6,6'-(butane-1,4-diyl)bis(1,2,3,4-tetrahydronaphthalene) | 1914-37-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 6,6'-(butane-1,4-diyl)bis(1,2,3,4-tetrahydronaphthalene)
• 英文别名: 1,4-bis(5,6,7,8-tetrahydronaphthalen-2-yl)butane；1,4-Di-<6>tetralyl-butan；1,4-Bis--butan；1,4-Di-<3,4-tetramethylenphenyl>-butan；6,6'-(Butane-1,4-diyl)di-1,2,3,4-tetrahydronaphthalene；6-[4-(5,6,7,8-tetrahydronaphthalen-2-yl)butyl]-1,2,3,4-tetrahydronaphthalene
• CAS: 1914-37-0
• 化学式: C₂₄H₃₀
• 分子量: 318.502
• InChiKey: GWYKYRFJJJKPGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6,6'-(butane-1,4-diyl)bis(1,2,3,4-tetrahydronaphthalene) 在 palladium on activated charcoal Methyl cinnamate 作用下， 反应 0.5h， 以77%的产率得到2,2'-(butane-1,4-diyl)bisnaphthalene
  参考文献：
  名称：

  Formation of 6,6'-(Butane-1,4-diyl)bis(1,2,3,4-tetrahydronaphthalene) in the reaction of tetralin with aluminium chloride

  摘要：

  研究表明 氯化铝与四氢萘反应生成 6,6'-（丁烷-1,4-二1）-双（1,2,3,4-四氢萘）以及其他一些产物。 其他一些产物。据推测，这种化合物是通过质子化 四氢萘的质子化、脂环的破碎和 然后与另一个四氢萘分子发生亲电作用。 分子的亲电作用。产物中的取代位置表明，离子对 参与了反应。很明显，中间产物具有足够的寿命，除了发生分子内取代反应外，还能发生分子间取代反应。 除了分子内取代或质子损失外，中间体显然还有足够的寿命来进行分子间取代反应。

  DOI：

  10.1071/ch9842379
• 作为产物：
  描述：

  1,7-辛二炔 在 五氯化钼 、 氢化铝 作用下， 以 乙二醇二甲醚 为溶剂， 反应 6.0h， 以46%的产率得到6,6'-(butane-1,4-diyl)bis(1,2,3,4-tetrahydronaphthalene)
  参考文献：
  名称：

  Reduction of Molybdenum(V) Chloride with Various Reducing Metals: Reactivity Correlations with the Descendant Lewis Acids

  摘要：

  来自MoCl5与各种还原金属在DME中制备的低价钼的反应性，依赖于还原金属，对于炔烃的环三聚化反应，其顺序为：Al > Sn, In > Zn, Mg, Li。这个顺序与后续路易斯酸的酸性相对应。

  DOI：

  10.1246/cl.2000.140

文献信息

• Oxidative nitrene transfer from azides to alkynes <i>via</i> Ti(<scp>ii</scp>)/Ti(<scp>iv</scp>) redox catalysis: formal [2+2+1] synthesis of pyrroles
  作者：Adam J. Pearce、Xin Yi See、Ian A. Tonks

  DOI：10.1039/c8cc02623h

  日期：——

  Catalytic oxidative nitrene transfer from azides with the early transition metals is rare, and has not been observed without the support of redox noninnocent spectator ligands.

  从早期过渡金属中的叠氮化物进行催化氧化亚胺转移是罕见的，并且在没有氧化还原非无辜旁观配体的支持下尚未观察到。
• Low-Valent Niobium-Catalyzed Intermolecular [2 + 2 + 2] Cycloaddition of <i>tert</i>-Butylacetylene and Arylnitriles to Form 2,3,6-Trisubstituted Pyridine Derivatives
  作者：Yasushi Satoh、Yasushi Obora

  DOI：10.1021/jo401399y

  日期：2013.8.2

  A catalytic system based on low-valent niobium has been developed, consisting of NbCl5, Zn, and an alkoxysilane. This combination has been shown to be an efficient catalyst for the synthesis of pyridine derivatives from the intermolecular cycloaddition of alkynes and nitriles via a niobacyclopentadiene intermediate.
• Substituted benzocyclobutenes, indans, and tetralins via cobalt-catalyzed cooligomerization of .alpha.,.omega.-diynes with substituted acetylenes. Formation and synthetic utility of trimethylsilylated benzocycloalkenes
  作者：R. L. Hillard、K. Peter C. Vollhardt

  DOI：10.1021/ja00454a026

  日期：1977.6
• Ruthenium-mediated cyclotrimerization of alkynes utilizing the cationic complex [RuCp(CH3CN)3]PF6
  作者：Eva Rüba、Roland Schmid、Karl Kirchner、Maria José Calhorda

  DOI：10.1016/s0022-328x(03)00783-6

  日期：2003.10

  The substitutionally labile cationic complex [RuCp(CH3CN)(3)](+) (as the PF6- salt) was tested with respect to its ability to catalyze the cyclotrimerization of terminal alkynes and diynes to afford benzene derivatives. Whereas [RuCp(CH3CN)(3)](+) is in fact promoting the catalytic cyclotrimerization of alkynes, the formation of stable and inert sandwich complexes of the type [RuCp(eta(6)- arene)](+) deactivates the catalyst and thus quenches the catalytic cycle. All new sandwich complexes were isolated and characterized spectroscopically. A proposal for a plausible catalytic cycle including possible degradation pathways of the catalyst is presented based on DFT calculations. As key intermediates several novel carbene complexes have been identified including metallacyclo-pentatriene and metallaheptatetraene species. (C) 2003 Elsevier B.V. All rights reserved.
• 579. Poly-cyclotrimerisation of alkadiynes and cycloalkadiynes on complex metal catalysts
  作者：A. J. Hubert、Johannes Dale

  DOI：10.1039/jr9650003160

  日期：——