potassium O,O'-diphenylphosphorodithioate | 3514-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: potassium O,O'-diphenylphosphorodithioate
• 英文别名: Potassium;diphenoxy-sulfanylidene-sulfido-lambda5-phosphane；potassium;diphenoxy-sulfanylidene-sulfido-λ5-phosphane
• CAS: 3514-82-7
• 化学式: C₁₂H₁₀O₂PS₂*K
• 分子量: 320.414
• InChiKey: XVUQRRXFQRPSCU-UHFFFAOYSA-M

物化性质

• 熔点：
  187-188 °C

计算性质

• 辛醇/水分配系数(LogP)：
  0.92
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-氯-1-甲基吡啶碘化物 、 potassium O,O'-diphenylphosphorodithioate 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 O,O,O,O-tetraphenyl trithiopyrophosphate
  参考文献：
  名称：

  Min, Shi; Ishihara, Hideharu; Murai, Toshiaki, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1989, vol. 44, # 2, p. 153 - 157

  摘要：

  DOI：

文献信息

• Chadaeva,N.A. et al., Journal of general chemistry of the USSR, 1976, vol. 46, p. 816 - 818
  作者：Chadaeva,N.A. et al.

  DOI：——

  日期：——
• Malinovskii,M.S. et al., Journal of Organic Chemistry USSR (English Translation), 1966, vol. 2, p. 85 - 86
  作者：Malinovskii,M.S. et al.

  DOI：——

  日期：——
• Ganushchak, N. I.; Vengrzhanovskii, V. A.; Baranov, V. A., Journal of general chemistry of the USSR, 1980, vol. 50, # 11, p. 1986 - 1989
  作者：Ganushchak, N. I.、Vengrzhanovskii, V. A.、Baranov, V. A.、Bachinskii, T. P.

  DOI：——

  日期：——
• Pentacoordination at antimony via endocyclic and exocyclic intramolecular interactions in dibenzostibocine diorganodithiophosphates [{D(C6H4S)2}Sb{S2P(OR)2}] (D=O, S)
  作者：José G. Alvarado-Rodríguez、Simplicio González-Montiel、Noemí Andrade-López

  DOI：10.1515/mgmc-2012-0069

  日期：2013.1.1

  Treatment of [D(C6H4S)(2)}SbCl] (D = O, 1; D = S, 2) with MS2P(OR)(2) afforded the stable dibenzostibocine dithiophosphate compounds [D(C6H4S)(2)}SbS2P(OR)(2)}] with D = O, R = 1,2-C6H4 (3); for D = S, R = 1,2-C6H4 (4), Et (5), Pr-n (6), Pr-i (7), and Ph (8). The compounds were characterized by IR and H-1, C-13H-1}, and P-31H-1} NMR spectroscopy in solution. The P-31H-1} NMR data are consistent with an anisobidentate coordination mode of the dithiophosphate ligand to the Sb atom. Single crystal X-ray diffraction analyses of compounds 3, 4, 7, and 8 revealed that the antimony atom acts as an acceptor atom exhibiting endocyclic and exocyclic intramolecular interactions with the donor D atom and with both sulfur atoms of the dithiophosphate ligand, expanding its coordination sphere from four in the starting materials to five and displaying a skew-trapezoidal pyramidal local geometry.
• Hypervalent iodine in synthesis. 10. An efficient route to S-alkynyl O,O-dialkyl phosphorodithioates
  作者：Zudong Liu、Zhenchu Chen

  DOI：10.1021/jo00059a053

  日期：1993.3