1,4-bis-(4-pyridylsulfenylmethyl)benzene | 220905-48-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,4-bis-(4-pyridylsulfenylmethyl)benzene
• 英文别名: 1,4-Bis(4-pyridylsulfanylmethyl)benzene；4-[[4-(pyridin-4-ylsulfanylmethyl)phenyl]methylsulfanyl]pyridine
• CAS: 220905-48-6
• 化学式: C₁₈H₁₆N₂S₂
• 分子量: 324.47
• InChiKey: BQKMNTGRKRESFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-bis-(4-pyridylsulfenylmethyl)benzene 、 cobalt(II) thiocyanate 以 甲醇 、 硝基甲烷 为溶剂， 以66%的产率得到
  参考文献：
  名称：

  Polymeric transition metal complexes of 1,4-bis- (4-pyridylsulfenylmethyl)benzene and of its 2-pyridyl analogue

  摘要：

  The preparations are reported of a range of complexes of Mn-II, Co-II, Ni-II and Cu-II with 1,4-bis-(4-pyridylsulfenylmethyl)benzene (B4PSB) and of complexes of Co-II, Ni-II and Cu-II with the 2-pyridyl analogue (B2PSB), together with relevant spectroscopic data. X-Ray crystallographic studies on Co(B2PSB)(NO3)(2) show the presence of a chain structure in which five-coordinate cobalt centers are linked by bridging (B2PSB) ligands, with the remaining coordination sites about each metal atom being occupied by one very asymmetrically chelating nitrate group and an oxygen atom of a unidentate nitrate. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00295-2

文献信息

• Polymeric transition metal complexes of 1,4-bis- (4-pyridylsulfenylmethyl)benzene and of its 2-pyridyl analogue
  作者：Zeno Atherton、David M.L. Goodgame、Stephan Menzer、David J. Williams

  DOI：10.1016/s0277-5387(98)00295-2

  日期：1998.12

  The preparations are reported of a range of complexes of Mn-II, Co-II, Ni-II and Cu-II with 1,4-bis-(4-pyridylsulfenylmethyl)benzene (B4PSB) and of complexes of Co-II, Ni-II and Cu-II with the 2-pyridyl analogue (B2PSB), together with relevant spectroscopic data. X-Ray crystallographic studies on Co(B2PSB)(NO3)(2) show the presence of a chain structure in which five-coordinate cobalt centers are linked by bridging (B2PSB) ligands, with the remaining coordination sites about each metal atom being occupied by one very asymmetrically chelating nitrate group and an oxygen atom of a unidentate nitrate. (C) 1998 Elsevier Science Ltd. All rights reserved.