N,N'-bis-1-hexylheptyl-bis-2,2'-(2-naphthyl)imidazolo[4,5:b;4,5:e]naphthalenetetracarboxylic-1,8:4,5-biscarboximide | 1252975-12-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N,N'-bis-1-hexylheptyl-bis-2,2'-(2-naphthyl)imidazolo[4,5:b;4,5:e]naphthalenetetracarboxylic-1,8:4,5-biscarboximide
• 英文别名: 4,14-Dinaphthalen-2-yl-9,19-di(tridecan-7-yl)-3,5,9,13,15,19-hexazahexacyclo[9.9.2.02,6.07,22.012,16.017,21]docosa-1,3,6,11,13,16,21-heptaene-8,10,18,20-tetrone；4,14-dinaphthalen-2-yl-9,19-di(tridecan-7-yl)-3,5,9,13,15,19-hexazahexacyclo[9.9.2.02,6.07,22.012,16.017,21]docosa-1,3,6,11,13,16,21-heptaene-8,10,18,20-tetrone
• CAS: 1252975-12-4
• 化学式: C₆₂H₇₀N₆O₄
• 分子量: 963.276
• InChiKey: BRPSHUPBORKQKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.7
• 重原子数：
  72
• 可旋转键数：
  24
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  132
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-萘甲腈 、 2,7-bis(1-hexylheptyl)benzo[lmn][3,8]phenanthroline-1,3,6,8-tetraone 在 sodium amide 作用下， 反应 3.0h， 以28%的产率得到N,N'-bis-1-hexylheptyl-bis-2,2'-(2-naphthyl)imidazolo[4,5:b;4,5:e]naphthalenetetracarboxylic-1,8:4,5-biscarboximide
  参考文献：
  名称：

  Laterally Extended Naphthalene Tetracarboxylic Bisimides

  摘要：

  The colorless naphthalene tetracarboxylic bisimides were laterally extended with imidazole rings to give colored and highly fluorescent materials Donor-substituted phenyl groups at the imidazole rings cause further bathochromic shifts in fluorescence where the strong solvent influence in the spectra is typical for a TICT process Applications are discussed

  DOI：

  10.1021/jo101520a

文献信息

• PREPARATION OF PI-EXTENDED NAPHTHALENE DIIMIDES AND THEIR USE AS SEMICONDUCTOR
  申请人：BASF SE

  公开号：EP2989109B1

  公开（公告）日：2019-09-11
• US9444058B2
  申请人：——

  公开号：US9444058B2

  公开（公告）日：2016-09-13
• [EN] PREPARATION OF PI-EXTENDED NAPHTHALENE DIIMIDES AND THEIR USE AS SEMICONDUCTOR<br/>[FR] PRÉPARATION DE NAPHTHALENE DIIMIDES À EXTENSION PI ET LEUR UTLISATION EN TANT QUE SEMI-CONDUCTEUR
  申请人：BASF SE

  公开号：WO2014174435A2

  公开（公告）日：2014-10-30

  The present invention provides the compounds of formulae (1) or (2) and electronic devices comprising these compounds.
• Laterally Extended Naphthalene Tetracarboxylic Bisimides
  作者：Heinz Langhals、Simon Kinzel

  DOI：10.1021/jo101520a

  日期：2010.11.19

  The colorless naphthalene tetracarboxylic bisimides were laterally extended with imidazole rings to give colored and highly fluorescent materials Donor-substituted phenyl groups at the imidazole rings cause further bathochromic shifts in fluorescence where the strong solvent influence in the spectra is typical for a TICT process Applications are discussed