R243 | 16120-30-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: R243
• 英文别名: 4-amino-6-anilino-1H-[1,3,5]triazin-2-one；4-Amino-6-anilino-1,3,5-triazin-2-ol；6-amino-4-anilino-1H-1,3,5-triazin-2-one
• CAS: 16120-30-2
• 化学式: C₉H₉N₅O
• mdl: MFCD28366473
• 分子量: 203.203
• InChiKey: NXUBUNGQAOUETQ-UHFFFAOYSA-N

物化性质

• 沸点：
  357.2±25.0 °C(Predicted)
• 密度：
  1.52±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91.9
• 氢给体数：
  3
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  6-chloro-N-phenyl-1,3,5-triazine-2,4-diamine 以 水 、 乙腈 为溶剂， 生成 R243
  参考文献：
  名称：

  Binding of s-triazines to dissolved humic substances: Electrophoretic approaches using Affinity Capillary Electrophoresis (ACE) and Micellar Electrokinetic Chromatography (MEKC)

  摘要：

  Binding studies were conducted between s-triazines and soil and water extracted fulvic and humic acids (FA and HA) using capillary electrophoretic methods,A first approach to estimate simultaneously the affinity of several s-triazines (hydroxyatrazine, ameline, atraton and ametryn) to dissolved humic substances (HS) was done with the affinity capillary electrophoresis (ACE) modus; the limits of the ACE method resulted in the measurement of the electrophoretic mobility of the pesticide-HS complexes. In a second approach, the partition of the s-triazines between the water and the dissolved humic substances was successfully described like in micellar electrokinetic chromatography (MEKC) using the humic substances as micellar phase, Similar to surfactants, humic acids (HA) behaved like ionic micelles in the aqueous running buffer at concentrations higher than a defined ''humic critical micellar concentration'' (HCMC). The low molecular weight acidic fulvic acids (FA) behaved the same but showing higher HCMC.These results confirm the micellar properties of HS and the hydrophobic type of interaction of the s-triazines with hydrophobic sites of humic and fulvic ionic micelles. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0045-6535(97)00139-2

文献信息

• Monomer Synthesis.¹ Triazines. A Novel Method for the Reduction of Halomethyl Groups in the Triazine Series
  作者：Seymour L. Shapiro、C. G. Overberger

  DOI：10.1021/ja01630a026

  日期：1954.1
• Binding of s-triazines to dissolved humic substances: Electrophoretic approaches using Affinity Capillary Electrophoresis (ACE) and Micellar Electrokinetic Chromatography (MEKC)
  作者：Ph. Schmitt、D. Freitag、I. Trapp、A.W. Garrison、M. Schiavon、A. Kettrup

  DOI：10.1016/s0045-6535(97)00139-2

  日期：1997.7

  Binding studies were conducted between s-triazines and soil and water extracted fulvic and humic acids (FA and HA) using capillary electrophoretic methods,A first approach to estimate simultaneously the affinity of several s-triazines (hydroxyatrazine, ameline, atraton and ametryn) to dissolved humic substances (HS) was done with the affinity capillary electrophoresis (ACE) modus; the limits of the ACE method resulted in the measurement of the electrophoretic mobility of the pesticide-HS complexes. In a second approach, the partition of the s-triazines between the water and the dissolved humic substances was successfully described like in micellar electrokinetic chromatography (MEKC) using the humic substances as micellar phase, Similar to surfactants, humic acids (HA) behaved like ionic micelles in the aqueous running buffer at concentrations higher than a defined ''humic critical micellar concentration'' (HCMC). The low molecular weight acidic fulvic acids (FA) behaved the same but showing higher HCMC.These results confirm the micellar properties of HS and the hydrophobic type of interaction of the s-triazines with hydrophobic sites of humic and fulvic ionic micelles. (C) 1997 Elsevier Science Ltd.