bis-(1,4-dimethyl-pentyl)-amine | 145659-67-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis-(1,4-dimethyl-pentyl)-amine
• 英文别名: Bis-(α.δ-dimethyl-pentyl)-amin；Bis-(α-methyl-isohexyl)-amin；Bis-(1,4-dimethyl-pentyl)-amin；5-methyl-N-(5-methylhexan-2-yl)hexan-2-amine
• CAS: 145659-67-2
• 化学式: C₁₄H₃₁N
• 分子量: 213.407
• InChiKey: GREVZGISCJVDKK-UHFFFAOYSA-N

物化性质

• 沸点：
  239.3±8.0 °C(Predicted)
• 密度：
  0.790±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-甲基-2-己酮 在 sodium hydroxide 、 镍 、 一水合肼 作用下， 生成 bis-(1,4-dimethyl-pentyl)-amine
  参考文献：
  名称：

  Mailhe, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1921, vol. 172, p. 692

  摘要：

  DOI：

文献信息

• Ruthenium-catalyzed deaminative redistribution of primary and secondary amines
  作者：S. Kostera、B. Wyrzykiewicz、P. Pawluć、B. Marciniec

  DOI：10.1039/c7dt02470c

  日期：——

  selective redistribution of primary and secondary amines bearing an α-hydrogen atom. This new deaminative coupling of amines enables the highly selective synthesis of secondary amines from primary amines and of tertiary amines from secondary amines with the evolution of ammonia. A preliminary mechanistic view of this novel reaction based on catalytic experiments using NMR methods confirms the synthetic

  发现钌-氢化物络合物[Ru（H）（Cl）（CO）（PCy 3）2 ]在带有α-氢原子的伯胺和仲胺的高选择性重新分布中具有活性。胺的这种新的脱氨基偶联使得能够随着伯氨的释放而从伯胺高度选择性地合成仲胺，并且能够从仲胺高度选择性地合成叔胺。基于使用NMR方法的催化实验，对该新颖反应的初步机理研究证实了合成观察结果。
• Ophthalmic Compositions for Treating Ocular Hypertension
  申请人：Doherty James B.

  公开号：US20090062280A1

  公开（公告）日：2009-03-05

  This invention relates to the use of potent potassium channel blockers or a formulation thereof in the treatment of glaucoma and other conditions which leads to elevated intraocular pressure in the eye of a patient. This invention also relates to the use of such compounds to provide a neuroprotective effect to the eye of mammalian species, particularly humans.

  本发明涉及在治疗青光眼和其他导致患者眼内压升高的疾病中使用强效钾通道阻滞剂或其配方。本发明还涉及使用这些化合物在哺乳动物，特别是人类的眼中提供神经保护作用。
• Preparation of color filter and photo-setting resin therefor
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0564237A2

  公开（公告）日：1993-10-06

  A photo-setting resin composition is here disclosed which comprises a photo-setting resin precursor and a dyestuff for uniformly coloring the photo-cured resin; and there is also disclosed a method for preparing a color filter by the use of this photo-setting resin composition.

  本文公开了一种光固化树脂组合物，它包括光固化树脂前体和用于使光固化树脂均匀着色的染料；还公开了一种使用这种光固化树脂组合物制备彩色滤光片的方法。
• Novel dyestuffs and their use
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0633296A1

  公开（公告）日：1995-01-11

  Dyestuffs represented by the below-described formula (1), that is, dyestuffs formed of a chromophoric nucleus and a bisphenol introduced therein have excellent solubility in solvents and binder resins, and can provide color filters having excellent transmittance characteristics and durability. wherein Dye represents a chromophoric nucleus, X represents a direct bond or a divalent connecting group, R¹ to R⁸ independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group or a substituted or unsubstituted alkoxyl group, R⁹ and R¹⁰ independently represent a hydrogen atom or a substituted or unsubstituted alkyl group, and n stands for an integer of 1 to 10, with the proviso that the total carbon number of R⁹ and R¹⁰ is at least 3.

  以下述式（1）为代表的染料，即由发色核和引入其中的双酚形成的染料，在溶剂和粘合剂树脂中具有优异的溶解性，可提供具有优异透射特性和耐久性的滤色片。 其中，染料代表发色核，X 代表直接键或二价连接基团，R¹ 至 R⁸ 各自代表氢原子、卤素原子、取代或未取代的烷基、取代或未取代的环烷基或取代或未取代的烷氧基、R⁹ 和 R¹⁰ 独立地代表氢原子或取代或未取代的烷基，且 n 代表 1 至 10 的整数，但 R⁹ 和 R¹⁰ 的总碳数至少为 3。
• Phthalocyanine compounds and usage thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0519423B1

  公开（公告）日：1999-03-03