荧光聚合物微粒组，至少包括第一荧光聚合物微粒，包括具有由疏水核和亲水壳形成的核壳构型的聚合物微粒，以及掺入聚合物微粒并含有镧系阳离子的第一荧光镧系染料、第二荧光聚合物微粒，包括该聚合物微粒和不同于第一荧光镧系染料的第二荧光镧系染料、荧光检测复合物构件组、荧光聚合物微粒组合物，以及利用该组合物的荧光检测方法。
• Fluorescent polymer fine particle set, fluorescence detecting complex member set, use of fluorescent polymer fine particle set and fluorescence detecting method
  申请人：FUJIFILM Corporation

  公开号：EP1903075B1

  公开（公告）日：2010-01-27
• Fluorescent polymer fine particle, method for forming thereof, fluorescence detection kit, and method for detecting fluorescence
  申请人：Makino Naonori

  公开号：US20070105990A1

  公开（公告）日：2007-05-10

  The invention provides a fluorescent polymer fine particle having at least: a polymer particle having a core-shell configuration having a hydrophobic core and a hydrophilic shell; and a fluorescent lanthanoid dye that is integrated with the polymer particle and has a fluorescent lanthanoid cation, wherein a hydrophilic polymer which forms the hydrophilic shell has a polymerizable unit and at least one hydrophilic unit selected from the group consisting of a hydrophilic (meth)acrylamide unit and a hydrophilic vinyl amine unit. The invention further provides a method for forming the fluorescent polymer fine particle having at least dispersing and polymerizing a hydrophobic radical polymerizable monomer in an aqueous solvent in the presence of a radical generator and the presence of a components for forming a hydrophilic polymer which forms the hydrophilic shell; and introducing the fluorescent lanthanoid dye with the polymer particle.
• FLUORESCENT POLYMER FINE PARTICLE SET, FLUORESCENCE DETECTING COMPLEX MEMBER SET, FLUORESCENT POLYMER FINE PARTICLE COMPOSITION AND FLUORESCENCE DETECTING METHOD
  申请人：MAKINO Naonori

  公开号：US20080070319A1

  公开（公告）日：2008-03-20

  The invention provides a fluorescent polymer fine particle set including at least a first fluorescent polymer fine particle including a polymer fine particle having a core-shell configuration formed by a hydrophobic core and a hydrophilic shell, and a first fluorescent lanthanoid dye incorporated in the polymer fine particle and containing a lanthanoid cation, and a second fluorescent polymer fine particle including the polymer fine particle, and a second fluorescent lanthanoid dye different from the first fluorescent lanthanoid dye, a fluorescence detecting complex member set, a fluorescent polymer fine particle composition, and a fluorescence detecting method utilizing the same.