2,4,6-tris(2-cyanophenyl)-1,3,5-triazine | 6876-33-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-tris(2-cyanophenyl)-1,3,5-triazine
• 英文别名: 2,4,6-tris(o-cyanophenyl)-1,3,5-triazine；tris(2-cyanophenyl)-1,3,5-triazine；2,2',2''-[1,3,5]triazine-2,4,6-triyl-tris-benzonitrile；2,2',2''-[1,3,5]triazine-2,4,6-triyl-tri-benzonitrile；2,2',2''-[1,3,5]Triazin-2,4,6-triyl-tri-benzonitril；2,4,6-tri(o-cyanophenyl)-1,3,5-triazine；2,2',2''-(1,3,5-Triazine-2,4,6-triyl)tribenzonitrile；2-[4,6-bis(2-cyanophenyl)-1,3,5-triazin-2-yl]benzonitrile
• CAS: 6876-33-1
• 化学式: C₂₄H₁₂N₆
• 分子量: 384.399
• InChiKey: MBRLIGRTTVARHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,2-二氰基苯 在 水 作用下， 生成 2,4,6-tris(2-cyanophenyl)-1,3,5-triazine
  参考文献：
  名称：

  The Trimer of o-Phthalonitrile¹

  摘要：

  DOI：

  10.1021/ja01163a532

文献信息

• SYNTHESIS OF PHTHALOCYANINES FROM PHTHALONITRILE WITH ORGANIC STRONG BASES
  作者：Haruhiko Tomoda、Shojiro Saito、Shojiro Ogawa、Shinsaku Shiraishi

  DOI：10.1246/cl.1980.1277

  日期：1980.10.5

  In the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene or 1,5-diazabicyclo[4.3.0]non-5-ene, metal-free phthalocyanine was obtained by heating phthalonitrile in alcohols. Addition of a copper(II) salt in the reaction gave copper phthalocyanine in a good yield.

  在1,8-二氮杂双环[5.4.0]十一碳-7-烯或1,5-二氮杂双环[4.3.0]非5-烯存在下，通过在醇中加热邻苯二甲腈获得不含金属的酞菁。在反应中加入铜(II)盐以良好的产率得到铜酞菁。
• Temperature for curing phthalonitrile-terminated poly(phthalazinone ether nitrile) reduced by a mixed curing agent and its curing behavior
  作者：Zhihuan Weng、Jiayi Fu、Lishuai Zong、Cheng Liu、Jinyan Wang、Xigao Jian

  DOI：10.1039/c5ra17234a

  日期：——

  Introduction of AMTU as a curing agent into PPEN-Ph resulted in considerable reduction of the curing temperature without compromise in thermal properties.

  将AMTU作为固化剂引入PPEN-Ph中，显著降低了固化温度，而不影响热性能。
• PRODUCTION METHOD OF XYLYLENEDIAMINE
  申请人：KUMANO Tatsuyuki

  公开号：US20100168474A1

  公开（公告）日：2010-07-01

  A method of producing xylylenediamine by the hydrogenation of dicyanobenzene obtained by the ammoxidation of xylene in a high yield while prolonging the catalyst life. In the method, a molten dicyanobenzene from which compounds having a boiling point lower than that of dicyanobenzene have been removed but compounds having a boiling point higher than that of dicyanobenzene are not removed is dissolved in a solvent containing liquid ammonia. By this dissolution, at least part of dicyanobenzene polymers precipitates as insolubles. The precipitates are removed by a solid-liquid separation. By subjecting the resulting solution containing the dicyanobenzene polymers in a reduced amount to hydrogenation, xylylenediamine is produced in a high yield and the life time of hydrogenation catalyst is prolonged.

