2-(phenylamino)pyridinium tetrachloro[2-(phenylamino)pyridinato-N,N']titanate(IV) | 186337-69-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(phenylamino)pyridinium tetrachloro[2-(phenylamino)pyridinato-N,N']titanate(IV)
• 英文别名: N-phenylpyridin-1-ium-2-amine;phenyl(pyridin-2-yl)azanide;titanium(4+);tetrachloride
• CAS: 186337-69-9
• 化学式: C₁₁H₉Cl₄N₂Ti*C₁₁H₁₁N₂
• 分子量: 530.12
• InChiKey: JMMNPYOLWMWQLM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  8.42
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.1
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-苯胺基吡啶 、 四氯化钛 以 甲苯 为溶剂， 生成 2-(phenylamino)pyridinium tetrachloro[2-(phenylamino)pyridinato-N,N']titanate(IV)
  参考文献：
  名称：

  Tetrachloro[2-(phenylamino)pyridinato]titanate(IV) with a 2-(Phenylamino)pyridinium Counterion

  摘要：

  The title salt, 2-(phenylamino)pyridinium tetrachloro[2- (phenylamino)pyridinato-N,N']titanate(IV), (C11H11N2)-[TiCl4(C11H9N2)], is a product of the reaction of titanium tetrachloride and 2-(phenylamino)pyridine. The coordinated deprotonated aminopyridine forms a four-membered chelate ring. Titanium has a pseudooctahedral coordination sphere. A second 2-(phenylamino)pyridine residue behaves as a proton acceptor and is a counterion in the solid state.

  DOI：

  10.1107/s0108270196010347

文献信息

• Tetrachloro[2-(phenylamino)pyridinato]titanate(IV) with a 2-(Phenylamino)pyridinium Counterion
  作者：M. Polamo、M. Leskelä

  DOI：10.1107/s0108270196010347

  日期：1996.12.15

  The title salt, 2-(phenylamino)pyridinium tetrachloro[2- (phenylamino)pyridinato-N,N']titanate(IV), (C11H11N2)-[TiCl4(C11H9N2)], is a product of the reaction of titanium tetrachloride and 2-(phenylamino)pyridine. The coordinated deprotonated aminopyridine forms a four-membered chelate ring. Titanium has a pseudooctahedral coordination sphere. A second 2-(phenylamino)pyridine residue behaves as a proton acceptor and is a counterion in the solid state.