2,9,16,23-tetracarboxyl phthalocyanine copper | 16337-64-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2,9,16,23-tetracarboxyl phthalocyanine copper
• 英文别名: copper 4,4',4'',4'''-tetracarboxyphthalocyanin；copper(II)-4,4',4'',4'''-phthalocyanine tetracarboxylic acid；copper tetra-4-carboxyphthalocyanine；copper tetra-carboxyl-phthalocyanine；Cu(4-COOH)4Pc；CuPc(COOH)4；(Tetracarboxyphthalocyaninato)copper(II)；copper;2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-6,15,24,33-tetracarboxylic acid
• CAS: 16337-64-7
• 化学式: C₃₆H₁₆CuN₈O₈
• 分子量: 752.118
• InChiKey: FSETZNSVSJCUDZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.92
• 重原子数：
  53
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  225
• 氢给体数：
  4
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  2,9,16,23-tetracarboxyl phthalocyanine copper 以 neat (no solvent) 为溶剂， 生成 [Cu(II)(tetra-tert-butylphthalocyanine-2H)]
  参考文献：
  名称：

  Studies on phthalocyanine sheet polymers

  摘要：

  Cobalt, nickel and copper phthalocyanine sheet polymers are synthesized by heating their respective metal (II) phthalocyanine tetracarboxylic acids at 400 degreesC in nitrogen atmosphere. These polymers are characterized using UV-Visible spectra, IR spectra, magnetic susceptibility.. X-ray powder diffraction and thermogravimetric analysis. Electrical conductivity studies are carried out using two-probe technique in the temperature range 25-200 degreesC for each polymer. These polymeric materials showed room temperature electrical conductivity 10-1000 times higher values compared to earlier reported values for this type of sheet polymers. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.017
• 作为产物：
  描述：

  1,2,4-苯三甲酸 在 ammonium molybdate 、 铜 、 尿素 、 sodium hydroxide 作用下， 生成 2,9,16,23-tetracarboxyl phthalocyanine copper
  参考文献：
  名称：

  Carboxy-substituted Phthalocyanine Metal Complexes

  摘要：

  合成了不同数量和位置的羧基取代酞菁金属配合物，以及同时具有羧基和其他取代基的化合物，并对它们的光谱及其他一些性质进行了研究。

  DOI：

  10.1007/s11176-005-0450-4

文献信息

• Improved Synthesis of Soluble Metal-Free/Metal Phthalocyanine Tetracarboxylic Acids and Their Application in the Catalytic Epoxidation of Cyclohexene
  作者：Xiaoling Sun、Li Wang、Zhi Tan

  DOI：10.1007/s10562-015-1500-0

  日期：2015.4

  selectivity of cyclohexene oxide. Metal-free phthalocyanine tetracarboxylic acid (5) and metal (copper (II), iron (III), and cobalt (II)) phthalocyanine tetracarboxylic acids (6–8, respectively) were compared. Complexes 6–8 exhibited higher catalytic activity than compound 5 under the optimal conditions.Graphical AbstractFour soluble metal-free and metal PTCs were synthesized using a novel method, and were

  摘要 使用基于重氮反应改进水解的新方法合成了不含可溶性金属和金属（铜 (II)、铁 (III) 和钴 (II)）酞菁四羧酸 (5-8)。所得化合物（5-8）通过 X 射线衍射、紫外-可见光谱和 FT-IR 光谱表征，然后用作催化剂以分子氧为氧化剂进行环己烯的环氧化。优化反应条件，包括反应时间、温度、催化剂用量和异丁醛/环己烯比，以实现最高的氧化环己烯选择性。比较了不含金属的酞菁四羧酸 (5) 和金属（铜 (II)、铁 (III) 和钴 (II)）酞菁四羧酸（分别为 6–8）。配合物6-8在最佳条件下表现出比化合物5更高的催化活性。图文摘要采用新方法合成了四种可溶性无金属和金属PTCs，并将其用作环己烯环氧化反应的催化剂，分子氧为氧化剂。在最佳条件下，共实现了58.1%的氧化环己烯选择性和收率。
• Synthesis, Characterization, Novel Interaction of DNA, Antioxidant and Antimicrobial Studies of New Water Soluble Metallophthalocyanines Posture Eight Hydroxyphenyl Moiety via 1,3,4-oxadiazole Bridge
  作者：Chidananda Basappa、Venugopala K. R. Reddy、Harish M. N. Kotresh、Pradeep K. Musturappa、Mruthyunjayachari C. Devendrachari、Shimoga D. Ganesh

  DOI：10.1002/jhet.2269

  日期：2015.11

  substituted MPc complexes. The successful synthesis of these novel water soluble MPc moieties were employed as an effective DNA binding with calf thymus DNA was monitored using ultraviolet−visible spectral titrations and cleavage pBR322 DNA conceded in the absence of reductant by agarose gel electrophoresis method. The results indicate that all these water soluble complexes significantly show excellent

  新的外围设备2（3），9（10），16（17），23（24）-tetra-5- [4,4'-二酚]-苯基-[1,3,4]-恶二唑取代的金属酞菁（ MPc）复合体已经过精心设计和执行。由于高的结合和在水中的极好的溶解性，使其在DNA结合和裂解研究中具有潜在的用途。傅里叶变换红外光谱，核磁共振，电子自旋电离质谱数据和元素分析证实了这些取代的MPc配合物的定义明确的鞍状扭曲结构。这些新颖的水溶性MPc部分的成功合成被用作与小牛胸腺DNA的有效DNA结合，使用紫外可见光谱滴定法进行监测，并通过琼脂糖凝胶电泳法在不存在还原剂的情况下裂解pBR322 DNA。结果表明，所有这些水溶性复合物均显着表现出优异的结合和适度的裂解敏感性活性。值得注意的是图6和7显示出与其他水溶性酞菁类相比潜在的抗微生物和明显的抗氧化活性。
• Solov'eva, L. I.; Luk'yanets, E. A., Journal of general chemistry of the USSR, 1980, vol. 50, p. 907 - 915
  作者：Solov'eva, L. I.、Luk'yanets, E. A.

  DOI：——

  日期：——
• Lebedeva; Pavlycheva; V'yugin, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 2, p. 289 - 293
  作者：Lebedeva、Pavlycheva、V'yugin、Maizlish、Shaposhnikov

  DOI：——

  日期：——
• Fabrication and Photoconductivity Study of Copper Phthalocyanine/Perylene Composite with Bulk Heterojunctions Obtained by Solution Blending
  作者：Xiong Mo、Hong-Zheng Chen、Yong Wang、Min-Min Shi、Mang Wang

  DOI：10.1021/jp050391+

  日期：2005.4.1

  Copper tetra-(octyl-alkoxy-carbonyl)-phthalocyanine (CuPc-C8) and 3,4,9,10-tetra-(octyl-alkoxy-carbonyl)perylene (Pery-C8) attached with long alkyl chains by covalent bonds were synthesized. Both of the two compounds showed good solubility in organic solvents, and the compatibility between them was improved. The novel composite of CuPc-C8/Pery-C8 was prepared by the solution-blending method. Atomic force microscopy (AFM) demonstrated the formation of the bulk heterojunction structure in their cast-coated films. Enhanced photosensitivity was observed in the photoreceptor made from the CuPc-C8/Pery-C8 composite, which was interpreted in terms of the large interfacial area between the two components due to the existence of the bulk heterojunction structure.