  一种通过将二甲苯氨氧化产生的二氰基苯经氢化反应制备对二甲苯二胺的方法，能够高产率地生产，同时延长催化剂的寿命。该方法中，将已去除沸点低于二氰基苯的化合物但未去除沸点高于二氰基苯的化合物的熔融二氰基苯溶于含有液氨的溶剂中。通过这种溶解，至少部分二氰基苯聚合物沉淀为不溶性物质。通过固液分离去除沉淀物。将含有少量二氰基苯聚合物的产物溶液进行还原反应，可以高产率地制备对二甲苯二胺，并延长氢化催化剂的使用寿命。
• Method for production of nuclear halogenated aromatic compound possessing cyano groups
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0795541A1

  公开（公告）日：1997-09-17

  A nuclear halogenated aromatic compound possessing cyano groups is produced by a method using as a raw material an aromatic compound which possesses cyano groups and assumes a solid state at room temperature and subjecting the raw material to a procedure comprising a step of melting and transporting the compound by a means transport-melting, a step of vaporizing the compound, a step of mixing the compound with a halogen gas, and a step of causing the vapor of the compound to react with the halogen gas in vapor phase in the presence of a catalyst sequentially in the order mentioned, which comprises maintaining a content of a self-condensate of the aromatic compound possessing cyano groups which arise during the melting of the aromatic compound possessing cyano groups in a gas of the compound which reacts with the halogen gas to a level of not more than 2.5 mol% based on the compound. The catalyst used in the method is activated carbon such that the average pore radius thereof determined by the nitrogen adsorption method is not less than 12.2 Å and the cumulative pore volume of the portion of the activated carbon having pore radiuses in the range of 5 - 100 Å determined by the steam adsorption method is not less than 0.45 g/cc.

  一种具有氰基的核卤化芳香族化合物的制备方法是，以一种具有氰基并在室温下呈固态的芳香族化合物为原料，将该原料置于一个程序中，该程序包括用一种运输-熔化方法熔化和运输该化合物的步骤、使该化合物气化的步骤、使该化合物与卤素气体混合的步骤，以及使该化合物的蒸气在有催化剂存在的情况下按上述顺序与气相中的卤素气体反应的步骤、在催化剂存在下，使化合物蒸气在气相中与卤素气体按上述顺序依次反应的步骤，该步骤包括将与卤素气体反应的化合物气体中具有氰基的芳香族化合物在熔化过程中产生的具有氰基的芳香族化合物自缩合物的含量保持在不超过化合物总量的 2.5 mol%。本发明方法中使用的催化剂是活性炭，其平均孔半径用氮吸附法测定不小于 12.2 Å，孔半径在 5 - 100 Å范围内的活性炭部分的累积孔体积用蒸汽吸附法测定不小于 0.45 g/cc。
• Production method of xylylenediamine
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2202218A1

  公开（公告）日：2010-06-30

  A method of producing xylylenediamine by the hydrogenation of dicyanobenzene obtained by the ammoxidation of xylene in a high yield while prolonging the catalyst life. In the method, a molten dicyanobenzene from which compounds having a boiling point lower than that of dicyanobenzene have been removed but compounds having a boiling point higher than that of dicyanobenzene are not removed is dissolved in a solvent containing liquid ammonia. By this dissolution, at least part of dicyanobenzene polymers precipitates as insolubles. The precipitates are removed by a solid-liquid separation. By subjecting the resulting solution containing the dicyanobenzene polymers in a reduced amount to hydrogenation, xylylenediamine is produced in a high yield and the life time of hydrogenation catalyst is prolonged.

  一种通过二甲苯氨氧化反应制得的二氰基苯的氢化反应生产二甲苯二胺的方法，该方法产率高，同时可延长催化剂寿命。在该方法中，将已除去沸点低于二氰基苯的化合物但未除去沸点高于二氰基苯的化合物的熔融二氰基苯溶解在含有液氨的溶剂中。通过这种溶解，至少有一部分二氰基苯聚合物以不溶物的形式沉淀下来。沉淀物通过固液分离去除。将所得的含有少量二氰基苯聚合物的溶液进行氢化，可生产出高产率的二甲苯，并延长氢化催化剂的使用寿命。